• Title/Summary/Keyword: Spectrum Dispersion

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Seismic deformation demands on rectangular structural walls in frame-wall systems

  • Kazaz, Ilker
    • Earthquakes and Structures
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    • v.10 no.2
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    • pp.329-350
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    • 2016
  • A parametric study was conducted to investigate the seismic deformation demands in terms of drift ratio, plastic base rotation and compression strain on rectangular wall members in frame-wall systems. The wall index defined as ratio of total wall area to the floor plan area was kept as variable in frame-wall models and its relation with the seismic demand at the base of the wall was investigated. The wall indexes of analyzed models are in the range of 0.2-2%. 4, 8 and 12-story frame-wall models were created. The seismic behavior of frame-wall models were calculated using nonlinear time-history analysis and design spectrum matched ground motion set. Analyses results revealed that the increased wall index led to significant reduction in the top and inter-story displacement demands especially for 4-story models. The calculated average inter-story drift decreased from 1.5% to 0.5% for 4-story models. The average drift ratio in 8- and 12-story models has changed from approximately 1.5% to 0.75%. As the wall index increases, the dispersion in the calculated drifts due to ground motion variability decreased considerably. This is mainly due to increase in the lateral stiffness of models that leads their fundamental period of vibration to fall into zone of the response spectra that has smaller dispersion for scaled ground motion data set. When walls were assessed according to plastic rotation limits defined in ASCE/SEI 41, it was seen that the walls in frame-wall systems with low wall index in the range of 0.2-0.6% could seldom survive the design earthquake without major damage. Concrete compressive strains calculated in all frame-wall structures were much higher than the limit allowed for design, ${\varepsilon}_c$=0.0035, so confinement is required at the boundaries. For rectangular walls above the wall index value of 1.0% nearly all walls assure at least life safety (LS) performance criteria. It is proposed that in the design of dual systems where frames and walls are connected by link and transverse beams, the minimum value of wall index should be greater than 0.6%, in order to prevent excessive damage to wall members.

Dispersion Analysis of Higher-Order Modes for Planar Transmission Lines Using the 2-Dimensional Finite-Difference Time-Domain Method (2차원 유한차분-시간영역 방법을 이용한 평면형 전송선로의 고차 모드 분산 특성 해석)

  • 전중창;박위상
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.10 no.6
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    • pp.847-854
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    • 1999
  • In this paper, we have analysed frequency-dispersion characteristics of higher-order modes for uniform planar transmission lines, using the 2-dimensional finite-difference time-domain method. The method presented in this paper uses both informations of amplitude and phase of the electromagnetic spectrum to determine resonant frequencies, while methods previously reported use the magnitude only. This algorithm is very useful when a resonant mode has a relatively small magnitude, where the identification of the resonant mode is quite difficult. Numerical results show that a strip line supports few higher-order modes within the frequency range of 20 GHz, but there occur many higher-order modes in the structure of grounded coplanar waveguide, where resonant frequencies of the first higher-order mode is very close to those of the fundamental mode and there occur lots of very adjacent higher-order modes. As in this example, for the analysis of planar transmission lines which support many resonant modes very close each other, the method presented in this paper can be applied very efficiently.

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Frequency Dependent Properties of Tris(8-Hydroxyquinoline) Aluminum Thin Films

  • Lee, Yong-Soo;Park, Jae-Hoon;Choi, Jong-Sun
    • KIEE International Transactions on Electrophysics and Applications
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    • v.11C no.3
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    • pp.70-74
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    • 2001
  • Admittance or impedance spectroscopy is one of the powerful tools to study dielectric relaxation and loss processes in organic and inorganic materials. In this study, the frequency dependent properties of an indium tin oxide/tris(8-hydroxyquinoline) aluminum($Alq_3$)/aluminum structure have been studied. The conductance of the $Alq_3$ film increases with the DC applied voltage up to 4V and decreases above 4V in the low frequency region. This indicates that the resistance of the device decreases with the applied bias due to the carrier injection enhancement, thereafter the injected carriers form the space charge and the additional injection of carriers is prevented. The Cole-Cole plot of the admittance takes a one-semicircle shape, which means that the device can be modeled as a parallel resistor-capacitor network. The resistance and capacitance were estimated as 8.62k${\Omega}$ and 2.7nF, respectively, at 3V in the low frequency region. The dielectric constant ( ${\epsilon}'$ ) of the $Alq_3$ film is independent of the frequency in the low frequency region below 100kHz, while the frequency dependency was observed at above 100kHz. The dielectric loss factor ( ${\epsilon}"$ ) of the $Alq_3$ film shows the dielectric dispersion below 100kHz and dielectric absorption in higher frequency domain. The dispersion is thought to be related to the hopping process of the carriers. The ${\epsilon}"$ is proportional to the reciprocal of the frequency. The dielectric relaxation time was extracted to about 0.318${\mu}s$ from the dielectric absorption spectrum.

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The Effect of Mercaptoundecanoic Acid (MUA) Coating on Dispersion Property of Au Nanoparticles in Synthesis of Au/TiO2 Core-shell Nanoparticles (Au/TiO2 core-shell 나노입자의 합성에 있어서 Au 나노입자의 분산특성에 미치는 Mercaptoundecanoic acid (MUA)의 피복 효과)

  • Yu, Yeon-Tae;Kim, Byoung-Gyu
    • Korean Journal of Materials Research
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    • v.16 no.12
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    • pp.754-760
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    • 2006
  • Mercaptoundecanoic acid (MUA) has been used to enhance the dispersity of Au nanoparticles in organic solvent and the affinity between the Au nanoparticles surface and titanium dioxide shell in the synthesis of $Au/TiO_2$ core-shell composite nanoparticles. The dispersity of the MUA-coated Au nanoparticles in ethanol aqueous solution with different concentration of $H_2O$ was investigated by UV-Vis. absorption spectrum and the coating amount of MUA was varied from 0.02 mM to 1.0 mM. The MUA-coated Au nanoparticles were highly dispersed in pure $H_2O$ in the wide range of the coating amount of MUA. On the contrary, the MUAcoated Au nanoparticles showed an enhanced stability in the ethanol/$H_2O$=8/2 mixed solution only when the coating amount of MUA was 0.05 mM, and in the ethanol/$H_2O$=7/3 mixed solution when the coating amount of MUA was in the range from 0.02 mM to 0.17 mM. From this systematic study, it can be inferred that the stability and the dispersibility of Au nanoparticles in organic solvents are highly sensitive towards the amount of MUA coating.

Physicochemical Properties of Fibrous Material Fraction from By-product of Aloe vera Gel Processing (알로에 베라 겔 가공부산물로서의 섬유질 분획의 성분 및 물리화학적 특성)

  • Baek, Jin-Hong;Lee, Shin-Young
    • Food Engineering Progress
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    • v.14 no.2
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    • pp.118-126
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    • 2010
  • The fibrous material fraction as a by-product from the commercial aloe vera gel processing was obtained and freeze dried. The physicochemical characteristics such as the proximate composition, crystalline/surface structures and several physical functionalities including the water holding capacity (WHC), swelling capacity (SW), oil holding capacity (OHC), emulsion/foam properties and viscosity properties of this powdered sample (100 mesh) were investigated and analyzed by comparison with commercial $\alpha$-cellulose as a reference sample. The total dietary fiber content of powdered sample was very high as much as 87.5%, and the insoluble dietary and soluble dietary fiber content ratios were 77.6 and 22.4%, respectively. The FT-IR spectrum of powdered sample showed a typical polysaccharide property and exhibited a x-ray diffraction pattern for cellulose III and IV like structure. SW (8.24${\pm}$0.15 mL/g), WHC(6.40${\pm}$0.19 g water/g solid) and OHC(10.32${\pm}$0.29 g oil/g solid) of freeze dried aloe cellulose were about 3.3, 1.4 and 2 times higher than those of commercial $\alpha$-cellulose, respectively. Aloe cellulose (~2%, w/v) alone had no foam capacity while improved the foam stability of protein solution (1% albumin+0.5% $CaCl_{2}$) by factor of 300%. Emulsion capacity of 2%(w/v) aloe cellulose was about 70% level of 0.5%(w/v) xanthan gum, but its emulsion stability was about 1.2 times higher than that of xanthan gum. Also, aloe cellulose containing CMC (carboxyl methyl cellulose) of 0.3%(w/v) showed a very good dispersity. Aloe cellulose dispersion of above 1%(w/v) exhibited higher pseudoplasticity and concentration dependence than those of $\alpha$-cellulose dispersion, indicating the viscosity properties for new potential usage such as an excellent thickening agent.

Development of Site Classification System and Modification of Site Coefficients in Korea Based on Mean Shear Wave Velocity of Soil and Depth to Bedrock (기반암 깊이와 토층 평균 전단파속도를 이용한 국내 지반분류 방법 및 지반 증폭계수 개선)

  • Kim, Dong-Soo;Lee, Sei-Hyun;Yoon, Jong-Ku
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.28 no.1C
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    • pp.63-74
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    • 2008
  • Site response analyses were performed based on equivalent linear technique using the local geologic and dynamic site characteristics, which include soil profiles, shear wave velocity profiles and depth to bedrock for 125 sites collected in Korean Peninsula. From the results of site response analyses, 2-parameters site classification system based on the combination of mean shear wave velocity of soil and depth to bedrock was newly recommended for regions of shallow bedrock depth in Korea. First, as the borders of bedrock depth (H) for site classification were determined as 10m and 20m, the soil sites were divided into 3 classes as $H_1$, $H_2$ and $H_3$ sites. And then, the 3 site classes were subdivided into 7 classes based on the mean shear wave velocity of soil ($V_{s,soil}$). The feasibility of new site classification system was verified and the representative site coefficients ($F_a$ and $F_v$) and design response spectrum were suggested by analyzing uniform trend and dispersion of site coefficients for each site class. The suggested site coefficients and the regression curves present the nonlinear characteristics of soils according to the change of rock outcrop acceleration with uniform trend effectively. From the comparison between the mean values of response spectrum which was acquired from the site response analysis and the suggested design response spectrum, there was a little difference in some of site classes and it was verified to adjust the integration interval to make it more suitable for the site condition in Korea.

A Study on the Dielectric Properties and Electrical Conduction of PVDF Thin Films by Physical Vapor Deposition (진공 증착법으로 제작한 PVDF 박막의 유전 특성과 전기전도도에 대한 연구)

  • Gang, Seong-Jun;Lee, Won-Jae;Jang, Dong-Hun;Yun, Yeong-Seop
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.37 no.5
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    • pp.9-15
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    • 2000
  • The 3 ${\mu}{\textrm}{m}$-thick PVDF (polyvinylidene fluoride) thin film have been prepared using physical vapor deposition with electric field, and its FT-IR spectrum, dielectric property and electric conduction phenomenon have been investigated. Since the characteristic peaks are detected at 509.45 [$cm^{-1}$ /] and 1273.6 [$cm^{-1}$ /]in the FT-IR spectrum, we are confirmed that the $\beta$ -phase is dominant in the PVDF thin film. In the results of dielectric properties, the PVDF thin film shows anomalous dispersion, i.e. gradual decrease of dielectric constant with increase of frequency, and also that the dielectric absorption point changes from 200 Hz to 7000 Hz with increasing temperature of thin film, which is consistent with the Debye's theory. The activation energy ( $\Delta$H) obtained from temperature dependence of dielectric loss is 21.64 ㎉/mole. We confirm that the electric conduction mechanism of PVDF thin film is dominated by ionic conduction by investigating the dependence of the leakage current of the thin film on the temperature and the electric field.

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Investigation on the Variation of Ocean Waves passing through Shallow Waters (낮은 수심을 통과하는 해양파의 변화에 대한 연구)

  • Seok, Woochan;Won, Younsang
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.28 no.1
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    • pp.161-167
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    • 2022
  • Ocean waves passing through the underwater bar at a shallow depth experience a shoaling effect caused by decreasing water depth, a nonlinear interaction therein owing to steepening wave slope, and a wave dispersion effect as the water depth increases again. Because this problem includes many complicated phenomena, it is used as a good example of validating a theoretical development or a CFD method for ocean wave applications. Validation is performed mainly for regular waves by comparing the wave elevation patterns in the time domain with the experimental results. In this study, the spectral evolution of wave spectrum is investigated in the frequency domain when a CFD method such as OpenFOAM is applied for this problem. In particular, the effects of initial phase conditions as well as the nonlinear interaction among harmonic waves are studied.

Emulsification of Chloroprene Rubber (CR) by Interfacial Chemistry; Stabilization and Enhancement of Mechanical Properties

  • Lee, Eun-Kyoung
    • Elastomers and Composites
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    • v.52 no.4
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    • pp.257-265
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    • 2017
  • In this work, CR (Chloroprene Rubber) was emulsified by phase-inversion emulsification with nonionic surfactants (NP-1025, LE-1017, and OP-1019) and an anionic surfactant (SDBS; sodium dodecylbenzenesulfonate), and its stabilization was investigated through a study of its adsorption characteristics, zeta potential, and flow behavior. As the amount of the mixed surfactant increased, the droplet size decreased, resulting in the increase of viscosity. In particular, a CR emulsion with a lower absorbance in the UV spectrum exhibited the highest zeta potential. The results of this experiment showed that the CR emulsion prepared using (LE-1017) and SDBS was the most stable. In this study, calcium hydroxide and aluminum hydroxide were added to enhance the mechanical properties of the CR emulsion, and the relationship between tensile strength, tear strength and surface free energy were investigated. The tensile and tear strengths of the CR emulsion incresed as the amount of calcium hydroxide and aluminum hydroxide increased. The highest tensile and tear strengths and surface free energy were observed for additions of 1.0% calcium hydroxide and 0.80% aluminum hydroxide, respectively. It was concluded that the interfacial bonding strength was improved by the even dispersion of calcium hydroxide and aluminum hydroxide in the CR emulsion.

Encapsulation of CdSe/ZnS Quantum Dots in Poly(ethylene glycol)-Poly(D,L-lactide) Micelle for Biomedical Imaging and Detection

  • Lee, Yong-Kyu;Hong, Suk-Min;Kim, Jin-Su;Im, Jeong-Hyuk;Min, Hyun-Su;Subramanyam, Elango;Huh, Kang-Moo;Park, Sung-Woo
    • Macromolecular Research
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    • v.15 no.4
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    • pp.330-336
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    • 2007
  • Luminescent CdSe/ZnS QDs, with emission in the red region of the spectrum, were synthesized and encapsulated in poly(ethylene glycol)-poly(D,L-lactide) diblock copolymer micelles, to prepare water-soluble, bio-compatible QD micelles. PEG-PLA diblock copolymers were synthesized by ring opening polymerization of D,L-lactide, in the presence of methoxy PEG as a macro initiator. QDs were encapsulated with PEG-PLA polymers using a solid dispersion method in chloroform. The resultant polymer micelles, with encapsulated QDs, were characterized using various analytical techniques, such as UV- Vis measurement, light scattering, fluorescence spectroscopy, transmission electron microscopy (TEM) and atomic forced microscopy (AFM). The polymer micelles, with encapsulated QDs, were spherical and showed diameters in the range of 20-150 nm. The encapsulated QDs were highly luminescent, and have high potential for applications in biomedical imaging and detection.