• Journal of the Korean Chemical Society
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• v.54 no.5
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• pp.515-522
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• 2010

A relation between antimicrobial activities and the formation constants of solid complexes of Cu(II), Ni(II), Co(II), Mn(II) and Fe(III) with tridentate Schiff base ligand, 4-hydroxy-3(1-{2-(benzylideneamino)-phenylimino}-ethyl)-6-methyl-2Hpyran-2-one (HL) derived from o-phenylene diamines, dehydroacetic acid (DHA) and p-chloro benzaldehyde have been studied. The ligand and metal complexes were characterized by elemental analysis, conductivity, magnetic susceptibility, thermal analysis, X-ray diffraction, IR, $^1H$-NMR, UV-vis and mass spectra. From the analytical data, the stiochiometry of the complexes was found to be 1:2 (metal:ligand) with octahedral geometry. The molar conductance values suggest the nonelectrolytic nature of metal complexes. The X-ray diffraction data suggests monoclinic crystal system for Ni(II) and orthorhombic crystal system for Cu(II) and Co(II) complexes. The IR spectral data suggest that the ligand behaves as tridentate ligand with ONN donor atoms sequence towards central metal ion. Thermal behavior (TG/DTA) and kinetic parameters calculated by Coats-Redfern method suggests more ordered activated state in complex formation. The protonation constants of the complexes were determined potentiometrically in THF:water (60:40) medium at $25^{\circ}C$ and ionic strength ${\mu}=0.1\;M$ ($NaClO_4$). Antibacterial activities in vitro were performed against Staphylococcus aureu and Escherichia coli. Antifungal activities were studied against Aspergillus Niger and Trichoderma. The effect of the metal ions and stabilities of complexes on antimicrobial activities are discussed.

• Journal of Digital Convergence
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• v.13 no.5
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• pp.337-344
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• 2015

Medicinal plants containing wellness-fusion-complex compound are increasingly being pursued as suitable alternative sources of various biological properties. In this study, inhibitory effect of Quintinia acutifolia, which is a New Zealand plant, on P388 murine lymphocytic leukemia cells using MTT [3-(4,5-dimethylthiazol-2-yl)- 2,5-diphenyl-tetrazolium bromide] assay. Based on $^1H-NMR$, $^{13}C-NMR$ spectral data and other spectral analysis, 2,3,2'',3''-tetrahydroochanaflavone (1) and 2'',3''-dihydroochana-flavone (3) inhibited the leukemia cells were purified from the plants. 2,3,2'',3''-tetrahydroochanaflavone (1) and 2'',3''-dihydroochana-flavone (3) are biflavonoids possessing two basic flavonoids and actively inhibited growth of P388 murine lymphocytic leukemia cells with a 50% inhibitory concentration ($IC_{50}$) of $8.2{\mu}g/mL$ and $3.1{\mu}g/mL$, respectively. Specially, 2'',3''-dihydroochana-flavone (3) possessed unconjugated flavonone system, which isn't consist of a pair with B ring of 2,3,2'',3''-tetrahydroochanaflavone (1). Therefore, the two compounds could be considered as a candidate for development of anticancer drugs and need to much studies in the future.

• Journal of Life Science
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• v.27 no.12
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• pp.1500-1506
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• 2017

Plants are reservoirs of naturally occurring chemical compounds and of structurally diverse bioactive molecules. The aim of this investigation was to screen for the presence of phytochemicals responsible for the lipolysis activity in mulberry (Morus alba) leaves, which are important in traditional Asian medicinal plants. Powdered mulberry leaves were extracted with hexane, ethyl acetate, and methanol. Daucosterol was isolated from the EtOAc extract of mulberry leaves, and its structure was elucidated by NMR spectral analyses. The NMR assignments for the compound were determined using $^1H$, $^{13}C$, DEPT, COSY, HSQC, and HMBC NMR spectral data. Daucosterol showed a concentration-dependent lipolysis activity that may impart medicinal properties that can be exploited by medical practitioners for the treatment of various diseases. However, further studies should be conducted to elucidate additional mechanisms of daucosterol.

• Korean Journal of Remote Sensing
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• v.37 no.3
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• pp.559-566
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• 2021

It is necessary to quickly detect and respond to ship accidents that occur continuously due to the influence of the recently increased maritime traffic. For this purpose, ship detection research is being actively conducted based on satellite images that can be monitored in real time over a wide area. However, there is a possibility that the wake may be falsely detected as a ship because the wake removal is not performed in previous studies that performed ship detection using spectral characteristics. Therefore, in this study, ship detection was performed using SDI (Ship Detection Index) based on the Sentinel-2A satellite image, and the wake was removed by utilizing the difference in the spectral characteristics of the ship and the wake. Probability of detection (POD) and false alarm rate (FAR) indices were used to verify the accuracy of the ship detection algorithm in this study. As a result of the verification, POD was similar and FAR was improved by 6.4% compared to the result of applying only SDI.

• Journal of the Korean Society of Marine Environment & Safety
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• v.28 no.4
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• pp.667-679
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• 2022

Fatigue damage analysis of ships includes parameters considering operational factors. Due to these operational variables, there is a difference between the fatigue damage estimated during the design stage and the actual accumulated fatigue damage. Likewise, there are various loading conditions for the real container ships, but at design stage the fatigue damage is calculated by applying the representative loading conditions. Moreover, although the difference in fatigue damages is expected when the actual and design loading conditions are applied, there are few studies on the contributions of the fatigue damage based on the loading conditions of container ships. In this paper, fatigue contributions were investigated from various cargo weight distributions. The hull girder loads calculated through seakeeping analysis and fatigue damages obtained by performing spectral fatigue analysis were identified under new loading conditions. As a result, it was found that the variation of cargo weight distribution in the container ship brought about changes in the hull girder loads and fatigue damage by affecting the hull girder stress.

• Korean Journal of Remote Sensing
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• v.39 no.3
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• pp.311-323
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• 2023

Oil spill accidents can cause various environmental issues, so it is important to quickly assess the extent and changes in the area and location of the spilled oil. In the case of oil spill detection using satellite imagery, it is possible to detect a wide range of oil spill areas by utilizing the information collected from various sensors equipped on the satellite. Previous studies have analyzed the reflectance of oil at specific wavelengths and have developed an oil spill index using bands within the specific wavelength ranges. When analyzing multiple images before and after an oil spill for monitoring purposes, a significant amount of time and computing resources are consumed due to the large volume of data. By utilizing Google Earth Engine, which allows for the analysis of large volumes of satellite imagery through a web browser, it is possible to efficiently detect oil spills. In this study, we evaluated the applicability of four types of oil spill indices in the area of various land cover using Sentinel-2 MultiSpectral Instrument data and the cloud-based Google Earth Engine platform. We assessed the separability of oil spill areas by comparing the index values for different land covers. The results of this study demonstrated the efficient utilization of Google Earth Engine in oil spill detection research and indicated that the use of oil spill index B ((B3+B4)/B2) and oil spill index C (R: B3/B2, G: (B3+B4)/B2, B: (B6+B7)/B5) can contribute to effective oil spill monitoring in other regions with complex land covers.

• Korean Journal of Mineralogy and Petrology
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• v.37 no.2
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• pp.13-22
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• 2024

X-ray absorption near-edge structure (XANES) spectroscopy can provide qualitative insights into the coordination chemistry of calcium (Ca) across a variety of geological materials. However, systematic studies on Ca K-edge XANES spectral features and the Ca coordination parameters are rare. This study investigated potential correlations between the spectral features of Ca K-edge XANES and the coordination parameters of Ca for selected Ca-bearing minerals (anorthite, aragonite, calcite, diopside, dolomite, grossular, monohydrocalcite, perovskite, and wollastonite), employing density functional theory (DFT) calculations. DFT calculations accurately reproduced the main features of their experimental Ca K-edge XANES spectra for representative silicates, carbonates, and titanates. No strong correlation was observed between XANES peak positions vs. Ca-O distances (or Ca coordination numbers). However, a significant correlation was noted between the peak intensity of post-edge peaks vs. the effective coordination number of Ca in minerals of similar chemical compositions. These results show the potential, yet limited, applicability of XANES spectra for molecular-level research of Ca-bearing geomaterials, and highlight the critical role of DFT computations in interpretating XANES spectra.

• Journal of the Institute of Electronics and Information Engineers
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• v.52 no.1
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• pp.7-16
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• 2015

The transmitter of quadrature multiplexed GMSK (QM-GMSK) is composed of two quadrature multiplexed GMSK modulators. QM-GMSK has a slightly increased spectrum main lobe compared with $Q^2PSK$ or QMSK, but it has highly suppressed side lobes. As a result, practical spectrum efficiency of QM-GMSK is achieved. By replacing the baseband elementary pulses of QM-GMSK with their approximate, the squared sinusoid of half-period, offset-$Q^2PSK$($OQ^2PSK$) is obtained. The $OQ^2PSK$ signal has similar spectral properties to QM-GMSK. The transmitter of $OQ^2PSK$ can be simply implemented without the Gaussian lowpass filter, which is required in QM-GMSK transmitter. In this paper, we propose an overlapped pulse shaping in $OQ^2PSK$ with RC(raised-cosine) or SRC(squared raised-cosine) pulses of length longer than the symbol period. Power spectrum of the proposed modulation scheme exhibits further suppressed side lobes, hence enhanced spectrum efficiency is obtained. Simulation results indicate that BER performance of the proposed scheme is comparable to that of $OQ^2PSK$.

• Journal of the Korean Association of Geographic Information Studies
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• v.7 no.4
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• pp.77-87
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• 2004

It is important for hydrographers to extract the accurate cross section of a river for the hydrographical analysis of the topography. Aerial photographs were used to extract the cross section of a river for the advantages of the accuracy and economical efficiency in this study, while the direct measurement has been used in existing studies. An ortho-rectified photo map using imageries taken by the PKNU 2 (High-resolution, multi-spectral, aerial photographic system developed by our laboratory) was generated using the surveyed data and a digital map. The cross section of a river that was obtained from the ortho-rectified by the surveyed Kinematic data of GPS was compared with the result using ImageStation stereo-plotter of corp. Z/I Imaging. As a result of this study, the RMSE in the ortho-rect process using the surveyed GPS data was lowered as from 5.5788 pixels (about 2m) to 2.84 (about 1m) in comparison with it in the process using a digital map. The surveyed kinematic GPS in extraction of the cross section of a river was excellent as 6.6cm of the planimetric and precision in the confidence level of 95%. The correlation coefficient between the result from the using stereo-plotter and the extraction of cross section of a river using aerial photos was 0.8 hydrographical acquisition of it using PKNU 2 imagery will be possible.

• Journal of the Korean Chemical Society
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• v.55 no.4
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• pp.594-602
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• 2011

The effect of ${\alpha}$-, ${\beta}$- and ${\gamma}$-picolines on the stereochemistry of the coordination compounds of lanthanide(III) nitrates derived from 4[N-(furfural)amino]antipyrine semicarbazone (FFAAPS) has been studied. The general composition of the present coordination compounds is [Ln(FFAAPS)$(NO_3)_3$Pic] (Ln=La, Pr, Nd, Sm, Gd, Tb, Dy or Ho and Pic=${\alpha}$-, ${\beta}$- or ${\gamma}$-picolines). All these coordination compounds have been characterized by elemental analyses, molecular weight, molar conductance, magnetic susceptibility, infrared and electronic spectra. The infrared studies suggest that the FFAAPS behaves as a neutral tridentate ligand with N, N, O donor while ${\alpha}$-, ${\beta}$- or ${\gamma}$-picoline is coordinated to the lanthanide(III) ions via heterocyclic N-atom. Nitrates are bicovalently bonded in these compounds. From the electronic spectral data, nephelauxetic effect (${\beta}$), covalence factor ($b^{1/2}$), Sinha parameter (${\delta}%$) and the covalence angular overlap parameter (${\eta}$) have been calculated. Thermal stabilities of these complexes have been studied by thermogravimetric analysis. The coordination number of lanthanide(III) ions in the present compound is found to be ten. The antibacterial studies screening of the primary ligand FFAAPS and the complexes showed that the present complexes have moderate antibacterial activities.