• Journal of the Korean Society of Fisheries and Ocean Technology
• /
• v.26 no.4
• /
• pp.372-379
• /
• 1990

The effect of primary solidification phase on the solidification cracking sensitivity, corrosion resistance and toughness at cryogenic temperature was investigated for the austenitic stainless steel welds. The conclusions were summarized as follows; 1. Soldification crack sensitivity of austenitic stainless steel welds depends on the primary solidification mode. 2. Austenitic stainless steels were very susceptible to solidification cracking in case of solidification as primary ${\gamma}$ and immune when solidified as primary $\delta$. 3. When the ratio of Creq/Nieq is in the range of 1.46 to 1.55, the most resistance against solidification cracking was obtained. These results agreed well with the relationship between primary solidification mode, corrosion resistance and toughness at cryogenic temperature. 4. Optimum toughness, corrosion and solidification cracking resistance can be obtained when alloys having chemical compositions described above and solidifies as primary $\delta$ containing no ferrite at room temperature.

• Journal of Welding and Joining
• /
• v.16 no.6
• /
• pp.59-68
• /
• 1998

In this study, effects of solidification modes (primary $\delta$-ferrite, primary ${\gamma}$-austenite) on the pit initiation and propagation in the 304L and 316L austenitic stainless steel weld metals were investigated. The solidification mode of weld metal was controlled by the addition of nitrogen to Ar shielding gas. Through the electrochemical experiments (potentiodynamic anodic polarization and potentiostatic time-current transient test) and metallographic examination (microstructure and elemental distribution), the following results were obtained. The more the volume content of nitrogen in the shielding gas were, the lower critical current density for passivity was observed. In comparison with weldments solidified through the primary $\delta$-ferrite solidification mode and the primary ${\gamma}$-solidification mode, the former showed higher critical pitting potential and a longer incubation time for stable pit initiation than the latter. However, in the pit propagation stage the former exhibited a faster dissolution rate than the latter. These results were believed to ee related to the distribution of alloying elements such as Cr, Mo, Ni and S.

• Journal of Welding and Joining
• /
• v.18 no.1
• /
• pp.59-69
• /
• 2000

The purpose of the present study was to investigate weld metallurgical phenomena such as primary solidification mode, microstructural evolution and hot cracking susceptibility in nitrogen-bearing austenitic stainless steel GTA welds. Eight experimental heats varying nitrogen content from 0.007 to 0.23 wt.% were used in this study. Autogenous GTA welding was performed on weld coupons and the primary solidification mode and their microstructural characteristics were investigated from the fusion welds. Varestraint test was employed to evaluate the solidification cracking susceptibility of the heats and TCL(Total Crack Length) was used as cracking susceptibility index. The solidification mode shifted from primary ferrite to primary austenite with an increase in nitrogen content. Retained delta ferrite exhibited a variety of morphology as nitrogen content varied. The weld fusion zone exhibited duplex structure(austenite+ferrite) at nitrogen contents less than 0.10 wt.% but fully austenitic structure at nitrogen contents more than 0.20 wt.%. The weld fusion zone in alloys with about 0.15 wt.% nitrogen experienced primary austenite + primary ferrite solidification (mode AF) and contained delta ferrite less than 1% at room temperature. Regarding to solidification cracking susceptibility, the welds with fully austenitic structure exhibited high cracking susceptibility while those with duplex structure low susceptibility. The cracking susceptibility increased slowly with an increase in nitrogen content up to 0.20 wt.% but sharply as nitrogen content exceeded 0.20 wt.%, which was attributed to solidification mode shift fro primary ferrite to primary austenite single phase solidification.

• Journal of Welding and Joining
• /
• v.16 no.3
• /
• pp.111-120
• /
• 1998

To predict and evaluate metallurgical and mechanical behavior of th welds, it is essential to understand solidification behavior and microstructural evolution experienced in the welds, neither of which follows the equilibrium phase diagram because of rapid heating and cooling conditions. Metallurgical phenomena in austenitic stainless steel fusion welds, types 304, 309S, 316L, 321 and 304N, were investigated in this study. Autogenous GTA welding was performed on weld coupons, and primary solidification mode and phase distribution were investigated from the welds. Varestraint test was employed to evaluate solidification cracking susceptibilities of the alloys. GTA weld fusion zones in type 304, 321 and 304N stainless steels experienced primary ferrite solidification while those in type 309S primary austenite solidification. Type 316L exhibited a mixed type of primary ferrite and primary austenite solidification. The primary solidification mode strongly depended on $Cr_{eq}/Ni_{eq}$ ratio. In terms of solidification cracking susceptibility, type 309S that solidified as primary austenite exhibited high cracking susceptibility while the alloys experienced primary ferrite solidification showed low cracking susceptibility. The relative ranking in solidification cracking susceptibility was type 304=type 304N < type 321 < type 316L < type 309S.

• Journal of Welding and Joining
• /
• v.34 no.5
• /
• pp.54-60
• /
• 2016

In order to quantitatively evaluate the solidification cracking susceptibility in laser welds of three types of austenitic stainless steels (type 310: A mode, type 316-A: AF mode, type 316-B: FA mode solidifications), the laser beam welding (LBW) transverse-Varestraint tests consisted of multi-mode fiber laser, welding robot and hydraulic pressure system were performed. As the welding speed increased from 1.67 to 40.0 mm/s, the solidification brittle temperature range (BTR) of laser welds for type 316 stainless steels enlarged (316-A: from 37 to 46 K, 316-B: from 14 to 40 K), while the BTR for type 310 stainless steel reduced from 146 to 120 K. In other words, it founds that solidification cracking susceptibility could not be simply mitigated through application of LBW process, and the BTR variation behavior is quite different upon solidification mode of austenitic stainless steels.

• Journal of the Korean Society of Fisheries and Ocean Technology
• /
• v.28 no.2
• /
• pp.208-215
• /
• 1992

Concept of primary solidification mode control was adopted to obtain optimal solidification crack resistance, hot ductility, corrosion resistance and toughness for austenitic stainless steel. By controlling primary solidification phase as primary $\delta$ and containing no ferrite at room temperature, optimal solidification crack resistance, hot ductility, corrosion resistance and cryogenic toughness could be obtained. The optimum chemical composition of austenitic stainless steel ranges 1.46~1.55(Creq/Nieq ratio) calculated by Schaeffler's equation.

• Journal of Ocean Engineering and Technology
• /
• v.11 no.1
• /
• pp.16-23
• /
• 1997

Stainless steel are widely applicable in various engineering fields for its exellent corrosion and impact ressistance. Austenitic weld metal has some ferrite for preventing solidification cracking by ASME specification. Several family of austenic stainless steel contains varying ferrite contents. But ferrite in austenic stainless steels is adversely affect weld metal toughness and since fully austenic grades are known to have good toughness. Austenic stainless steel has various alloying addition for improving corrosion resistance, impact toughness and solidification crack resistance. The effect of various alloying elements are not found to be clear in present. From this view of point, this study tried to establish the criteria of alloy design for austenic stainless steel by controlling primary solidification mode and clarifying the effect of several alloying elements.

• Journal of the Korean Society of Marine Environment & Safety
• /
• v.3 no.2
• /
• pp.13-21
• /
• 1997

This paper describes the effectiveness of laser pulse shaping in eliminating weld defects such as porosity, cracks and undercuts in pulsed Nd:YAG Laser welding. A large porosity was formed in a keyhole mode of deep penetration weld metal of any stainless steel. Solidification cracks were present in Type 303 with about 0.3%s. The conditions for the formation of porosity were determined in further detail in Type 316. With the objectives of obtaining a fundamental knowledge of formation and prevention of weld defects, the fusion and solidification behavior of a molten puddle was observed during laser spot welding of Type 310S. through high speed video photographing technique. It was deduced that cellular dendrite tips grew rapidly from the bottom to the surface, and consequently residual liquid remained at the grain boundaries in wide regions and enhanced the solidification cracking susceptibility. Several laser pulse shapes were investigated and optimum pulse shapes were proposed for the reduction and prevention of porosity and solidification cracking.

• Journal of Korea Foundry Society
• /
• v.26 no.3
• /
• pp.116-122
• /
• 2006

• Journal of Advanced Marine Engineering and Technology
• /
• v.28 no.8
• /
• pp.1270-1278
• /
• 2004

This paper describes the effectiveness of laser pulse shaping in eliminating weld defects such as porosity, cracks and undercuts in pulsed Nd:YAG laser welding. A large porosity was formed in a keyhole mode of deeply penetrated weld metal of any stainless steel. Solidification cracks were present in STS 310S with above 0.017%P and undercuts were formed in STS 303 with about 0.3%S. The conditions for the formation of porosity were determined in further detail in STS 316. With the objectives of obtaining a fundamental knowledge of formation and prevention of weld defects, the fusion and solidification behavior of a molten puddle was observed during laser spot welding of STS 310S through a high speed video photographing technique. It was deduced that cellular dendrite tips grew rapidly from the bottom to the surface, and consequently residual liquid remained at the grain boundaries in wide regions and enhanced the solidification cracking susceptibility. Several laser pulse shapes were investigated and optimum pulse shapes were proposed for the reduction and prevention of porosity and solidification cracking.