• Title/Summary/Keyword: Spectrum Charge

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Statistical Characterization of the Multi-Charged Fragment Ions in the CID and HCD Spectrum

  • Ramachandran, Sangeetha;Thomas, Tessamma
    • Mass Spectrometry Letters
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    • v.12 no.2
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    • pp.41-46
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    • 2021
  • Collision-induced dissociation (CID) and higher-energy collisional dissociation (HCD) are the widely used fragmentation technique in mass spectrometry-based proteomics studies. Understanding the fragmentation pattern from the tandem mass spectra using statistical methods helps to implement efficient spectrum analysis algorithms. The study characterizes the frequency of occurrence of multi-charged fragment ions and their neutral loss events of doubly and triply charged peptides in the CID and HCD spectrum. The dependency of the length of the fragment ion on the occurrence of multi-charged fragment ion is characterized here. Study shows that the singly charged fragment ions are generally dominated in the doubly charged peptide spectrum. However, as the length of the product ion increases, the frequency of occurrence of charge 2 fragment ions increases. The y- ions have more tendencies to generate charge 2 fragment ions than b- ions, both in CID and HCD spectrum. The frequency of occurrence of charge 2 fragment ion peaks is prominent upon the dissociation of the triply charged peptides. For triply charged peptides, product ion of higher length occurred in multiple charge states in CID spectrum. The neutral loss peaks mostly exist in charge 2 states in the triply charged peptide spectrum. The b-ions peaks are observed in much less frequency than y-ions in HCD spectrum as the length of the fragment increases. Isotopic peaks are occurred in charge 2 state both in doubly and triply charged peptide's HCD spectrum.

Multi-point response spectrum analysis of a historical bridge to blast ground motion

  • Haciefendioglu, Kemal;Banerjee, Swagata;Soyluk, Kurtulus;Koksal, Olgun
    • Structural Engineering and Mechanics
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    • v.53 no.5
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    • pp.897-919
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    • 2015
  • In this study, the effects of ground shocks due to explosive loads on the dynamic response of historical masonry bridges are investigated by using the multi-point shock response spectrum method. With this purpose, different charge weights and distances from the charge center are considered for the analyses of a masonry bridge and depending on these parameters frequency-varying shock spectra are determined and applied to each support of the two-span masonry bridge. The net blast induced ground motion consists of air-induced and direct-induced ground motions. Acceleration time histories of blast induced ground motions are obtained depending on a deterministic shape function and a stationary process. Shock response spectrums determined from the ground shock time histories are simulated using BlastGM software. The results obtained from uniform and multi-point response spectrum analyses cases show that significant differences take place between the uniform and multi-point blast-induced ground motions.

A CMOS Charge Pump Circuit with Short Turn-on Time for Low-spur PLL Synthesizers

  • Sohn, Jihoon;Shin, Hyunchol
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.16 no.6
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    • pp.873-879
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    • 2016
  • A charge pump circuit with very short turn-on time is presented for minimizing reference spurs in CMOS PLL frequency synthesizers. In the source switching charge pump circuit, applying proper voltages to the source nodes of the current source FETs can significantly reduce the unwanted glitch at the output current while not degrading the rising time, thus resulting in low spur at the synthesizer output spectrum. A 1.1-1.6 GHz PLL synthesizer employing the proposed charge pump circuit is fabricated in 65 nm CMOS. The current consumption of the charge pump is $490{\mu}A$ from 1 V supply. Compared to the conventional charge pump, it is shown that the reference spur is improved by dB through minimizing the turn-on time. Theoretical analysis is described to show that the measured results agree well with the theory.

Charge Transfer Complex Formation of Amines with Organic Halides (I) (아민과 有機할로겐 化合物間의 Charge Transfer Complex 形成에 關한 硏究 (I))

  • Kim, Yoo-Sun;Oh, Jung-Hee
    • Journal of the Korean Chemical Society
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    • v.11 no.4
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    • pp.121-125
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    • 1967
  • The formation of a charge transfer complex between various amines and organic halogen compounds was closely investigated. A mixture of amine (piperidine, pyridine, diethylamine, ethylamine, triethylamine and triethanolamine) and organic halides(carbon tetrachloride and chloroform) was checked for its UV absorption spectrum in presence of n-hexane solvent. A red shift was observed. The formation of charge transfer complex was observed in the case of triethylamine and diethylamine, whereas the formation of contact complex was distinct in case of piperidine. The relation between the nucleophilicity of amines and their tendency of forming charge transfer complex was discussed.

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Synergy study on charge transport dynamics in hybrid organic solar cell: Photocurrent mapping and performance analysis under local spectrum

  • Hong, Kai Jeat;Tan, Sin Tee;Chong, Kok-Keong;Lee, Hock Beng;Ginting, Riski Titian;Lim, Fang Sheng;Yap, Chi Chin;Tan, Chun Hui;Chang, Wei Sea;Jumali, Mohammad Hafizuddin Hj
    • Current Applied Physics
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    • v.18 no.12
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    • pp.1564-1570
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    • 2018
  • Charge transport dynamics in ZnO based inverted organic solar cell (IOSC) has been characterized with transient photocurrent spectroscopy and localised photocurrent mapping-atomic force microscopy. The value of maximum exciton generation rate was found to vary from $2.6{\times}10^{27}m^{-3}s^{-1}$ ($J_{sat}=79.7A\;m^{-2}$) to $2.9{\times}10^{27}m^{-3}s^{-1}$ ($J_{sat}=90.8A\;m^{-2}$) for devices with power conversion efficiency ranging from 2.03 to 2.51%. These results suggest that nanorods served as an excellent electron transporting layer that provides efficient charge transport and enhances IOSC device performance. The photovoltaic performance of OSCs with various growth times of ZnO nanorods have been analysed for a comparison between AM1.5G spectrum and local solar spectrum. The simulated PCE of all devices operating under local spectrum exhibited extensive improvement with the gain of 13.3-3.7% in which the ZnO nanorods grown at 15 min possess the highest PCE under local solar with the value of 2.82%.

Efficient Spectrum Sensing for Multi-Copter (멀티콥터를 위한 효율적인 스펙트럼 센싱)

  • Jung, Kuk Hyun;Lee, Sun Yui;Park, Ji Ho;Kim, Jin Young
    • Journal of Satellite, Information and Communications
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    • v.9 no.4
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    • pp.20-25
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    • 2014
  • In this paper, we provide efficient spectrum sensing technology for smooth use of frequency and energy charge of multi-copter. The proposed structures focus on improving performance of spectrum sensing that is based on Ad-hoc network. First, we explain basic principles and disadvantages of cooperative spectrum sensing and ad-hoc based spectrum sensing. To solve these problems, in this paper, we employ the beamforming technology that guarantees higher transmit primary users' signal power to secondary users in ad-hoc network. The performance of proposed algorithm is analyzed in terms of detection probabilities, and the results of this paper can be applied to the various ad-hoc based Cognitive Radio system.

The Fundamental Study About Partial Discharge Detection With The Radiated Electromagnetic Wave Characteristics (방사전자파 특성을 이용한 부분방전 검출의 기초연구)

  • Lee, Sang-Hun;Park, Gwang-Seo;Kim, Chung-Nyeon;Lee, Hyeon-Dong;Song, Hyeon-Jik;Kim, Gi-Chae;Lee, Gwang-Sik;Lee, Dong-In
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.49 no.7
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    • pp.412-417
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    • 2000
  • This paper offer fundamental materials about Partial Discharge(PD) detection by electromagnetic waves. All spectrum data-usually used as grape- can be used as numbers. And then the average of background noise spectrum strength was made. Average value subtract from every data. Then average value appeared, graphed. The graph was compared with the magnitude of charge. The shape of changes is similar, and the change of electric field strength could be seen in one sight. When the magnitude of charge is over than 100[pC], antenna can detect partial discharge. So this method will be very useful to diagnosis of insulation. It the performance of the antenna used in this experiment is analyzed, good results can be obtained.

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Novel State-of-Charge Estimation Method for Lithium Polymer Batteries Using Electrochemical Impedance Spectroscopy

  • Lee, Jong-Hak;Choi, Woo-Jin
    • Journal of Power Electronics
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    • v.11 no.2
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    • pp.237-243
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    • 2011
  • Lithium batteries are widely used in mobile electronic devices due to their higher voltage and energy density, lighter weight and longer life cycle when compared to other secondary batteries. In particular, a high demand for lithium batteries is expected for electric cars. In the case of the lithium batteries used in electric cars, driving distance must be calculated accurately and discharging should not be done below a level that makes it impossible to crank. Therefore, accurate information on the state-of-charge (SOC) becomes an essential element for reliable driving. In this paper, a novel method for estimating the SOC of lithium polymer batteries using AC impedance is proposed. In the proposed method, the parameters are extracted by fitting the measured impedance spectrum on an equivalent impedance model and the variation in the parameter values at each SOC is used to estimate the SOC. Also to shorten the long length of time required for the measurement of the impedance spectrum, a novel method is proposed that can extract the equivalent impedance model parameters of lithium polymer batteries with the impedance measured at only two specific frequencies. Experiments are conducted on lithium polymer batteries, with similar capacities, made by different manufacturers to prove the validity of the proposed method.

Optical and Electrical Properties of Thin Film Electroluminescent Devices with SrS:Cu, Ag Phosphor Layer

  • Chang, Ho-Jung;Park, Jun-Seo;Chang, Young-Chul
    • Journal of the Microelectronics and Packaging Society
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    • v.9 no.1
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    • pp.29-33
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    • 2002
  • The SrS:Cu, Ag thin film electroluminescient devices were fabricated on $AlTiO_3$/ITO/glass substrates by electron-beam evaporation. The emission spectrum of the device was about 460 nm with $\chi$=0.20, y=0.29 in the CIE color coordinator. It was found that the emission spectrum was saturated to pure blue color when Ag sensitizer was doped in SrS:CuCl phosphors. The luminance of the device was increased by increasing the sulfur pressure. The measured luminance was saturated with 430 cd/$m^2$at the applied voltage of 90 V and the maximum luminance was 580 cd/$m^2$at 110V. The polarization charge and conduction charge of the devices were found to be found to be about $3.5\mu$C/$\textrm{cm}^2$ and $7.4\mu$C/$\textrm{cm}^2$, respectively.

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Some Peculiarities of Photo-structural Transformations in Amorphous Chalcogenide Glassy Semiconductor Films

  • Prikhodko, O.;Almasov, N.;Korobova, Natalya
    • Journal of information and communication convergence engineering
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    • v.9 no.5
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    • pp.587-590
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    • 2011
  • The absence of deep traps for electrons in the spectrum of $As_{40}Se_{30}S_30$ localized states films obtained by ion sputtering was determined. Bipolar drift of charge carriers was found in amorphous $As_{40}Se_{30}S_30$ films of chalcogenide glassy semiconductors, obtained by ion-plasma sputtering of high-frequency, unlike the films of these materials obtained by thermal evaporation.