• Title/Summary/Keyword: Spectral studies

Search Result 691, Processing Time 0.03 seconds

Synthesis of New Triazolyl-N,N-Dialkyldithiocarbamates as Antifungal Agents

  • Ozkirimli Sumru;Apak T. Idil;Kiraz Muammer;Yegenoglu Yildiz
    • Archives of Pharmacal Research
    • /
    • v.28 no.11
    • /
    • pp.1213-1218
    • /
    • 2005
  • N,N-Dialkylditihiocarbamate derivatives have been well known as broad-range fungicides. In this study, the triazole derivatives of ten new N,N-disubstituted dithiocarbamates (3a-j) were synthesized and their structures were identified by spectral and elemental analysis. Results of the antifungal activity studies showed that some of the compounds tested were active against M. canis, M. gypseum, and T rubrum at the concentration of 12.5 $\mu$g/mL when c1otrimazol was used as a standard.

다목적 위성 2호 MSC 영상 자료를 위한 검보정 target 준비

  • 이동한;송정헌;김용승
    • Proceedings of the Korean Association of Geographic Inforamtion Studies Conference
    • /
    • 2004.03a
    • /
    • pp.255-259
    • /
    • 2004
  • 본 논문에서는 다목적 위성 2호의 주 탑재체인 MSC (Multi-Spectral Camera)의 영상자료 검보정을 위한 검보정 target 준비 작업에 대해 설명한다. MSC 영상 자료에 대한 검보정 작업은 다목적 위성 2호의 발사 후 초기 운영 기간 (LEOP: Launch and Early Operation Phase)인 3개월 동안 수행될 예정이다. 위성 발사 전까지 MSC 영상 자료에 대한 검보정을 수행하기 위해 필요한 준비 작업들이 현재 한국항공우주연구원에서 진행중이다. LEOP 기간 동안 MSC 영상 자료를 검보정하기 위해서, MSC의 센서 특성에 따라 7가지 정도의 검보정 target에 대한 설계 초안이 완성되었으며, 향후 target에 대한 설계를 완성한 후에 2004년 중에 한 두 부지에 몇 가지 target들을 건설하고, 다목적 위성 2호의 궤도 특성을 고려하여 일부 target은 운반이 가능하도록 제작할 예정이다. 검보정 target이 촬영된 MSC 영상 자료의 분석을 통해, GSD (Ground Sample Distance), Aliasing, Linearity, Edge Slope & Response, MTF (Modulation Transfer Function), FOV & IFOV, Absolute radiometric validation, Position Accuracy 등의 MSC 검보정 요소 값들을 측정할 계획이다.

  • PDF

Standardizing Agriculture-related Land Cover Classification Scheme Using IKONOS Satellite Imagery (IKONOS 영상자료를 이용한 농업관련 토지피복 분류기준 설정 연구)

  • 홍성민;정인균;김성준
    • Proceedings of the Korean Association of Geographic Inforamtion Studies Conference
    • /
    • 2004.03a
    • /
    • pp.261-265
    • /
    • 2004
  • The purpose of this study is to present a standardized scheme for providing agriculture-related information at various spatial resolutions of satellite images including Landsat+ETM, KOMPSAT-1 EOC, ASTER VNIR, and IKONOS panchromatic and multi-spectral images. The satellite images were interpreted especially for identifying agricultural areas, crop types, agricultural facilities and structures. The results were compared with the land cover/land use classification system suggested by Ministry of Construction & Transportation based on NGIS (National Geographic Information System) and Ministry of Environment based on satellite remote sensing data. As a result, high-resolution agricultural land cover map from IKONOS imageries was made out. The results by IKONOS image will be provided to KOMPSAT-2 project for agricultural application.

  • PDF

Synthesis of Some New Biologically Active Benzothiazole Derivatives Containing Benzimidazole and Imidazoline Moieties

  • Chaudhary, Manish;Pareek, Deepak;Pareek, Pawan K.;Kant, Ravi;Ojha, Krishan G.;Pareek, Arun
    • Bulletin of the Korean Chemical Society
    • /
    • v.32 no.1
    • /
    • pp.131-136
    • /
    • 2011
  • Synthesis of N-(1H-benzimidazol-2-yl)-6-substituted-1,3-benzothiazol-2-amines and 6-substituted-N-(4,5-dihydro-1H-imidazol-2-yl)-1,3-benzothiazol-2-amines by the reaction of substituted 2-aminobenzothiazoles with carbon disulphide and methyl iodide followed by the reaction with o-phenylene diamine/ethylene diamine are reported. All the synthesized compounds were characterized by elemental analysis, IR spectra and $^1H$ NMR spectral studies. The potent antibacterial and entomological (antifeedant, acaricidal, contact toxicity and stomach toxicity) activities of the synthesized compounds were investigated.

Synthesis and Characterization of Cobalt(II)/(III), Nickel(II) and Copper(II) Complexes of New 14, 15 and 16-Membered Macrocyclic Ligands

  • El-Tabl, Abdou Saad
    • Bulletin of the Korean Chemical Society
    • /
    • v.25 no.12
    • /
    • pp.1757-1763
    • /
    • 2004
  • A new series of nickel(II), cobalt(II)/(III) and copper(II) complexes of 14, 15 and 16-membered of macrocyclic ligands have been prepared and characterized by elemental analyses, IR, UV-VIS and $^1H-NMR$ spectra, magnetic susceptibilities, conductivities, DTA and ESR measurements. Molar conductances in DMF solution indicate that, the complexes are nonelectrolytes except (9-12) complexes. The electronic spectra show that, all complexes are square planar or distorted octahedral geometry. The ESR spectra of solid complexes (4), (8) and (11) show square planar of axial type symmetry $(d_{x2-y2})$ with considerable covalent bond character. However, complex (12) shows a spectrum of octahedral geometry with $d_{z2}$ ground state. Complex (12) shows exploitation in reducing the amount of electron adducts formed in DNA during irradiation with low radiation products.

Synthesis and Antibacterial Activity of Novel [3-(4-substitutedphenylamino)-8-azabicyclo [3.2.1] oct-8yl]-phenyl-methanone Derivatives

  • Reddy, B. Surendra;Reddy, A. Babul;Reddy, G. Ramachandra;Reddy, P. Raveendra
    • Journal of the Korean Chemical Society
    • /
    • v.55 no.6
    • /
    • pp.969-973
    • /
    • 2011
  • The synthesis, as well as spectroscopic and biological studies of a novel class of [3-(4-substitutedphenylamino)-8-azabicyclo [3.2.1] oct-8yl]-phenyl-methanone derivatives are described. All the synthesized compounds were characterized by elemental analysis FTIR, $^1H$-NMR, $^{13}C$ NMR, and Mass spectral data. All the synthesized compounds were exhibit in vitro antibacterial activity.

Synthesis and Characterization of Transition Metal Complexes with Benzimidazolyl-2-hydrazones of o-anisaldehyde and Furfural

  • Mohapatra, R.K.;Mishra, U.K.;Mishra, S.K.;Mahapatra, A.;Dash, D.C.
    • Journal of the Korean Chemical Society
    • /
    • v.55 no.6
    • /
    • pp.926-931
    • /
    • 2011
  • A series of complexes of the type [$ML_2Cl_2$], where L=2-(o-anisylidene-2'-imino) amino benzimidazole (AIAB) and 2-(furfurylidene imino) amino benzimidazole (FIAB), M=Cu(II), Co(II), Ni(II) and Zn(II), have been synthesized and characterized on the basis of elemental analysis, thermal analysis, molar conductivity, magnetic moment, electronic, infrared, $^1H$-NMR spectral studies. The results are in consistent with bidentate chelation of ligand with azomethine nitrogen and ring nitrogen donors. All these Schiff bases and their complexes have also been screened for their antibacterial (Bacillus subtilis, Bacillus stearothermophilus, Escherichia coli and Salmonella typhi) and antifungal activities (Aspergillus niger and Aspergillus flavus).

Studies on Some Bioactive 1,1-Bis(2-benzylidene-5-aryliden-1,3-thiadiazolidin-4-one)cyclopropane

  • Panwar, Hemant;Chaudhary, Nidhi;Singh, Sachi;Chawla, Amit
    • Journal of the Korean Chemical Society
    • /
    • v.55 no.6
    • /
    • pp.994-999
    • /
    • 2011
  • Some novel heterocyclic derivatives of 1,1-bis(2-phenyl-5-arylidine-1,3-thiadiazolidin-4-one)cyclopropane 4(a-i) have been synthesized from cyclopropane dicarboxylic acid and substituted thiadiazole moieties. All the synthesized compounds have been characterized by elemental and spectral (I.R., $^1H$-NMR, Mass) analysis. Furthermore, above said compounds were screened for their antifungal and antibacterial activities. Compound 4c was found the most potent one which further evaluated for lesser toxicity test.

Dehydrodivanillin: Multi-dimensional NMR Spectral Studies, Surface Morphology and Electrical Characteristics of Thin Films

  • Gaur, Manoj;Lohani, Jaya;Balakrishnan, V.R.;Raghunathan, P.;Eswaran, S.V.
    • Bulletin of the Korean Chemical Society
    • /
    • v.30 no.12
    • /
    • pp.2895-2898
    • /
    • 2009
  • The complete structural characterization of dehydrodivanillin, an important natural product of interest to the food, cosmetics and aroma industries, has been carried out using multi-dimensional NMR spectroscopic techniques, and its previously $reported^{13}$C-NMR values have been reassigned. Dense and granular thin films of dehydrodivanillin have been grown by sublimation under high vacuum and studied using Scanning Electron Microscopy (SEM), electrical and optical techniques. The transmittance spectra of the films indicate a wide optical band gap of more than 3 eV. Typical J-V characteristics of Glass/ITO/dehydrodivanillin/Al structure exhibited moderate current densities ${\sim}10^{-4}\;A/cm^2$ at voltages > 25 V with an appreciable SCLC mobility of the order of $10^{-6}\;cm^2$/V-s.

Design, Synthesis and Antibacterial Activity Studies of Novel Quinoline Carboxamide Derivatives

  • Shivaraj, Yellappa;Naveen, Malenahalli H.;Vijayakumar, Giriyapura R.;Kumar, Doyijode B. Aruna
    • Journal of the Korean Chemical Society
    • /
    • v.57 no.2
    • /
    • pp.241-245
    • /
    • 2013
  • A series of novel quinoline-6-carboxamides and 2-chloroquinoline-4-carboxamides were synthesized by the reaction of their analogous carboxylic acids with various amine derivatives in the presence of base TEA and protecting agent BOP at room temperature. Synthesized compounds were confirmed by spectral characterization viz IR, $^1H$-NMR, and MS. Antibacterial activity carried out against Escherichia coli and Staphyllococcus aureus indicated that the synthesized compounds were active against these microorganisms.