• Title/Summary/Keyword: Solid surface

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Synthesis characterization of a high conductivity LSCF cathode materials and electrochemical studies for IT-SOFC (중.저온 고체산화물 연료전지용 고전도성 공기극 소재 합성 및 전기화학적 특성 평가)

  • Kim, Hyoshin;Lee, Jongho;Kim, Ho-Sung;Lee, Yunsung
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.139-139
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    • 2010
  • LSM is widely used as a cathode material in SOFC, because of its high electrochemical activity, good stability and compatibility with YSZ electrolyte at high temperature. However, LSM in traditional cathode materials will not generate a satisfactory performance at intermediate temperature. In order to reduce the polarization resistance of cell with the operating temperature of SOFC system, the cathode material of LSCF is one of the most suitable electrode materials because of its high mixed ionic and electronic conductivity. In this report, cathode material, $La_{0.6}Sr_{0.4}Co_{0.2}Fe_{0.8}O_3$ powder for intermediate temperature SOFC was synthesized by Pechini method using the starting materials such as nitrate of La, Sr, Co and Fe including ethylene glycol, etc. As a result, the synthesized powder that calcined above $700^{\circ}C$ exhibits successfully perovskite structure, indicating phase-pure of LSCF. Moreover, the particle size, surface area, crystal structure and morphology of the synthesized oxide powders were characterized by SEM, XRD, and BET, etc. In order to evaluate the electrochemical performance for the synthesized powder, slury mixture using the synthesized cathode material was coated by screen-printing process on the anode-supported electrolyte which was prepared by a tape casting method and co-sintering. Finally, electrochemical studies of the SOFC unit cell, including measurements such as power density and impedance, were performed.

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The development status and key technologies of Solid oxide fuel cell (고체산화물연료전지의 핵심기술과 개발 현황)

  • Kim, Ho-Sung;Kang, Ju Hee;Kim, Hyo Shin;Kim, Young Mi;Lee, Jong Ho;Oh, Ik Hyun
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.127.1-127.1
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    • 2010
  • 고체산화물연료전지는 고효율 및 무공해의 전기화학 에너지 변환장치로서, 최근 국내외에서 활발한 연구개발이 수행되고 있다. 특히, 고체산화물 연료전지 시스템의 조기 상용화를 위해 시스템의 작동온도를 약 $800^{\circ}C$ 이하로 낮추고 저가로 생산 할 수 있는 제조공정 개발에 대한 연구를 적극적으로 수행하고 있다. 본 연구에서는 고체산화물연료전지의 단위셀를 구성하는 연료극지지체 및 박막 전해질에 대해서 저가 양산의 테이프케스팅법 및 동시소성 공정, 그리고 연료극 지지체 전해질(anode-supported electrolyte)에 대한 공기극 페이스트 프린팅 제조공정에 대해 소개한다. 또한 고체산 화물연료전지의 제조공정 및 시간을 단축하기 위해 방전플라즈마 소결공법(SPS)에 의한 연료극 지지체 제조 공정, 단위셀의 성능 최적화를 위한 나노 스케일의 고성능 전해질 소재 분말합성 공정(crystallite size: 5~10nm, surface area : $100m^2/g$ 이상) 그리고 테이프케스팅에 의한 박막 전해질 제조 공정(thin film : $10{\mu}m$ 이하) 등 주요 단위셀 소재 및 부품의 제조공정 특성 그리고 단위셀의 전기화학적 특성(max. power density : 1.0 W/$cm^2$)에 대해 소개하며, 최종적으로 평판형 대면적 고체산화물연료전지(max. $20cm{\times}15cm$)의 단위셀 상용화 제조 기술 및 성능평가 기술에 대해서도 소개 할 예정이다.

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Synthesis and Evaluation of Variable Temperature-Electrical Resistance Materials Coated on Metallic Bipolar Plates (온도 의존성 가변 저항 발열체로 표면 처리된 금속 분리판 제조 및 평가)

  • Jung, Hye-Mi;Noh, Jung-Hun;Im, Se-Joon;Lee, Jong Hyun;Ahn, Byung Ki;Um, Sukkee
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.73.1-73.1
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    • 2010
  • For the successful cold starting of a fuel cell engine, either internal of external heat supply must be made to overcome the formation of ice from water below the freezing point of water. In the present study, switchable vanadium oxide compounds as variable temperature-electrical resistance materials onto the surface of flat metallic bipolar plates have been prepared by a dip-coating technique via an aqueous sol-gel method. Subsequently, the chemical composition and micro-structure of the polycrystalline solid thin films were analyzed by X-ray diffraction, X-ray fluorescence spectroscopy, and field emission scanning electron microscopy. In addition, it was carefully measured electrical resistance hysteresis loop over a temperature range from $-20^{\circ}C$ to $80^{\circ}C$ using the four-point probe method. The experimental results revealed that the thin films was mainly composed of Karelianite $V_2O_3$ which acts as negative temperature coefficient materials. Also, it was found that thermal dissipation rate of the vanadium oxide thin films partially satisfy about 50% saving of the substantial amount of energy required for ice melting at $-20^{\circ}C$. Moreover, electrical resistances of the vanadium-based materials converge on an extremely small value similar to that of pure flat metallic bipolar plates at higher temperature, i.e. $T{\geq}40^{\circ}C$. As a consequence, experimental studies proved that it is possible to apply the variable temperature-electrical resistance material based on vanadium oxides for the cold starting enhancement of a fuel cell vehicle and minimize parasitic power loss and eliminate any necessity for external equipment for heat supply in freezing conditions.

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Absorption Characteristics of Persimmon Powder Depending on Temperature Changes and Drying Methods (건조방법과 온도변화에 따른 감 분말의 흡습특성)

  • 이원영;김종국
    • Journal of the East Asian Society of Dietary Life
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    • v.11 no.6
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    • pp.479-484
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    • 2001
  • The absorption characteristics of persimmon powder related to different drying methods and various storage temperatures was investigated. The physical properties of persimmon powder by different drying methods displayed the largest amount of porosity in the freeze-dried sample, and the smallest in hot air dried sample. Equilibrium moisture was reached in 6 days. Monolayer moisture contents were predicted to 0.09687~0.19712(freeze drying), 0.07820~0.18617(vacuum drying) and 0.07715~0.18056(hot air drying) g H2O/g solid respectively using the BET equation. BET equation for isothermal absorption curve showed over 0.95 R-square for all dried methods. Monolayer moisture contents were increased as storage temperature was incremented because water molecular movement was more active and there was a greater chance to clash with the absorption surface area.

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Defects analysis of RE : YAG (RE = Nd3+, Er3+) single crystal synthesized by Czochralski method (Czochralski법으로 성장된 RE : YAG(RE = Nd3+, Er3+) 단결정의 결함분석)

  • Park, Cheong Ho;Joo, Young Jun;Kim, Hye Young;Shim, Jang Bo;Kim, Cheol Jin
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.26 no.1
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    • pp.1-7
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    • 2016
  • RE : YAG ($RE=Nd^{3+}$, $Er^{3+}$) single crystals are laser diodes and generally grown by Czochralski method with controlling the various growth parameter. Since the defects occurred by temperature gradient or the rotation speed of solid-liquid growth interface act as the decline of crystal optical property during the growth procedure, crystalline quality improvement via defects analysis is necessary. The etch pit density (EPD) analysis was used to confirm the surface defect of grown RE : YAG single crystal and to select the area of transmission electron microscopy (TEM) analysis. Defects in the specimen produced by tripod polishing method such as buckling, rod shaped, bend contours by internal stress, segregation and others were observed by using 200 kV TEM and 300 kV FE-TEM.

Role of span length in the adaptation of implant-supported cobalt chromium frameworks fabricated by three techniques

  • Zhou, Ying;Li, Yong;Ma, Xiao;Huang, Yiqing;Wang, Jiawei
    • The Journal of Advanced Prosthodontics
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    • v.9 no.2
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    • pp.124-129
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    • 2017
  • PURPOSE. This study evaluated the effect of span length on the adaptation of implant-supported cobalt chromium frameworks fabricated by three techniques. MATERIALS AND METHODS. Models with two solid abutment analogs at different inter-abutment distances were digitized using a laboratory scanner. Frameworks of two-, three-, and four-unit fixed prostheses were designed by a computer. Six dots with a diameter of 0.2 mm were preset on the surface of each framework. A total of 54 implant-supported cobalt chromium frameworks were fabricated by milling, selective laser melting (SLM), and cast techniques. The frameworks were scanned and exported as Stereolithography files. Distances between two dots in X, Y, and Z coordinates were measured in both the designed and fabricated frameworks. Marginal gaps between the framework and the abutments were also evaluated by impression replica method. RESULTS. In terms of distance measurement, significant differences were found between three- and four-unit frameworks, as well as between two- and four-unit frameworks prepared by milling technique (P<.05). Significant differences were also noted between two- and three-unit frameworks, as well as between two- and four-unit frameworks prepared by cast technique (P<.05). The milling technique presented smaller differences than the SLM technique, and the SLM technique showed smaller differences than the cast technique at any unit prostheses (P<.05). Evaluation with the impression replica method indicated significant differences among the span lengths for any fabrication method (P<.05), as well as among the fabrication methods at any unit prostheses (P<.05). CONCLUSION. The adaptation of implant-supported cobalt chromium frameworks was affected by the span length and fabrication method.

Ensuring Stability in Accordance with the Secondary sedimentation tank Surface Loading rate Increase (장방향 이차침전지에서 이중정류벽 설치를 통한 침강속도 증대에 따른안정성 확보 분석)

  • Choi, Dongkyu;Im, Jiyeol;Gil, Kyungik
    • Journal of Wetlands Research
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    • v.18 no.4
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    • pp.357-362
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    • 2016
  • Improvement of the solid-liquid separation efficiency in the secondary sedimentation tank of the biological treatment process, is known to be increasing effectiveness of the overall system operation. Sewage treatment plant effluent SS is composed of most organic substances. In order to reduce the SS component in the secondary sedimentation tank discharge, fine SS components constituting the heterogeneous should be increased by its own aggregation (self flocculation), so that can be deleted through their precipitation. So, it is improved through using the installation of double rectification wall in this secondary tank. In case, sewage is rapidly increased due to the daily change of the influent water, it was confirmed that suspended solids caused by the impact load are processed stably. Therefore, there is a need for a facility installation which can be its own aggregation for reduction suspended solids in secondary sedimentation tank.

Effect of High Molecular Weight Chitosan on the Quality and Decay of Strawberry Fruits (고분자 키토산 처리가 딸기 과실의 품질과 부패에 미치는 영향)

  • Hwang, Yong-Soo;Ku, Ja-Hyeong
    • Korean Journal of Agricultural Science
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    • v.31 no.2
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    • pp.77-86
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    • 2004
  • This study was aimed to determine the effect of high molecular weight chitosan treatment on the decay incidence and fruit quality in strawberries. Preharvest spray of chitosan (0.2%) effectively reduced the incidence of grey mould and increased fruit firmness. Chitosan application was also effective on remaining of surface gloss. This is probably due to coating effect. Physiological disorders were not found in treatment of 4 sprays. Internal quality such as soluble solid content and acidity seemed not to be affected by chitosan application. The effect of chitosan on keeping freshness was clear in fruit without physical damage at harvest, but much less effective in injured fruit. Postharvest application of chitosan did not affect fruit quality. Above results indicated that chitosan is an alternative to keep strawberry quality through delaying decay and keeping firmness.

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Genomic Analysis of a Freshwater Actinobacterium, "Candidatus Limnosphaera aquatica" Strain IMCC26207, Isolated from Lake Soyang

  • Kim, Suhyun;Kang, Ilnam;Cho, Jang-Cheon
    • Journal of Microbiology and Biotechnology
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    • v.27 no.4
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    • pp.825-833
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    • 2017
  • Strain IMCC26207 was isolated from the surface layer of Lake Soyang in Korea by the dilutionto-extinction culturing method, using a liquid medium prepared with filtered and autoclaved lake water. The strain could neither be maintained in a synthetic medium other than natural freshwater medium nor grown on solid agar plates. Phylogenetic analysis of 16S rRNA gene sequences indicated that strain IMCC26207 formed a distinct lineage in the order Acidimicrobiales of the phylum Actinobacteria. The closest relative among the previously identified bacterial taxa was "Candidatus Microthrix parvicella" with 16S rRNA gene sequence similarity of 91.7%. Here, the draft genome sequence of strain IMCC26207, a freshwater actinobacterium, is reported with the description of the genome properties and annotation summary. The draft genome consisted of 10 contigs with a total size of 3,316,799 bp and an average G+C content of 57.3%. The IMCC26207 genome was predicted to contain 2,975 protein-coding genes and 51 non-coding RNA genes, including 45 tRNA genes. Approximately 76.8% of the protein coding genes could be assigned with a specific function. Annotation of the IMCC26207 genome showed several traits of adaptation to living in oligotrophic freshwater environments, such as phosphorus-limited condition. Comparative genomic analysis revealed that the genome of strain IMCC26207 was distinct from that of "Candidatus Microthrix" strains; therefore, we propose the name "Candidatus Limnosphaera aquatica" for this bacterium.

Markov chain-based mass estimation method for loose part monitoring system and its performance

  • Shin, Sung-Hwan;Park, Jin-Ho;Yoon, Doo-Byung;Han, Soon-Woo;Kang, To
    • Nuclear Engineering and Technology
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    • v.49 no.7
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    • pp.1555-1562
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    • 2017
  • A loose part monitoring system is used to identify unexpected loose parts in a nuclear reactor vessel or steam generator. It is still necessary for the mass estimation of loose parts, one function of a loose part monitoring system, to develop a new method due to the high estimation error of conventional methods such as Hertz's impact theory and the frequency ratio method. The purpose of this study is to propose a mass estimation method using a Markov decision process and compare its performance with a method using an artificial neural network model proposed in a previous study. First, how to extract feature vectors using discrete cosine transform was explained. Second, Markov chains were designed with codebooks obtained from the feature vector. A 1/8-scaled mockup of the reactor vessel for OPR1000 was employed, and all used signals were obtained by impacting its surface with several solid spherical masses. Next, the performance of mass estimation by the proposed Markov model was compared with that of the artificial neural network model. Finally, it was investigated that the proposed Markov model had matching error below 20% in mass estimation. That was a similar performance to the method using an artificial neural network model and considerably improved in comparison with the conventional methods.