• 한국음향학회지
• /
• 제40권5호
• /
• pp.408-416
• /
• 2021

초음파 분산에 있어서 초음파의 방사면이 시료에 직접 닿는 것을 피하기 위해 액체시료는 유리용기에 의해 분리되어 음향매질에 의해 초음파 에너지를 받는다. 이와 같이 다층구조로 이루어진 음향시스템에서 초음파에너지의 전달효율은 중요한 요소이다. 본 연구에서는 다층구조로 이루어진 음향시스템에 있어서 프로필렌글리콜 용액을 액체정합층으로 사용하여 초음파에너지 전달효율을 개선하는 방법을 제안하였다. 제안된 방법에서는 란주반형 초음파 트랜스듀서와 루미놀용액과의 사이에 프로필렌글리콜 용액을 액체정합층 매질로 채우고, 초음파트랜스듀서로부터 방사되는 강력초음파의 비선형현상에 의해 발광되는 루미놀용액의 발광정도를 광전증폭관을 이용하여 관측하여 루미놀용액으로의 초음파에너지 전달 효율을 조사하였다. 프로필렌글리콜 농도변화에 따른 초음파에너지 전달정도를 측정하였고, 그 결과 프로필렌글리콜 용액의 농도가 증가함에 따라 정합효과는 증가하는 반면 음향감쇠가 증가함을 알 수 있었다. 이들 두 상충되는 조건이 절충되는 최적의 농도가 존재함을 확인할 수 있었으며, 프로필렌글리콜 용액의 최적 농도를 실험적으로 결정할 수 있었다.

• Bulletin of the Korean Chemical Society
• /
• 제31권2호
• /
• pp.327-330
• /
• 2010

$LiCoO_2$, a cathode material for lithium rechargeable batteries, was prepared in a nanoscale through a simple sonochemistry. First, $Co_3O_4$ nanoparticles were prepared by reacting NaOH and $CoCl_2$ or $CoSO_4$ with a sonochemical method, operated at 20 kHz and 220 W for 20 min, very powerful multibubble sonoluminescence conditions for chemical reactions. Second, LiOH was coated onto the $Co_3O_4$ nanoparticles by the same method as above. Finally, $LiCoO_2$ nanoparticles of about 10~30 nm size in diameter were obtained by the thermal treatment of the resulting LiOH-coated $Co_3O_4$ nanoparticles at $500^{\circ}C$ for 3 hr. This synthetic process is relatively quite mild and simple compared to the known method for the synthesis of $LiCoO_2$ nanoparticles. The materials synthesized were characterized by infrared spectroscopy, X-ray diffraction, inductively coupled plasma spectrometer, and high resolution-transmission electron microscopy analyses.

• Bulletin of the Korean Chemical Society
• /
• 제35권8호
• /
• pp.2331-2334
• /
• 2014

$Cu_2SnSe_3$ (CTSe) and $Cu_2ZnSnSe_4$ (CZTSe) nanoparticles were synthesized by sonochemical reactions under multibubble sonoluminescence (MBSL) conditions. First, $Cu_2SnSe_3$ nanoparticles were synthesized by the sonochemical method with an 85% yield, using CuCl, $SnCl_2$, and Se. Second, ZnSe was coated on the CTSe nanoparticles by the same method. Then, they were transformed into CZTSe nanoparticles of 5-7 nm diameters by heating them at $500^{\circ}C$ for 1 h. The ratios between Zn and Sn could be controlled from 1 to 3.75 by adjusting the relative concentrations of CTSe and ZnSe. With relatively lower Zn:Sn ratios (0.75-1.26), there are mostly CZTSe nanoparticles but they are believed to include very small amount of CTS and ZnSe particles. The prepared nanoparticles show different band gaps from 1.36 to 1.47 eV depending on the Zn/Sn ratios. In this sonochemical method without using any toxic or high temperature solvents, the specific stoichiometric element Zn/Sn ratios in CZTSe were controllable on demand and their experimental results were always reproducible in separate syntheses. The CZTSe nanoparticles were investigated by using X-ray diffractometer, a UV-Vis spectrophotometer, scanning electron microscope, Raman spectroscopy, and a high resolution-transmission electron microscope.

• 대한기계학회:학술대회논문집
• /
• 대한기계학회 2001년도 춘계학술대회논문집E
• /
• pp.69-74
• /
• 2001

It is well known that an air bubble trapped in water emits light at its collapse robustly with a proper forcing amplitude of ultrasound. Instability mechanism which causes deviation from sphericity of bubble wall was investigated theoretically. The rapid change of the bubble wall velocity which is both dependent on the forcing amplitude, was found to be a major factor of instability of the interface. The Rayleigh-Taylor instability which occurs when rapid acceleration is directed from the lighter towards the heavier fluid is found to be not related to the instability of the sonoluminescing gas bubble. A good agreement between the calculation results and experimental data is found.

• 대한기계학회:학술대회논문집
• /
• 대한기계학회 2004년도 추계학술대회
• /
• pp.1282-1287
• /
• 2004

The bubble behavior and the radiation mechanism from a laser-induced collapsing bubble were investigated theoretically using the Keller-Miksis equation for the bubble wall motion and analytical solutions for the vapor inside bubble. The calculated time dependent bubble radius is in good agreement with observed ones. The half-width of the luminescence pulse at the collapse point, which was calculated under assumption that the light emission mechanism is black body radiation from the vapor bubble agreed well with observed value of several nanoseconds. The gas content inside the vapor bubble was too small to produce the light emission due to bremsstrahlung.

• 대한기계학회:학술대회논문집
• /
• 대한기계학회 2000년도 추계학술대회논문집B
• /
• pp.550-555
• /
• 2000

Nonlinear oscillation of a microbubble under ultrasound was investigated theoretically. The bubble radius-time curves calculated by the Rayleigh-Plesset equation with a polytropic index and by the Keller-Miksis equation with the analytical solution for the Navier-Stokes equations of the gases were compared with the observed results by the light scattering method. This study has revealed that the bubble behavior such as the expansion ratio and the bouncing motion after the first collapse under ultrasound depends crucially on the retarded time of the bubble motion to the applied ultrasound.

• 기계저널
• /
• 제35권8호
• /
• pp.725-736
• /
• 1995

소노루미네센스(SL)현상은 액체 내에서 초음파에 동기화되어 진동하는 미소기포$~10\mu\textrm{m}$)가 수축할 때 기포내부의 온도가 고온이 됨에 따라 기포중심으로부터 빛이 나오는 현상을 말한다. 단일기 포가 초음파에 가진 될 경우 그 스펙트럼이 X선에 가까운 것임이 밝혀질뿐더러 촉매물 질의 개발이나 활성화, 고분자 합성뿐만 아니라 용액 내에서의 불순물 제거 등에 대한 응용의 가능성이 속속 발견되자, 현재 과학계뿐만 아니라 일반 매스컴에서도 화제의 대상이 되고 있다. SL현상은 원자당 $10^{11}eV$ 에 해당되는 초음파 에너지의 파장이 0.19.mu. 이하인 X선, 즉 6eV 이상의 광자에너지로 증폭됨에 따라 기포수축시 기포내 가스의 온도가 수만 도에 이르는 것, 레이저에 상응하는 광펄스 폭(50 ps)과 초음파에 동기되어 현존하는 최상의 수정시계에 필적하는 SL펄스의 규칙성, 기포수축시의 $10^{10}W/m^{2}$에 해당되는 열의 방출과 10억분의 수 초 동안에 $10^{4}K$의 고온상태에서 200K 정도의 저온상태로 바뀜에 따른 급격한 냉각속도 등 으로 특징지어질 수 있다. 이 글에서는 현재 실험을 통하여 알려진 SL에 관한 현상의 특징과 응용에 대해 구체적으로 기술하였다.

• Journal of Advanced Marine Engineering and Technology
• /
• 제26권1호
• /
• pp.116-124
• /
• 2002

The bubble model by Keller and Prosperetti is adapted to solve the nonlinear oscillation of a gas bubble. This formulation leads to accurate results since it introduces the energy equation instead of the polytropic assumption for the bubble interior. The numerical method used in this study is stable enough to handle large amplitude of bubble oscillation. The numerical results show some interesting nonlinear phenomena fur the bubble oscillator. The excitation changes the natural frequency of the bubble and makes some harmonic resonances at $f/f_0=1/2, 1/3$ and so on. The natural frequency of a bubble oscillator decreases compared with the linear case result, which means that the nonlinear bubble oscillation system is a "softening"system. In addition, the frequency response curve jumps up or down at a certain frequency. It is also found that there exist multi-valued regions in the frequency response curve depending on the initial conditions of bubble. The dependency of the bubble motion on the initial condition can generate extremely large pressure and temperature which might be the cause of the acoustic cavitation and the sonoluminescence.inescence.

• 한국재료학회지
• /
• 제24권1호
• /
• pp.6-12
• /
• 2014

In the present work, $WO_3$ and $WO_3-TiO_2$ were prepared by the chemical deposition method. Structural variations, surface state and elemental compositions were investigated for preparation of $WO_3-TiO_2$ sonocatalyst. X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray (EDX) and transmission electron microscopy (TEM) were employed for characterization of these new photocatalysts. A rhodamine B (Rh.B) solution under ultrasonic irradiation was used to determine the catalytic activity. Excellent catalytic degradation of an Rh.B solution was observed using the $WO_3-TiO_2$ composites under ultrasonic irradiation. Sonocatalytic degradation is a novel technology of treating wastewater. During the ultrasonic treatment of aqueous solutions sonoluminescence, cavitaties and "hot spot" occurred, leading to the dissociation of water molecules. In case of a $WO_3$ coupled system, a semiconductor coupled with two components has a beneficial role in improving charge separation and enhancing $TiO_2$ response to ultrasonic radiations. In case of the addition of $WO_3$ as new matter, the excited electrons from the $WO_3$ particles are quickly transferred to $TiO_2$ particle, as the conduction band of $WO_3$ is 0.74 eV which is -0.5 eV more than that of $TiO_2$. This transfer of charge should enhance the oxidation of the adsorbed organic substrate. The result shows that the photocatalytic performance of $TiO_2$ nanoparticles was improved by loading $WO_3$.