• Title/Summary/Keyword: Specific heat at High Temperature

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Experimental Study on the Physical and Mechanical Properties of a Copper Alloy for Liquid Rocket Combustion Chamber Application (액체로켓 연소기용 구리합금의 열/기계적 특성에 관한 실험적 연구)

  • Ryu, Chul-Sung;Baek, Un-Bong;Choi, Hwan-Seok
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.30 no.11 s.254
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    • pp.1494-1501
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    • 2006
  • Mechanical and physical properties of a copper alloy for a liquid rocket engine(LRE) combustion chamber liner application were tested at various temperatures. All test specimens were heat treated with the condition they might experience during actual fabrication process of the LRE combustion chamber. Physical properties measured include thermal conductivity, specific heat and thermal expansion data. Uniaxial tension tests were preformed to get mechanical properties at several temperatures ranging from room temperature to 600$^{\circ}C$. The result demonstrated that yield stress and ultimate tensile stress of the copper alloy decreases considerably and strain hardening increases as the result of the heat treatment. Since the LRE combustion chamber operates at higher temperature over 400$^{\circ}C$, the copper alloy can exhibit time-dependent behavior. Strain rate, creep and stress relaxation tests were performed to check the time-dependent behavior of the copper alloy. Strain rate tests revealed that strain rate effect is negligible up to 400$^{\circ}C$ while stress-strain curve is changed at 500$^{\circ}C$ as the strain rate is changed. Creep tests were conducted at 250$^{\circ}C$ and 500$^{\circ}C$ and the secondary creep rate was found to be very small at both temperatures implying that creep effect is negligible for the combustion chamber liner because its operating time is quite short.

Structural stability of fire-resistant steel (FR490) H-section columns at elevated temperatures

  • Kwon, In-Kyu;Kwon, Young-Bong
    • Steel and Composite Structures
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    • v.17 no.1
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    • pp.105-121
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    • 2014
  • A fundamental limitation of steel structures is the decrease in their load-bearing capacity at high temperatures in fire situations such that structural members may require some additional treatment for fire resistance. In this regard, this paper evaluates the structural stability of fire-resistant steel, introduced in the late 1999s, through tensile coupon tests and proposes some experimental equations for the yield stress, the elastic modulus, and specific heat. The surface temperature, deflection, and maximum stress of fire-resistant steel H-section columns were calculated using their own mechanical and thermal properties. According to a comparison of mechanical properties between fire-resistant steel and Eurocode 3, the former outperformed the latter, and based on a comparison of structural performance between fire-resistant steel and ordinary structural steel of equivalent mechanical properties at room temperature, the former had greater structural stability than the latter through $900^{\circ}C$.

메탄 하이드레이트의 부존 가능성과 평형조건

  • 류병재;허대기;선우돈;정태진;김현태;김세준;이호섭
    • 한국석유지질학회:학술대회논문집
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    • spring
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    • pp.56-65
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    • 1998
  • Methane hydrate is ice-like solid compound consisting of mainly methane and water, and is stable under specific low temperature and high pressure conditions (HSZ : methane hydrate stability zone) that occurs in permafrost regions and in the ocean floor sediments. Geophysical survey was implemented in the southern area of the East Sea, and the HSZ of the study area is determined by the temperature, pressure and local heat flow obtained from the survey and well data. In the study area, methane hydrates could exist in the sediments below the water depths of about $300{\cal}m$, and the base of HSZ is about 600m beneath the seafloor. The acoustically blanking zones in the sediment and phenomena of gas seepage were detected from the seismic section. These sediments have the sufficient physical condition for the formation of methane hydrate. The temperature and pressure conditions were experimentally measured for the dissociation of methane and propane hydrates in Pure water. Equilibrium conditions of methane and propane hydrates were obtained in the pressure range up to 19050Kpa and 401.3Kpa. Under same temperature condition, propane hydrate was dissociated at lower pressure than that of methane hydrate.

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Effects of Turbine Inlet Temperature on Performance of Regenerative Gas Turbine System with Afterfogging

  • Kim, Kyoung-Hoon;Kim, Se-Woong;Ko, Hyung-Jong
    • International Journal of Air-Conditioning and Refrigeration
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    • v.17 no.4
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    • pp.141-148
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    • 2009
  • Afterfogging of the regenerative gas turbine system has an advantage over inlet fogging in that the high outlet temperature of air compressor makes the injection of more water and the recuperation of more exhaust heat possible. This study investigates the effects of turbine inlet temperature (TIT) on the performance of regenerative gas turbine system with afterfogging through a thermodynamic analysis model. For the standard ambient conditions and the water injection ratios up to 5%, the variation of system performance including the thermal efficiency is numerically analyzed with respect to the variations of TIT and pressure ratio. It is also analyzed how the maximum thermal efficiency, net specific work, and pressure ratio itself change with TIT at the peak points of thermal efficiency curve. All of these are found to increase almost linearly with the increases of both TIT and water injection ratio.

Wet Chemical Preparation of Li-rich LiMn$_2$O$_4$ Spinel by Oxalate Precipitation (Oxalate 침전을 이용한 Li-과량 LiMn$_2$O$_4$ Spinel의 습식합성가 분말 특성)

  • 이병우;김세호
    • Journal of the Korean Ceramic Society
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    • v.36 no.7
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    • pp.698-704
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    • 1999
  • Li rich Li1+xMn2-xO4(x=0.07) spinel powders were prepared by an oxalate precipitation of wet chemical methods at temperature lower than $600^{\circ}C$. The FTIR results showed that the powders prepared at $600^{\circ}C$ had high degree of crystal quality comparing with the spinel powders prepared by solid state reaction at 75$0^{\circ}C$ which was the lowest synthesis temperature of the solid state reaction method. The particle size of powders prepared by the oxalate precipitation at $600^{\circ}C$ was smaller than 0.2${\mu}{\textrm}{m}$ and the specific surface area was 11.01 m2/g A heat treatment over 90$0^{\circ}C$ formed second phase in the precipitates. It was shown that there were phase transitions at temperatures. T1,T2 and T2. The transitions involved weight loss and gain during heating and cooling. The low temperature synthesis below $600^{\circ}C$ avoided the second phase formation and the prepared powders showed improved compositional and physical properties for secondary lithium battery applications.

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Thermal Steady State in an Anatomical Model of the Human Head under High-Power EM Exposure (고출력 전자기파 노출 환경에서 인체 두부의 온도 변화)

  • Kim, Woo-Tae;Yook, Jong-Gwan
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.21 no.10
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    • pp.1073-1084
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    • 2010
  • In this paper, the bio-heat equation including thermoregulatory functions is solved for an anatomically based human head model comprised of 14 tissues to study the thermal implications of high-power exposure to electromagnetic(EM) fields due to half-wave dipole antenna both at 835 and 1,800 MHz. The dipole antenna is located at the side of the ear and the front of the eyes. The FDTD method has been used for the SAR computation. When solving the BHE, the thermoregulation function and sweating effetecs are included in order to predict more exact temperature increase. It is noted that an approximately proportional relationship between the tissues and the maximum temperature increase and the antenna power is not maintained when the thermoregulation and sweating effects are fully accounted for under high power exposure.

Electrical Properties of TiN/TiO2/FTO Resistive Random-Access Memory Based on Peroxo Titanium Complex Sol Solution by Heat Treatment (열처리에 따른 Peroxo Titanium Complex 졸 용액 기반 TiN/TiO2/FTO Resistive Random-Access Memory의 전기적 특성)

  • Yim, Hyeonmin;Lee, Jinho;Kim, Won Jin;Oh, Seung-Hwan;Seo, Dong Hyeok;Lee, Donghee;Kim, Ryun Na;Kim, Woo-Byoung
    • Korean Journal of Materials Research
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    • v.32 no.9
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    • pp.384-390
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    • 2022
  • A spin coating process for RRAM, which is a TiN/TiO2/FTO structure based on a PTC sol solution, was developed in this laboratory, a method which enables low-temperature and eco-friendly manufacturing. The RRAM corresponds to an OxRAM that operates through the formation and extinction of conductive filaments. Heat treatment was selected as a method of controlling oxygen vacancy (VO), a major factor of the conductive filament. It was carried out at 100 ℃ under moisture removal conditions and at 300 ℃ and 500 ℃ for excellent phase stability. XRD analysis confirmed the anatase phase in the thin film increased as the heat treatment increased, and the Ti3+ and OH- groups were observed to decrease in the XPS analysis. In the I-V analysis, the device at 100 ℃ showed a low primary SET voltage of 5.1 V and a high ON/OFF ratio of 104. The double-logarithmic plot of the I-V curve confirmed the device at 100 ℃ required a low operating voltage. As a result, the 100 ℃ heat treatment conditions were suitable for the low voltage driving and high ON/OFF ratio of TiN/TiO2/FTO RRAM devices and these results suggest that the operating voltage and ON/OFF ratio required for OxRAM devices used in various fields under specific heat treatment conditions can be compromised.

An Experimental Study on the Physical Properties Model of High Strength Concrete at High Temperature (고온시 고강도 콘크리트의 물리적 특성 모델 설정에 관한 실험적 연구)

  • Kim Heung-Yaul;Seo Chee-Ho;Choi Seng-Kwan;Jeon Hyun-Kyu
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.05b
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    • pp.1-4
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    • 2005
  • This research is to present experimental materials model of high strength concrete for prediction of fire safety of structural members based on physical properties of materials during heating up to 800$^{circ}C$. The following conclusions are drawn from this study. First of all, between 100 to 200 $^{circ}C$, the physical models of concrete such as specific heat and thermal conductivity, show visible degradation, regardless of concrete strength. Second, between 300 to 600$^{circ}C$, the physical models of the 29MPa and 49MPa concrete show degradation continually at these temperatures. Finally, beyond 600$^{circ}C$, the physical models of 49MPa strength concrete show larger degradation than 29MPa strength concrete due to rise of pore pressure and melting of the interface between aggregate and cement paste.

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Effect of Room-temperature, Calcined Eggshell Reactants on Synthesis of Hydroxyapatite

  • Kang, Tea-Sung;Pantilimon, Cristian M.;Lee, Sang-Jin
    • Journal of the Korean Ceramic Society
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    • v.52 no.3
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    • pp.204-208
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    • 2015
  • Synthesis of hydroxyapatite (HA) was attempted through a room-temperature reaction of calcined eggshell with phosphoric acid. Ball-milled, calcined eggshell powder, which has a specific surface area of $31.6m^2/g$, was mixed with various concentrations of phosphoric acid at room temperature. The mixtures showed high reactivity and a vigorous exothermic reaction ; the reacted samples showed both $Ca(OH)_2$ and $CaHPO_4$ crystal phases. After heating at temperatures above $400^{\circ}C$, an HA crystal phase was observed in all samples. The calcined eggshell showed a pure CaO single phase, while the $Ca(OH)_2$ phase was only observed in the wet, ball-milled calcined powder. The degree of formation of the HA crystal phase increased as the phosphoric acid concentration and the heating temperature were increased. A mixture with 50 wt% phosphoric acid concentration showed a well-developed HA crystal phase after heat treatment at $800^{\circ}C$, while the formation of a more intensive amorphous phase was observed in the products of the room-temperature reaction.

A Study on the Measurement of Burnet Gas Temperature in Premized Combustion by Modified Two-Color Method (변형 2색법에 의한 예혼합기 연소의 연소가스온도 측정에 관한 연구)

  • 배명환
    • Transactions of the Korean Society of Automotive Engineers
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    • v.7 no.8
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    • pp.43-54
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    • 1999
  • The effects of equivalence ratio and pressure on burnt gas temperature in premixed fuel rich propane-oxygen-inert gas combustion are investigated over the wide ranges of equivalence ration from 1.5 to 2.7 and pressure from 0.1 to 7 MPa by using a specially designed disk -type constant-voume combustion chamber, The premixtures are simultaneously ignited by eight spark plugs located on the circumference of combustion chamber with 45 degree interals. The eight converging flames compress the end gases to high pressures. The burnt gas temperature is meausured by the nmodifie dtow-colr pyrometry method. The transmissivity in the chamber center during the final stage of combustion at the hightest pressure is meausred by in situ laser extinction method. It is found that a temperature difference between the burnt gas temperature measured by mofidied and conventrational two-color method is 10 to 20 K, but the accuracy of the modified two-color methdo is higher if the local transmissivity in observed region is uniform , and the combustion at higher pressures results gas density conditions and the burnt gas temperature increases as the volume fraction of argon is increased because the specific heat of argon is lower compared to that of nitrogen with a constant equivalence ratio.

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