• Corrosion Science and Technology
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• 제19권6호
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• pp.281-287
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• 2020

Chloride ion is one of the most important corrosive agents in atmospheric corrosion, especially in marine environments. It has high adsorption rate and increases the conductivity of electrolytes. Since chloride ions affect the protective properties and the surface composition of the corrosion product, they increase the corrosion rate. A low level of chloride ions leads to uniform corrosion, whereas a high level of chloride ions may induce localized corrosion. However, higher solution temperatures tend to increase the corrosion rate by enhancing the migration of oxygen in the solution. This work focused on the effect of NaCl concentration and temperature on galvanic corrosion between A516Gr.55 carbon steel and AA7075T6 aluminum alloys. When AA7075T6 aluminum alloy was galvanically coupled to A516Gr.55 carbon steel, AA7075T6 was severely corroded regardless of NaCl concentration and solution temperature, unlike the corrosion properties of single specimen. The combined effect of surface treatment involving carbon steel and aluminum alloy on corrosion behavior was also discussed.

• 대한기계학회논문집
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• 제3권4호
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• pp.173-180
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• 1979

Temperature distriburion in a hollow chlinder has been analyzed mathematically. Unsteady condition considered assumed a constant heat flux input from the inside. The results are compared with experimental results of surface temperature rise of a gun barrel during continuous firing. Their agreements are acceptable. Effects of various dimensionless parameters on the surface temperature rise are discussed. For small Biot numbers, the external survface temperature approaches more rapidly to the steady temperature. Temperature difference between internal and external surfaces becomes greater for small Biot number. Steady solution assumed that the gas temperature inside the cylinder varies periodically. Relative amplitude and phase angles between the gas temperature and the internal or external surface temperature are obtained. Phase angles become smaller for large radiancy of gas temperature variation, small external Biot number, or large internal biot number. Relative amplitudes become samller as radiancy of gas temperature variation and internal Biot number become smaller. or external Biot number becomes larger. The solution obtained in this paper can be applied to gun barrels, heat pipes used in heat excangers, and reciprocation engines.

• 한국임상약학회지
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• 제8권2호
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• pp.147-158
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• 1998

The purpose of this study was to test the stability of TPN basic solutions containing amino acids and dextrose. Test solutions containing $4.25\%$ amino acids in $25\%$ dextrose (central TPN basic solution) or $4.25\%$ amino acids in $10\%$ dextrose (peripheral TPN basic solution) were prepared. Two different amino acids solutions $(Fravasol^{(R)}\;vs\;Freamine^{(R)})$ were tested. The samples were taken from each admixture and stored in the evacuated, sterile containers at $2{\sim}8^{\circ}C$ and ambient room temperature. Each sample was analyzed at 0, 3, 7, 14 and 30 days of storage. Each amino acid was analyzed by amino acid analyzer. Dextrose content was measured by polarimeter. The pH and chromagen formation were also monitored. The decomposition was measured by the changes in concentration of amino acids and dextroser TPN basic $solution-Freamine^{(R)}$ admixture stored at $2\sim8^{\circ}C$ were stable for 30 days. Central and peripheral TPN basic solutions stored at room temperature were stable for 7 days and 14 days, respectively. There were no changes in color for 30 days by naked eye. Amino acid concentrations in TPN basic $solution-Fravasol^{(R)}$ admixture stored at $2\sim8^{\circ}C$ or room temperature were stable for 30 days. But, significant color change was detected according to passing time. In conclusion, Peripheral TPN basic $solution-Fravasol^{(R)}$ admixture stored at room temperature and in refrigerator were stable for 3 days and 7 days, respectively. However, central TPN basic solution-Fravasol admixtures were unstable. Therefore, it is recommended that it should be admixed right before use.

• 대한화학회지
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• 제15권5호
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• pp.223-228
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• 1971

In the electrolytic preparation of persulphate from sulphate solution, the current efficiency decrease with temperature increase at the platinum anode. But in case of electrodeposited lead peroxide anode, the current efficiency increase with temperature of the solution. The reason seems to be that the ozone formation is faster in platinum anode than in lead peroxide as temperature increase.

• 한국표면공학회지
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• 제37권6호
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• pp.319-325
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• 2004

Fe thin films containing Si particles were prepared on metallic substrates by electrodeposition method in sulfate solutions and the content of codeposited Si particles in the films was investigated as a function of applied current density, the content of Si particels in the solution, solution pH, solution temperature and concentration of $FeSO_4$$7H_2$O in the solution. The amount of Si codeposited in the film was not dependent on the applied current density, solution pH and solution temperature, while it was dependent on the content of Si particles in the solution and the concentration of $FeSO_4$$7H_2$O in the solution. The amount of Si codeposited in the film increased with increasing content of Si particles in the solution but reached a maximum value of about 6 wt% when the content of Si particles in the solution exceeds 100 g/l. On the other hand, the content of Si codeposited in the film increased up to about 17 wt% with decreasing concentration of $FeSO_4$$7H_2$O in the solution. These results would be applied to the fabrication of very thin Fe-6.5 wt% Si sheets for electrical applications.

• 한국물환경학회지
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• 제27권6호
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• pp.896-904
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• 2011

The features of the capture reaction of $CO_2$ by ammonia solution have been investigated along with the effect of temperature on the reaction based upon computer program-utilizing calculation and thermodynamic estimation. The stable region of $CO{_3}^{2-}$ was observed to increase with temperature and the change of the stable region of $CO{_3}^{2-}$ with temperature was greater than the temperature variation of the stable region of other carbonate species. The distribution diagram for $NH_4{^+}-NH_3$ system was constructed and the rise of temperature resulted in the decrease of the stability of $NH_4{^+}$ ion, which was thought to be due to the endothermic nature of its acidic dissociation. Considering the introduction of $Ca^{2+}$ ion in the carbon capture reaction by $NH_4{^+}$, the temperature was observed to be important in the determination of the order of reaction between carbonate ion and these cations. The removal process of $CO_2$ gas by ammonia solution was presumed to occur in open system and the temperature variations of the concentration of carbonate system species along with their total concentration were calculated for the proper control and design of the real process.

• Korean Chemical Engineering Research
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• 제46권6호
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• pp.1052-1056
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• 2008

소다 공정에서 탄산칼슘 결정의 평균입경과 형상 변화를 온도변화와 PAA 용액의 첨가에 대하여 연구하였다. 낮은온도($30^{\circ}C$, $60^{\circ}C$)에서는 Calcite 결정을, 높은 온도($80^{\circ}C$)에서는 Aragonite 결정을 얻었다. $30^{\circ}C$와 $80^{\circ}C$에서 용액에 PAA 용액을 첨가하여도 결정의 형상변화는 없었다. 중간온도($60^{\circ}C$)에서 PAA 용액을 첨가하여 Aragonite 결정을 얻었다. 결정의 형상변화가 PAA 분자 첨가로 인하여 일어났다. PAA 용액의 농도가 높을수록, 더 많은 Aragonite 결정을 얻었다. PAA 수용액의 농도가 높고 분자량이 클수록 탄산칼슘 결정의 평균입경은 증대하였으며, 형상변화가 일어나는 영역에서는 PAA의 분자량이 평균입경변화에 중요한 변수가 된다.

• 태양에너지
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• 제15권2호
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• pp.25-37
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• 1995

유입관성에 의한 유체혼합뿐 아니라 입구온도의 변화까지 고려된 성층축열조의 충전과정 모델에 대하여 해석적 근사해를 제시하였다. 해석모델은 깊이가 일정한 완전혼합 및 압출유동영역으로 구성되며, 입구온도의 변화는 중첩의 원리에 근거하여 계단함수로 근사화하였다. 완전혼합영역의 과도온도를 구한 후 함수형태에 따라 구분하고, 각각을 경계조건으로 하는 압출유동영역의 온도분포를 잘 정의된 함수의 항으로 유도하였다. 결과적으로 이들의 일차결합이 압출유동영역에 대한 최종해이다. 근사해의 타당성 및 결과의 유용성은 입구온도가 선형적으로 증가하는 경우에 대한 엄밀해와의 비교를 통하여 검증하였다. 계단수의 증가에 따라 근사해는 엄밀해로 급속히 접근하며, 유한한 수의 계단에 의한 근사해도 광범위한 혼합깊이에 대하여 엄밀해와 잘 일치한다. 또한, 혼합깊이가 클수록 소수의 계단에 의한 근사해로도 의미있는 예측결과를 얻을 수 있었다.

• 동의생리병리학회지
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• 제17권5호
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• pp.1257-1263
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• 2003

The modified engineering methodology and the modified electronic circuit in classical ultrasonic principles were applied to ultrasonic aerosol nebulizer for inhalation toxicology study of cadmium aerosol. 1532.96ppm Cd nebulizing solution was used to generate cadmium aerosol for particle size analysis with the modifying source and inlet temperatures. The results of particle size analysis for cadmium aerosol were as following. The highest particle counting for source temperature 20℃ was 399.75 × 10² in inlet temperature 100℃ and particle diameter 0.75㎛. The highest particle counting for source temperature 50℃ was 399.70 × 10² in inlet temperature 50℃ and particle diameter 0.75㎛. The highest particle counting for source temperature 70℃ was 411.14 × 10² in inlet temperature 100℃ and particle diameter 0.75㎛. The ranges of geometric mean diameter were 0.74-0.79㎛ in source temperature 20℃, 0.65-0.72㎛ in source temperature 50℃, and 0.65-0.80㎛ in source temperature 70℃. The smallest geometric mean diameter was 0.65㎛ in source temperature 50, 70℃ and inlet temperature 20, 50℃, and the largest geometric mean diameter was 0.80㎛ in source temperature 70℃ and inlet temperature 100℃. The ranges of geometric standard deviation were 1.71-1.80 in source temperature 20℃, 1.27-1.61 in source temperature 50℃, and 1.27-2.29 in source temperature 70℃. The lowest geometric standard deviation was 1.27 in source temperature 50, 70℃ and inlet temperature 20, 50℃, and the highest geometric standard deviation was 2.29 in source temperature 70℃ and inlet temperature 100℃. Generated aerosol for cadmium inhalation toxicology study was polydisperse aerosol with the above geometric standard deviation 1.2. The ranges of mass median diameter(MMD) were 1.75-2.25㎛ in source temperature 20℃, 1.27-1.61㎛ in source temperature 50℃, and 1.27-2.29㎛ in source temperature 70℃. The smallest MMD was 1.27㎛ in source temperature 50, 70℃ and inlet temperature 20, 50℃, and the largest MMD was 2.29㎛ in source temperature 70℃ and inlet temperature 100℃. Cadmium chloride concentration in nebulizing solution affected the particle size and distribution of cadium aerosol in air. MMO for inhalation toxicology testing in OECD and EU is less than 3㎛ and EPA guidance is less than 4㎛. In our results, in source temperatures of 20, 50, 70℃, and inlet temperatures of 20, 50, 100, 150, 200, 250℃ were conformed to the those guidance.

• 대한기계학회논문집
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• 제19권1호
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• pp.231-239
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• 1995

This paper describes a computer simulation of the triple effect, water-lithium bromide absorption cooling cycles. The performance of the absorption systems is investigated through cycle simulation to obtain the system characteristics with the cooling water inlet temperature, the working solution concentrations, the ratio of the amount of the weak solution to the high, middle and low temperature generators, and the temperature difference of each solution heat exchanger. The efficiency of different cycles has been studied and the simulation results show that higher coefficient of performance could be obtained for the parallel cycle of constant solution distribution rate. As a result of this analysis, the optimum designs and operating conditions were determined based on the operating conditions and coefficient of performance.