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Influence of Temperature and PAA(PolyAcrylic Acid) Solution in the Formation of Calcium Carbonate Crystal  

Han, Hyun Kak (Department of Chemical Engineering, Soonchunhyang University)
Kim, Bo-Mi (Department of Chemical Engineering, Soonchunhyang University)
Kim, Jin-a (Department of Chemical Engineering, Soonchunhyang University)
Publication Information
Korean Chemical Engineering Research / v.46, no.6, 2008 , pp. 1052-1056 More about this Journal
Abstract
Crystal mean size and shape change of calcium carbonate crystal was investigated by the temperature change and addition of PAA solution in the soda process. At low temperature($30^{\circ}C$, $60^{\circ}C$), calcite particles were made by. But at high temperature($80^{\circ}C$), aragonite particles were made by. At $30^{\circ}C$ and $80^{\circ}C$, Crystal shape were not changed by adding PAA solution. At moderate temperature($60^{\circ}C$), aragonite was obtained by adding PAA aqueous solution. Crystal shape was changed by adding PAA molecules. The higher concentration of PAA solution is, the more aragonite particles were observed. Incase of calcite and aragonite, mean size of calcium carbonate crystals were increased by higher molecule weight and higher concentration of PAA solution. But in the shape change region, the molecule weight of PAA was the main parameter of increasing mean crystal size.
Keywords
Calcium Carbonate; Calcite; Aragonite; PAA;
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Times Cited By KSCI : 3  (Citation Analysis)
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