• Title/Summary/Keyword: Spectroscopic Analysis

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Iridoid Compounds from the Whole Plant of Galium verum var. asiaticum

  • Lee, Tae Gwan;Kim, Dae Keun
    • Natural Product Sciences
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    • v.19 no.3
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    • pp.227-230
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    • 2013
  • One new iridoid glycoside, 10-p-dihydrocoumaroyl-6-${\alpha}$-hydroxygeniposide (1), and six known iridoid glycoside derivatives, 10-p-dihydrocoumaroyl deacetylasperuloside (2), asperulosidic acid methylester (3), asperuloside (4), asperulosidic acid (5), deacetylasperuloside (6), and scandoside (7) were isolated from the methanolic extract of the whole plant of Galium verum var. asiaticum Nakai (Rubiaceae) through repeated column chromatography. Their chemical structures were characterized by spectroscopic analysis. This is the first report of the characterization of compounds 1 - 7 from this plant.

Two Cyanidin compound from the Fruits of Acanthopanax divaricatus var. albeofructus

  • Hahn, Dug-Ryong;Park, Seon-Jin
    • Natural Product Sciences
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    • v.16 no.3
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    • pp.198-201
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    • 2010
  • Acanthopanax divaricatus var. albeofructus is one of the indigenous medicinal plant and the fruits of Acanthopanax spp. used as a remedial for "wipe out evil wind". Two anthocyanin were isolated from the fruits of Acanthopanax divaricatus var. albeofructus. Their structures were elucidated as cyanidin 3-lathyroside (1) and cyanidin 3-galactoside (2) by chemicophysical and spectroscopic analysis. And also, four chemical, syringin, chlorogenic acid, caffeic acid and acanthoside D were identified. Both anthocyanide were isolated for the first time from Acanthopanax species. cyanidin 3-lathyroside is one of the rare anthocyanin in natural resources.

Phytochemical Studies on the Constituents of Filipendula glaberrima (터리풀의 성분에 관한 식물 화학적 연구)

  • Yeo, Ho-Sup;Kim, Jin-Woong;Chung, Bo-Sup
    • Korean Journal of Pharmacognosy
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    • v.23 no.3
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    • pp.121-125
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    • 1992
  • Three compounds were isolated from the chloroform and n-butanol extracts of Filipendula glaberrima (Rosaceae). The structures of these isolates were elucidated as monotropitin, (+)-catechin, and ${\beta}-sitosteryl-3-O-{\beta}-D-glucopyranoside$ by spectroscopic analysis, and were identified by comparison of their spectra with those of reported ones.

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C-Glycosylflavonoids from the Whole Plants of Setaria faberi Herrmann (가을강아지풀의 C-Glycosylflavone 성분)

  • Kim, Dae Keun
    • Korean Journal of Pharmacognosy
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    • v.47 no.3
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    • pp.222-225
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    • 2016
  • Four flavone compounds were isolated from the whole plants of Setaria faberi Herrmann (Gramineae) through repeated column chromatography. Their chemical structures were elucidated as tricin (1), and three C-glycosylflavone, 2"-O-rhamnosylvitexin (2), 2"-O-rhamnosylscoparin (3), and 2"-O-rhamnosylorientin (4), respectively, by spectroscopic analysis. These compounds were isolated for the first time from this plant.

Phytochemical Constituents of Panicum dichotomiflorum Michaux (미국개기장의 식물화학적 성분)

  • Bae, Jong Jin
    • Korean Journal of Pharmacognosy
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    • v.48 no.4
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    • pp.285-288
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    • 2017
  • A lignan and four flavonoid derivatives were isolated from the aerial parts of Panicum dichotomiflorum Michaux (Gramineae) through repeated column chromatography. Their chemical structures were identified as (-)-pinoresinol (1), tricin (2), luteolin (3), luteolin-4'-O-${\beta}$-D-glucopyranosde (4) and luteolin-7-O-${\beta}$-D-glucopyranosde (5), respectively, by spectroscopic analysis. These compounds were isolated for the first time from this plant.

Crystal Growth and Spectroscopic Investigation of Yb,Er:$YCa_4O{(BO_3)}_3$ for 1.55$\mu m$ Laser

  • Jeong, Suk-Jong;Yu, Young-Moon
    • Proceedings of the Optical Society of Korea Conference
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    • 1999.08a
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    • pp.220-221
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    • 1999
  • Single crystals of Yttrium Calcium Oxyborate (YCOB) doped with different concentrations of Er3+ and Yb3+ ions were growth by Czochralski method. High qualities of crystals in morphology and transparency were obtained . Analysis on crystal structure and lattice parameters were performed by X-ray diffraction method. It was found that congruent melting composition is YCA4.2O1.2(BO3)3. Absorption and fluorescence properties of grown crystals were also reported.

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Pentacyclic Triterpenoids from Ilex macropoda

  • Kim, Dae-Keun;Nam, Il-Yong;Kim, Jin-Wook;Shin, Tae-Yong;Lim, Jong-Pil
    • Archives of Pharmacal Research
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    • v.25 no.5
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    • pp.617-620
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    • 2002
  • Six compounds were isolated from the twigs of Ilex macropoda. Their structures were elucidated as betulinic acid, lupeol, betulone, betulin, erythrodiol and 11-oxo-erythrodiol by physicochemical and spectroscopic analysis. Among them, lupeol, betulone, erythrodiol and 11-oxo-erythrodiol were isolated for the first time from this plant.

Positron Annihilation Lifetime Spectroscopic Analysis to Demonstrate Flux-Enhancement Mechanism of Aromatic Polyamide Reverse Osmosis Membranes (양전자 소멸시간 분광분석을 통한 방향족 폴리아미드 역삼투 분리막의 수투과 향상 메커니즘 제시)

  • Kim, Sung-Ho;Kwak, Seung-Yeop
    • Proceedings of the Membrane Society of Korea Conference
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    • 2004.05b
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    • pp.82-85
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    • 2004
  • Flux-enhancement mechanism of thin-film-composite (TFC) membranes for the reverse comosis (RO) process was newly explained by positron annihilation lifetime spectroscopy (PALS) that has been found to be applied for detecting molecular vacancies or pores having sizes that are equivalent to salt or hydrate ions in RO membrane.(omitted)

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New Synthetic Method of Perfluoro-Silanes for the Stable Electrolyte of Lithium Ion Battery Application

  • Koh, Kyungkuk;Sohn, Honglae
    • Journal of Integrative Natural Science
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    • v.10 no.3
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    • pp.171-174
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    • 2017
  • Non-hydrolyzable fluorinated organosilicon compounds as an eletrolyte for the application of lithium-ion batteries (LIB) are synthesized. New synthetic method for the perfluorinated organosilicon compound containing spacer such as ethyl and propyl group with cyano moiety instead of ethylene glycol to prevent hydrolysis and to promote conductivity are developed in one pot reaction with moderately high yield. Air-sensitive boron trifluoride etherate is no longer required in this reaction. The products are characterized by spectroscopic analysis.

Structural and Spectral Characterization of a Chromium(III) Picolinate Complex: Introducing a New Redox Reaction

  • Hakimi, Mohammad
    • Journal of the Korean Chemical Society
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    • v.57 no.6
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    • pp.721-725
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    • 2013
  • Reaction between 2-pyridinecarboxylic acid (Hpic) and $K_3[Cr(O_2)_4]$ give complex $[Cr(pic)_3].H_2O$ (1) which is characterized by elemental analysis and spectroscopic methods (FT-IR, Raman) and X-ray crystallography. In the crystal structure of 1, chromium atom with coordinated by three nitrogen and three oxygen atoms has a distorted octahedral geometry. Also a water molecule is incorporated in crystal network. Each water molecule acts as hydrogen bond bridging and connects two adjacent complexes by two $O-H{\cdots}O$ hydrogen bonds.