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Template-free preparation of TiO2 microspheres for the photocatalytic degradation of organic dyes

  • Al Ruqaishy, Mouza;Al Marzouqi, Faisal;Qi, Kezhen;Liu, Shu-yuan;Karthikeyan, Sreejith;Kim, Younghun;Al-Kindy, Salma Mohamed Zahran;Kuvarega, Alex Tawanda;Selvaraj, Rengaraj
    • Korean Journal of Chemical Engineering
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    • v.35 no.11
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    • pp.2283-2289
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    • 2018
  • $TiO_2$ microspheres were successfully synthesised by simple solution phase method by using various amount of titanium butoxide as precursor. The prepared $TiO_2$ were characterized by X-ray diffraction (XRD), UV-vis diffuse reflectance absorption spectra (UV-DRS), X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM). XRD analysis revealed that the as-synthesized $TiO_2$ microsphere poses an anatase phase. The photocatalytic degradation experiments were carried out with three different dyes, such as methylene blue, brilliant black, reactive red-120 for four hours under UV light irradiation. The results show that $TiO_2$ morphology had great influence on photocatalytic degradation of organic dyes. The experimental results of dye mineralization indicated the concentration was reduced by a high portion of up to 99% within 4 hours. On the basis of various characterization of the photocatalysts, the reactions involved to explain the photocatalytic activity enhancement due to the concentration of titanium butoxide and morphology include a better separation of photogenerated charge carriers and improved oxygen reduction inducing a higher extent of degradation of aromatics.

Smelting of Platinum Group Metals and Recycling of Spent Catalyst (백금족 금속의 제련과 폐촉매의 리사이클링)

  • Son, Injoon;Sohn, Ho-Sang
    • Resources Recycling
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    • v.30 no.3
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    • pp.18-29
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    • 2021
  • Platinum group metals (PGMs) are used in a wide range of application fields such as catalysts, electronic devices, electrodes, electrical devices, fuel cells and high temperature materials due to their excellent electrical and thermal conductivity as well as chemical resistivity. Platinum group elements are generally associated with nickel-copper sulfides in magmatic rocks. Depending on the relative concentrations of the PGMs, they are produced either as the primary products or as by-products of the nickel and copper. However, PGMs natural resource deposits are strictly limited in countries such as South Africa and Russia. The annual supply of PGMs is only under 500 t. Considering the limited supply of PGMs, there will be a noticeable increase in the supply risk associated with PGMs in the near future. Therefore, it is extremely important to recover PGMs from secondary resources such as spent catalysts. This paper reviews on overview of PGMs extraction and recycling processes.

New Record for Alien Plant, Urtica dioica L. (Urticaceae) in Korea (한반도 미기록 외래식물: 서양쐐기풀)

  • Sim, Sunhee;Kim, Jin-Seok;Jin, Dong-Pil;Lee, Woong;Hyun, Chang Woo;Kim, Jung-Hyun
    • Korean Journal of Plant Resources
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    • v.35 no.1
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    • pp.100-108
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    • 2022
  • We found Urtica dioica L., an unrecorded alien plant, in the Han River basin of Korea. U. dioica is considered to be native to Europe, much of temperate Asia and western North Africa. This plant has been introduced to many other parts of the world. In Particularly, it reported as an invasive species from East Asia (Japan), Oceania and South America. This species is distinguished from related Korean taxa of the genus by its unisexual flower and dioecious plant species. In the Neighbor-Joining tree, U. dioica samples from the Han River Park (Sangam-dong, Mapo-gu, Seoul) and Yangjaecheon Stream (Daechi-dong, Gangnam-gu, Seoul) clustered into a clade consisting of a U. dioica s.s. Here, we provide a precise description, illustrations, a key to the related taxa, and photographs of its habitat.

Analysis of Structural Changes in Container Volume of Gwangyang Port (광양항 컨테이너물동량의 구조적 변화추이분석)

  • Kim, Seung-Chul;Kang, Hyo-Won
    • Journal of Korea Port Economic Association
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    • v.38 no.4
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    • pp.171-185
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    • 2022
  • This study conducted a comparative analysis by period and route through a variation allocation analysis with domestic container ports to analyze the change structure of container volume at Gwangyang Port. As a result of analysis of the absolute volume of container traffic at Gwangyang Port, the period and routes that showed the highest growth values by period and route were Europe, North America, Middle East, and South America in 2001-2007. It was followed by Southeast Asia, Oceania, Far East Asia, Europe, and Japan during the 2008-2012 period. Among the sections from 2018 to 2022, there are Oceania and Southwest Asia. In order to secure container shipments at Gwangyang Port in the future, it is essential to secure routes in Europe, the Americas, and Africa, and it is necessary to secure port competitiveness through improved management and service of container terminal operators

The timing of unprecedented hydrological drought under climate change

  • Yusuke Satoh;Hyungjun Kim
    • Proceedings of the Korea Water Resources Association Conference
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    • 2023.05a
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    • pp.48-48
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    • 2023
  • The intensified droughts under climate change are expected to threaten stable water resource availability. Droughts exceeding the magnitude of historical variability could occur increasingly frequently under future climate conditions. It is crucial to understand how drought will evolve over time because the assumption of hydrological stationarity of the past decades would be inappropriate for future water resources management. However, the timing of the emergence of unprecedented drought conditions under climate change has rarely been examined. Here, using multimodel hydrological simulations, we investigate the changes in the frequency of hydrological drought (defined as abnormally low river discharge) under high and low greenhouse gas concentration scenarios and with existing water resources management and estimate the timing of the first emergence of unprecedented regional drought conditions that persist for over several consecutive years. This new metric enables a new quantification of the urgency of adaptation and mitigation with regard to drought under climate change. The times are detected for several sub-continental-scale regions, and three regions, namely, southwestern South America, Mediterranean Europe, and northern Africa, exhibit particularly robust and earlier critical times under the high-emission scenario. These three regions are expected to confront unprecedented conditions within the next 30 years with a high likelihood, regardless of the emission scenarios. In addition, the results obtained herein demonstrate the benefits of the lower-emission pathway in reducing the likelihood of emergence. The Paris Agreement goals are shown to be effective in reducing the likelihood to the unlikely level in most regions. Nevertheless, appropriate and prior adaptation measures are considered indispensable to when facing unprecedented drought conditions. The results of this study underscore the importance of improving drought preparedness within the considered time horizons.

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Southeast Asia as Theoretical Laboratory for the World

  • Salemink, Oscar
    • SUVANNABHUMI
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    • v.10 no.2
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    • pp.121-142
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    • 2018
  • Area studies are sometimes framed as focused on specific localities, rooted in deep linguistic, cultural and historical knowledge, and hence empirically rich but, as a result, as yielding non-transferable/non-translatable findings and hence as theoretically poor. In Europe and North America some social science disciplines like sociology, economics and political science routinely dismiss any reference to local specifics as parochial "noise" interfering with their universalizing pretensions which in reality obscure their own Euro-American parochialism. For more qualitatively oriented disciplines like history, anthropology and cultural studies the inherent non-universality of (geographically constricted) area studies presents a predicament which is increasingly fought out by resorting to philosophical concepts which usually have a Eurocentric pedigree. In this paper, however, I argue that concepts with arguably European pedigree - like religion, culture, identity, heritage and art - travel around the world and are adopted through vernacular discourses that are specific to locally inflected histories and cultural contexts by annexing existing vocabularies as linguistic vehicles. In the process, these vernacularized "universal" concepts acquire different meanings or connotations, and can be used as powerful devices in local discursive fields. The study of these processes offer at once a powerful antidote against simplistic notions of "global"/"universal" and "local," and a potential corrective to localizing parochialism and blindly Eurocentric universalism. I develop this substantive argument with reference to my own professional, disciplinary and theoretical trajectory as an anthropologist and historian focusing on Vietnam, who used that experience - and the empirical puzzles and wonder encountered - in order to develop theoretical interests and questions that became the basis for larger-scale, comparative research projects in Japan, China, India, South Africa, Brazil and Europe. The subsequent challenge is to bring the results of such larger, comparative research "home" to Vietnam in a meaningful way, and thus overcome the limitations of both area studies and Eurocentric disciplines.

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Mapping Publication Pattern in African Journal of Library, Archives and Information Science, 2009-2018: An Informetric Study

  • Amusan, Blessing Babawale;Adeyoyin, Samuel Olu
    • International Journal of Knowledge Content Development & Technology
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    • v.12 no.1
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    • pp.17-34
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    • 2022
  • This informetrics study was conducted to find out the distribution of articles and authors that published in African Journal of Library, Archives and Information Studies [AJLAIS]) from 2009 to 2018; considering the year-wise growth of research articles; authorship pattern and collaboration ratio; subject and geographical distributions of authors; and authors' productivity level. A descriptive informetrics research design was adopted. Quota sampling technique was used to select all the articles published within the ten-year period. Data collected through a self-designed checklist was analyzed using frequency count and percentage. The findings revealed that 141 articles, contributed by 266 authors were published by AJLAIS during the period. An annual average growth of 1.20% was recorded. Overall year-wise authorship pattern revealed that majority of articles (62.41%) published in AJLAIS were multiple authored. Also, articles on Informetrics and ICT dominated the journal. Some subject areas not covered were identified such as: indexing and serial collections management. Average collaborative index across the 10-year period for the journal was 0.62. South Africa and Nigeria were the two major prolific contributors to AJLAIS, just as evidence-based research papers of survey type (65.25%) were the most common to the journal. There should be increased numbers of articles in each edition over the coming years, and awareness should be created by the publishers to familiarize the researchers with the publishing requirements of the journal. Also, LIS researchers should concentrate more on areas usually left untouched by previous studies. The study is original as no other similar study was found on publication pattern of articles in AJLAIS covering a ten year period of 2009-2018. The findings of the study will also serve as a feedback mechanism for the Publisher of the Journal and LIS researchers on how to improve the journal and LIS research in general.

Exserohilum turcicum (Northern Corn Leaf Blight) Severity on Maize Hybrids and the Associated Crop Performance in O.R. Tambo District, Eastern Cape, South Africa

  • Mxolisi Mtyobile;Silindile Miya
    • Research in Plant Disease
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    • v.29 no.2
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    • pp.137-144
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    • 2023
  • Exserohilum turcicum is a fungus that causes northern corn leaf blight (NCLB) and has deleterious effects on maize production globally. Therefore, it is prudent to mitigate the effects of NCLB using genetic diversity. The objective of this research was to assess the severity of NCLB disease on the growth and yield of various maize genotypes. A randomized complete block design field experiment, replicated three times, was conducted to evaluate the effect of E. turcicum on 10 maize hybrids. Percent disease index, plant height, and leaf area were recorded at the silk stage. Cob weight, grain fresh weight, and grain yields were determined at harvest maturity. All measured parameters were significantly different (P<0.05) between the maize hybrids. Of the 10 genotypes, four (PAN 4R-528R, PAN 4R-728BR, PAN 3R-724BR, and P1788BR) were susceptible, five (DKC74-74BR, PAN 5R-582R, PAN 5R-890R, PAN 5R-854R, and PAN 5R-590R) were moderately susceptible, and one (DKC80-40BR) was moderately resistant. DKC80-40BR exhibited greater cob weight, while DKC74-74BR was superior in all other plant growth and yield components. Interestingly, although not significant (P>0.05) and high, maize growth and yield parameters had negative correlations with disease incidence, except for grain fresh weight. Therefore, DKC80-40BR may be selected for cultivation in areas prone to NCLB to reduce maize susceptibility to the disease, while DKC74-74BR may improve crop performance. These hybrids could be considered as potential sources of resistance or tolerance to NCLB for further validation by plant breeders.

β-Carotene, Cucumisin Content and Fruit Morphology of Melon (Cucumis melo) Germplasm Collection

  • Hyungjun Noh;Ae-Jin Hwang;Jae-Jong Noh;Bum-Soo Hahn;On-Sook Hur;Na-Young Ro;Jae-Eun Lee;Bit-Sam Kim;Ju-hee Rhee;Jung Yoon Lee;Ji Hyun Kim;Awraris Debie Assefa;Tania Afroz;Myung-kon Kim
    • Proceedings of the Plant Resources Society of Korea Conference
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    • 2021.04a
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    • pp.48-48
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    • 2021
  • This study was carried out to investigating quality and nutritional traits of melon genetic resources. It could provide important baseline data in breeding for increased β-Carotene, cucumisin content thereby increasing the marketability of melon. To this end, we have examined some fruit morphological traits and β-Carotene, cucumisin content of 163 genetic resources. The morphological characters were recorded on the field and inside laboratory and nutritional contents for β-carotene, cucumisin was measured using spectrophotomertic and HPLC methods. Melon fruits have shown a diverse morphological characters. Green and white is dominant for fruit skin color and round and oval-shape is dominant for form in the entire collections. The β-carotene content varied between 0.5 and 233.6mg/kg, 0.7 and 226.5mg/kg, 0.4 and 189.0 mg/kg using UV-Vis and microplated reader instruments, HPLC respectively. The high β-carotene contents were characterized five melon fruit originated from South Africa, Uzbekistan, Albania, France. The cucumisin content varied between 0.3 and 33.5 unit/mg, 0.29 and 32.1unit/mg using UV-Vis and microplated reader instruments, respectively.

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The impact of different shapes of aggregate and crumb rubber on the deformation properties of asphalt concrete

  • Felix N. Okonta;Koketso Tshukutsoane;Babak Karimi
    • Geomechanics and Engineering
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    • v.36 no.1
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    • pp.39-50
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    • 2024
  • Bitumen and high-quality subangular aggregates, the two principal materials used for asphalt concrete construction, are finite and expensive materials. The general availability of crumb rubber and naturally occurring aggregates of different shapes, especially flat and elongated shapes, indicates that they are feasible alternative materials for expanding the volume of bitumen and utilizing a wider range of aggregate shapes for the development of asphalt concrete, with an associated environmental benefit. The study investigated the effect of adding up to 15% crumb rubber and aggregates sorted into different groups, i.e., rounded, elongated, flat, and their combinations, on the rheological and mechanical properties and durability of 50/70 of hot-mix asphalt pavement. The addition of crumb rubber decreased ductility and penetration but increased the softening point. For a 5.5% bitumen content, asphalt concrete briquettes consisting of 7% crumb rubber and three types of aggregate shapes, i.e., 100% rounded, a mix of 75% rounded and 25% elongated, and a mix of 75% rounded, 15% elongated and 10% flat, were associated with high Marshall stability and indirect tensile strength as well as low lateral deformation due to their high solidity and moderate angularity ratio. Also, the addition of 7% crumb rubber resulted in a significant improvement in the tensile strength ratio and rebound strain of briquettes consisting of 75% rounded and 25% elongated aggregates and those with 75% rounded, 15% elongated and 10% flat aggregates. In relation to the parameters investigated, the three groups of briquettes met some of the local (South Africa) requirements for the surface course and base course of low traffic volume roads.