• Journal of Soil and Groundwater Environment
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• v.20 no.2
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• pp.41-46
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• 2015

The drag of the excess charge in an electrical double layer at the solid fluid interface due to water flow induces the streaming current, i.e., the streaming potential (SP). Here we introduce a sandbox experiment to study this hydroelectric coupling in case of a tracer test. An acrylic tank was filled up with homogeneous sand as a sand aquifer, and the upstream and downstream reservoirs were connected to the sand aquifer to control the hydraulic gradient. Under a steady-state water flow condition, a tracer test was performed in the sandbox with the help of peristaltic pump, and tracer samples were collected from the same interval of five screened wells in the sandbox. During the tracer test, SP signals resulting from the distribution of 20 nonpolarizable electrodes were measured at the top of the tank by a multichannel meter. The results showed that there were changes in the observed SP after injection of tracer, which indicated that the SP was likely to be related to the solute transport.

• Proceedings of the Membrane Society of Korea Conference
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• 2005.11a
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• pp.96-101
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• 2005

A theory for the material transports through ion exchange membrane has been developed on the basis of nonequilibrium thermodynamics by removing the assumption of solvent flow in the previous paper and applied to a detailed study of the ionic transport properties of new charged mosaic membrane(CMM) system. The CMM having two different fixed charges in the polymer membrane indicated unique selective transport behavior then ion-exchange membrane. The separation behavior of ion transport across the CMM with a parallel array of positive and negative functional charges were investigated. It was well-known the analysis of the volume flux and solute flux based on nonequilibrium thermodynamics. Our suggests preferential salt transport across the charged mosaic membranes. Transport properties of heavy metal ions, $Mg^{2+}$, $Mn^{2+}$and sucrose system across the charged mosaic membrane were estimated. As a result, we were known metal salts transport depended largely on the CMM. The reflection coefficient indicated the negative value that suggested preferential material transport and was independent of charged mosaic membrane thickness.

• Journal of Korea Water Resources Association
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• v.32 no.6
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• pp.751-762
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• 1999

In this study, a 1-D laboratory experiment was conducted to investigate the characteristics of transient unsaturated solute transport by using two kinds of soils of which properties were known by test. Especially the TDR method which is proposed in this study was used to measure water content and solute concentration. As results, in the transient flow, the wetting front moves down rapidly, and the distribution of solute concentration near the wetting front showed the similar type of the water content distribution(semi-bell type). A numerical model HYDRUS was used to compare with the experimental results. Numerical results for the water movement are similar to experimental result. However, numerical results of the distribution of solute concentration are more scattered than experimental results. It means that measured dispersivity, numerical dispersion, adsorption coefficient, and soil sample size etc. should be considered in order to determine the dispersivity used in the numerical model. The present measuring method was proved to be superior to other formula and to be an available method to apply to solute transport test. The measuring error of the developed method is estimated smaller than 10% while water content is larger than 0.15.

• Journal of Environmental Science International
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• v.5 no.4
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• pp.495-511
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• 1996

The quantitative study of the groundwater contamination in a porous media is a difficult task. For complex problems, numerical solutions are the most effective means to study the movement of contaminants in the groundwater, The solute transport model used in this study has proved to be an efficient tool to model contaminant transport for complex problems. The model demonstrates its effectiveness in reproducing the coniamination by ihlorides of the groundwater at the landfill site due to leachath from the wastes. It describes the two dimentional solute transport and alteration of the water quality and forecasts the contamination for different management alternatives of the landfill. The model also indicates how the groundwater contamination can be contained within the lower site if a barrier is constructed downstream of the disposed wastes.

• Proceedings of the KSME Conference
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• 2004.04a
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• pp.1195-1200
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• 2004

A fully coupled fluid flow, heat, and solute transport model was developed to investigate turbulent flow, solidification, and macrosegregation in a continuous casting process of steel slab with EMBR. Transport equations of mass, momentum, energy, and species for a binary iron-carbon alloy system were solved using a continuum model. The electromagnetic field was described by the Maxwell equations. A finite-volume method was employed to solve the conservation equations associated with appropriate boundary conditions. The effects of intensity of magnetic field and carbon segregation were investigated. The electromagnetic field reduces the velocity of molten flow in the mold and an increase in the percentage of C in steel results in a decrease of carbon segregation ratio.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.23 no.6
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• pp.651-657
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• 2010

Solute transport through a groove is affected by its vortices. Our laboratory and numerical experiments of dye transport through a single axisymmetric groove reveal evidence of enhanced spreading and mixing by the vortex, i.e., a new kind of dispersion called here the vortex dispersion. The uptake and release of contaminants by vortices in porous media is affected by the flow Reynolds number. The larger the flow Reynolds number, the larger is the vortex dispersion, and the larger is the mass-transfer rate between the mobile zone and the vortex. The long known dependence of the mass-transfer rate between the mobile and "immobile" zones in porous media on flow velocity can be explained by the presence of vortices in the "immobile" zone and their uptake and release of contaminants.

• Magazine of the Korean Society of Agricultural Engineers
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• v.42 no.2
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• pp.71-77
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• 2000

A multi-region model for solute transport through saturated soils has been developed to describe preferential flow. The model consists of numerous discrete pore groups, which are characterized by a discrete dispersion coefficient, flow velocity, and porosity . The hydraulic properties for each pore group are derived from a soil's hydraluic conductivity and soil water characteristic functions . Flow in pore group is described by the classical advection-disersion equation (ADE). An implict finite difference scheme was applied to the governing equation that results in a block-tridiagonal system of equations that is very efficient and allows the soil to be divided into any number of pore groups. The numerical technique is derived from methods used to solve coupled equations in fluid dynamics problems and can also be applied to the transport of interacting solutes. The results of the model are compared to the experimental data from published papers. This paper contributes on the characteristics of the method when applied to the parallel porosity model to describe preferential flow of solutes in soil.

• Journal of Electrochemical Science and Technology
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• v.13 no.3
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• pp.347-353
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• 2022

Agarose hydrogel, a solid electrolyte, was investigated voltammetrically in terms of transport properties and natural convection effects using a ferrocenyl compound as a redox probe. To confirm the diffusion properties of solute on the agarose interface, the diffusion coefficients (D) of ferrocenemethanol in agarose hydrogel were determined by cyclic voltammetry (CV) according to the concentration of agarose hydrogel. While the value of D on the agarose interface is smaller than that in the bulk solution, the square root of the scan rate-dependent peak current reveals that the mass transport behavior of the solute on the agarose surface shows negligible convection or migration effects. In order to confirm the reduced natural convection on the gel interface, scan rate-dependent CV was performed in the solution phase and on the agarose surface, respectively. Slow scan voltammetry at the gel interface can determine a conventional and reproducible diffusion-controlled current down to a scan rate of 0.3 mV/s without any complicated equipment.

• Bulletin of the Korean Chemical Society
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• v.25 no.5
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• pp.665-667
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• 2004

In previous studies, charged mosaic membranes having two different fixed charges in the membrane matrix indicated unique transport behavior such as preferential material transport. In this study, the composite charged mosaic membrane endurable to mechanical pressure in practical application was investigated from the same aspect of solute and solvent transport as before. Lp and ${\omega}$ estimated by taking account of active layer thickness were satisfactorily consistent with those in mosaic membrane without reinforcement. On the other hand, the reflection coefficient s indicated the negative value that suggests preferential material transport.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.26 no.6B
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• pp.623-631
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• 2006

A new model, the periodic transient storage zone model, is developed to describe solute transport mixing in natural streams and rivers with various bottom boundaries. To assess the effects of storage zones structure on transient storage exchange, we analyze data from salt and dye injection experiments in a recirculating laboratory flume with four spatially periodic pool-riffle sequences characteristic of natural river systems under low flow conditions. Dye injections show that solute transport mixing controlled by surface shapes of both the bed and the side in channels. As no existing transient storage model could represent these effects, we developed a new axially periodic transient storage zone model that better represent the effects of channel characteristics in natural river systems. The new model is also fitted to data from salt tracer injection experiments in four reaches of the upper Sabin River, Texas, USA. The proposed model is in good agreement with the field experimental data.