• Title/Summary/Keyword: Solvent removal

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Removal of Organic Pollutants from Aqueous Solution by Hollow Fiber Module (중공사모듈에 의한 수용액으로부터 유기오염물의 제거)

  • 유홍진
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.4 no.2
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    • pp.114-119
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    • 2003
  • This study is to remove several organic pollutants from wastewater by non-dispersive membrane solvent extraction technique. The distribution coefficients of several solvents were determined and the experimental system was operated counter-currently and cocurrently with respect to the aqueous phase and solvent. In these experiments, as the flow rate of aqueous solution inclosed, due to being shortened contact time to solvent, the rate of removal of organic pollutants decreased and as the flow rate of solvent increased, the rate of removal increased. Meanwhile, the rate of removal of organic pollutants for the countercurrent flow system was higher than that for the occurrent flow system.

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Removal of Oily and Particulate Soils from Silk Fabrics (견직물에 부착한 지용성 오구 및 고형 오구의 제거)

  • Lee, Jeong-Sook
    • Fashion & Textile Research Journal
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    • v.7 no.6
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    • pp.680-688
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    • 2005
  • This study was carried out to investigate on the removal of oily and particulate soils from silk fabrics. Various kinds of solvents were used on the removal of two kinds of soils treated into the silk fabrics. The removal of oily soil was analyzed by liquid scintillation counting method, and the removal of oil and carbon particulate mixed soils was evaluated by measuring of reflectance on the surface of soiled fabrics with/without drysoap in solvent washing by Terg-o-tometer. The surfaces of fabrics were also observed by SEM before and after washing. The results obtained were as follows : oily soils were removed efficiently by various kinds of solvents regardless of kinds of silk fabrics in short washing time. The removal effect of solvents from the soiled silk fabrics were high in the order of isopropyl alcohol>trichloroethane>monochlorobenzene>ethylether>perchloroethylene. Oil and carbon particulate mixed soils could be efficiently removed by adding of drysoap in solvent washing. The removal of mixed soils were increased drastically with rinsing and increased drysoap. The removal of soils was more efficiently removed from degummed silk fabrics than from the raw silk fabrics.

Effect of Drycleaning on the Removal of Microorganisms (Part 1) (드라이클리닝에 의한 미생물 제거효과(제1보))

  • 신정숙;차옥선
    • Journal of the Korean Society of Clothing and Textiles
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    • v.19 no.3
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    • pp.548-559
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    • 1995
  • The purpose of this study was 1) to investigate the effect of drycleaning on the removal of microorganisms according to on the conditions or the kinds of drycleaning solvent about the Quantity of microorganism which remains in kinds of the drycleaning solvent and the sludge after drycleaning. 2) to investigate the removal effect of :microorganisms in using drycleaning solvent repeatedly 3) to investigate the kinds of microorganism living in textiles. The re, ;ultras of tai, ; study were as follows; 1) less microorganisms remains in perchloroethylen than in petroleum solvent. The most microorganisms was isolated at the beginning stage during the drycleaning. 2) In fresh drycleaning solvents, Pseudomonas aeruginosa ATTIC 27853, taphylococcsu atreus ATTIC 6538. and Candida albicans 10529 were killed immediately, while in case of pesters solvents used for 6 month-drycleaning, Pseudomonas Aeruginosa ATTIC 27853 were survived a lot of still in 17 days. 3) On the kind of bacteria in textile goods, Pseudomonas acidovorans and Ewsipelothrix rhusiopathiae are isolated. a genus Rhodetorula is observed through microscope. On the kind of fungi in textile goods, genus Penicillins and genus Apergillus are found through microscope, genus Caddie and genus Trichophyton are found with shapes.

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Removal of Potassium from Molasses by Solvent Extraction and Ion Exchange

  • Wang, Lingyun;Nam, Sang-Ho;Lee, Manseung
    • Bulletin of the Korean Chemical Society
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    • v.35 no.9
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    • pp.2711-2716
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    • 2014
  • The high content of potassium in molasses limits its usage as a raw material for stock feed. Moreover, its high viscosity makes it difficult to develop an efficient removal process. In this study, ion exchange and solvent extraction experiments have been performed to investigate the removal of potassium from a mixture of molasses with water. Cationic exchange resins (AG50W-X8 and Diphonix) showed a high loading percentage of potassium but the occurrence of breakthrough in few bed volumes was a drawback to the industrial application. Among the cationic extractants (D2EHPA, PC 88A, Cyanex 272) tested in this study, saponified PC 88A was found to be the best extractant for the removal of potassium. Batch simulation studies on a three stage counter current extraction confirmed that 85% of potassium was removed from 50 wt % molasses solution in water by using saponifed PC 88A.

Treatment of ground waters in a hollow-fibre liquid membrane contactor for removal of ions

  • Hossain, Md. M.
    • Membrane and Water Treatment
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    • v.4 no.2
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    • pp.95-108
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    • 2013
  • Metal ions exist in seawater, groundwater and industrial wastewaters. These source waters can be recycled if their concentrations are reduced. A number of processes can be applied for this purpose. Liquid-liquid extraction is one of the promising methods. In this paper, experimental results are presented on the removal of Cr(VI) using Aliquat-336, a reactive carrier, in sunflower oil (a non-toxic solvent). The performance of this new system is compared with those of kerosene (a toxic solvent). The extent of removal of Cr(VI) from samples with high and low concentrations are presented. The process was upgraded to a bench-scale module that can selectively remove about 50-90% Cr(VI) from samples of groundwater. Thus this process can produce water within the acceptable range for recycling and for use in secondary purposes such as irrigation.

Study of Supercritical Carbon Dioxide/n-Butyl Acetate Co-solvent System with High Selectivity in Photoresist Removal Process (포토레지스트 공정에서 높은 선택성을 가지는 초임계 이산화탄소/n-butyl acetate 공용매 시스템 연구)

  • Kim, Dong Woo;Heo, Hoon;Lim, Kwon Teak
    • Clean Technology
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    • v.23 no.4
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    • pp.357-363
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    • 2017
  • In this study, the supercritical carbon dioxide ($scCO_2$)/ n-butyl acetate (n-BA) co-solvent system was employed to remove an unexposed negative photoresist (PR) from the surface of a silicon wafer. In addition, the selectivity of the $scCO_2$/n-BA co-solvent system was confirmed for the unexposed and exposed negative PR. Optimum conditions for removal of the unexposed PR were obtained from various conditions such as pressure, temperature and n-BA ratio. The n-BA was highly soluble in $scCO_2$ without cloud point and phase separation in mostly experimental conditions. However, the $scCO_2$/n-BA co-solvent was phase separated at 100 bar, above $80^{\circ}C$. The unexposed and exposed PR was swelled in $scCO_2$ solvent at all experimental conditions. The complete removal of unexposed PR was achieved from the reaction condition of 160 bar, 10 min, $40^{\circ}C$ and 75 wt% n-BA in $scCO_2$, as measured by ellipsometry. The exposed photoresist showed high stability in the $scCO_2$/n-BA co-solvent system, which indicated that the $scCO_2$/n-BA co-solvent system has high selectivity for the PR removal in photo lithograph process. The $scCO_2$/n-BA co-solvent system not only prevent swelling of exposed PR, but also provide efficient and powful performance to removal unexposed PR.

Pretreatment Condition of Cu by Ammonium-Based Mixed Solvent and Its Effects on the Fabrication of Ag-Coated Cu Particles (Ag 도금 Cu 입자의 제조에서 암모늄 기반 혼합 용매를 사용한 Cu 입자의 전처리 조건과 이의 영향)

  • Lee, Hee Bum;Lee, Jong-Hyun
    • Korean Journal of Materials Research
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    • v.26 no.3
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    • pp.109-116
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    • 2016
  • To achieve the fabrication of high-quality Ag-coated Cu particles through a wet chemical process, we reported herein pretreatment conditions using an ammonium-based mixed solvent for the removal of a $Cu_2O$ layer on Cu particles that were oxidized in air for 1 hr at $200^{\circ}C$ or for 3 days at room temperature. Furthermore, we discussed the results of post-Ag plating with respect to removal level of the oxide layer. X-ray diffraction results revealed that the removal rate of the oxide layer is directly proportional to the concentration of the pretreatment solvent. With the results of Auger electron spectroscopy using oxidized Cu plates, the concentrations required to completely remove 50-nm-thick and 2-nm-thick oxides within 5 min were determined to be X2.5 and X0.13. However, the optimal concentrations in an actual Ag plating process using Cu powder increased to X0.4 and X0.5, respectively, because the oxidation in powder may be accelerated and the complete removal of oxide should be tuned to the thickest oxide layer among all the particles. Back-scattered electron images showed the formation of pure fine Ag particles instead of a uniform and smooth Ag coating in the Ag plating performed after incomplete removal of the oxide layer, indicating that the remaining oxide layer obstructs heterogeneous nucleation and plating by reduced Ag atoms.

Effect of Template Removal on Synthesis of Organic-Inorganic Hybrid Mesoporous MCM-48

  • Zhao, Ya Nan;Li, San Xi;Han, Chong-Soo
    • Bulletin of the Korean Chemical Society
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    • v.33 no.10
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    • pp.3196-3202
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    • 2012
  • Post-synthesis is used to synthesize organic hybrid inorganic mesoporous sieves. In this method, the activity and structure of the base sieve are crucial to obtain the definable hybrid materials. The chemical and physical properties of the base can be largely changed either by the final step of its synthesizing processes, by template removal which is accomplished with the oxidative thermal decomposition (burning) method or by solvent extraction method. In this paper we compared two methods for the post-synthesis of organic hybrid MCM-48. When the template was extracted with HCl/alcohol mixture, the final product showed larger pore size, larger pore volume and better crystallinity compared to the case of the thermal decomposition. The reactivity of the surface silanol group of template free MCM-48 was also checked with an alkylsilylation reagent $CH_2=CHSi(OC_2H_5)_3$. Raman and $^{29}Si$ NMR spectra of MCM-48 in the test reaction indicated that more of the organic group was grafted to the surface of the sample after the template was removed with the solvent extraction method. Direct synthesis of vinyl-MCM-48 was also investigated and its characteristics were compared with the case of post-synthesis. From the results, it was suggested that the structure and chemical reactivity can be maintained in the solvent extraction method and that organic grafting after the solvent extraction can be a good candidate to synthesize a definable hybrid porous material.

Solvent/Detergent Inactivation and Chromatographic Removal of Human Immunodeficiency Virus During the manufacturing of a High Purity Antihemophilic Factor VIII concentrate

  • Kim, In-Seop;Park, Yong-Woon;Woo, Hang-Sang;Chong E. Chang;Lee, Soungmin
    • Journal of Microbiology
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    • v.38 no.3
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    • pp.187-191
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    • 2000
  • A validation study was conducted to determine the efficacy of solvent/Detergent (S/D) inactivation and Q-Sepharose column chromatographic removal of the human immunodeficiency virus (HIV) during the manufacturing of a high purity antihemopilic factor VIII (GreenMono) from human plasma. S/D treatment using the organic solvent, tri (n-butyl) phosphate, and the detergent, Trition X-100, was a robust and effective step in eliminating HIV-1. The HIV-1 titer was reduced from an initial titer of 8.3 log10 TCID50 to undetectable levels within one minute of S/D treatment, HIV-1 was effectively partitioned form factor VIII during Q-Sepharose column chromatography with the log reduction factor of 4.1 . These results strongly assure the safety of GreenMono From HIV.

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Developent of a new technique removing paint from recycled car-bumper (기계적 방법과 화학적 방법을 혼합한 폐범퍼 도장 제거 기술 개발)

  • Cruz, Heidy;Son, Younggon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.5
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    • pp.3298-3303
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    • 2014
  • In order to recycle the waste bumper, techniques removing coated paint on a bumper is crucial. Chemical methods are known to be much more effective in removing the paint compared to physical methods. However, the chemical methods generally use toxic solvents and consequently cause environmental pollution. In this study, we tested a new method which combines the chemical and physical method to reduce the amount of solvent and increase the paint removal efficiency. We found that mechanical stirring increases the paint removal efficiency in soaking stage of solvent. When solid particles as a stress transfer media are incorporated into the solvent and high mechanical stirring is applied, the paint removal efficiency is very high. It was proved that the combined method can accomplish high level of the paint removal efficiency maintaining low amount of solvent consumed.