• Title/Summary/Keyword: Solid surface

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Shear Strength Characteristics of Dredged Soil with Oyster Shell Binder (굴패각 고화재를 혼합한 준설토의 전단특성)

  • Lee, Sangjin;Yoon, Gillim;Lee, Yoongyu;Lee, Kidong;Kang, Ingyu;Kim, Hongtaek;Baek, Seungcheol
    • Journal of the Korean GEO-environmental Society
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    • v.8 no.1
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    • pp.27-32
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    • 2007
  • Trafficability for construction equipments in soft ground should be secured by improving the surface course. For this situation, the ground improvement technique has been used with stiffening agent, but the improvement cement has been mostly used so far. However, oyster shell has been developed and used as the stiffening agent to expand the chance of recycling oyster shell, which is regarded as solid waste. In this research, it was confirmed mechanical characteristics of oyster shell as stiffening agent by analyzing the strength characteristic such as mixing rates, water contents, and curing days of that to the dredging soil.

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Application of a General Gas Electrode Model to Ni-YSZ Symmetric Cells: Humidity and Current Collector Effects

  • Shin, Eui-Chol;Ahn, Pyung-An;Seo, Hyun-Ho;Lee, Jong-Sook
    • Journal of the Korean Ceramic Society
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    • v.53 no.5
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    • pp.511-520
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    • 2016
  • Electrolyte-supported symmetric Ni-YSZ cermet electrodes of ca. $23{\mu}m$ were prepared by screenprinting and the impedance was measured as a function of humidity from 2% to 90% balanced in $H_2$ at a total flow rate of 50 sccm. The Ni felt current collector of 1 mm thickness exhibited a Gerischer-like gas concentration impedance in the low frequency range, which was similarly observed in the cermet-supported solid oxide cells, while the Pt paste collector exhibited only electrochemical polarization. The electrochemical polarization of both samples was modeled by a non-ideal diffusion-reaction transmission line model including CPEs with ${\alpha}$= 0.5. In the case of the Pt paste collector, all the Bisquert parameters exhibited humidity dependence to the -1/2 power, supporting a non-faradaic chemical reaction mechanism at three phase boundaries. Consequently, the surface diffusivity and reaction rate increased linearly with humidity. Less pronounced humidity dependence and somewhat lower utilization length with an Ni felt collector can be attributed to the diffusion-limited gas flow through the collector.

Chemical cleaning of fouled polyethersulphone membranes during ultrafiltration of palm oil mill effluent

  • Said, Muhammad;Mohammad, Abdul Wahab;Nor, Mohd Tusirin Mohd;Abdullah, Siti Rozaimah Sheikh;Hasan, Hassimi Abu
    • Membrane and Water Treatment
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    • v.5 no.3
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    • pp.207-219
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    • 2014
  • Fouling is one of the critical factors associated with the application of membrane technology in treating palm oil mill effluent (POME), due to the presence of high concentration of solid organic matter, oil, and grease. In order to overcome this, chemical cleaning is needed to enhance the effectiveness of membranes for filtration. The potential use of sodium hydroxide (NaOH), sodium chloride (NaCl), hydrochloric acid (HCl), ethylenediaminetetraacetic acid (EDTA), and ultrapure water (UPW) as cleaning agents have been investigated in this study. It was found that sodium hydroxide is the most powerful cleaning agent, the optimum conditions that apply are as follows: 3% for the concentration of NaOH, $45^{\circ}C$ for temperature solution, 5 bar operating pressure, and solution pH 11.64. Overall, flux recovery reached 99.5%. SEM images demonstrated that the membrane surface after cleaning demonstrated similar performance to fresh membranes. This is indicative of the fact that NaOH solution is capable of removing almost all of the foulants from PES membranes.

A Study on the Development of a Three-dimensional Measurement System for Flow-Structure Interaction Using Digital Image Processing (디지털영상처리기술을 이용한 비접촉식 유체-구조물 연동운동 3차원 측정시스템 개발에 관한 연구)

  • DOH DEOG-HEE;JO HYO-JAE;SANG JI-WOONG;HWANG TAE-GYU;CHO YONG-BEOM;PYEONTN YONG-BEOM
    • Journal of Ocean Engineering and Technology
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    • v.18 no.4 s.59
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    • pp.1-7
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    • 2004
  • A simultaneous measurement system that can analyze the flow-structure interaction has been developed. This system consists of four CCD cameras, two for capturing instantaneous flow fields and two for tracking a solid body. The three-dimensional vector fields around a cylinder are measured, while the motion of the cylinder forced by the flow field is measured, simultaneously, with the constructed system. The cylinder is suspended in the working fluid of a water channel, and the surface of the working fluid is forced sinusoidally to make the cylinder bounced. Reynolds number for the mean main stream is about 3500. The interaction between the flow fields and the cylinder motion is examined quantitatively.

Charge/discharge Properties As a Function of Synthetic Conditions of LiMnO$_2$ for Lithium Polymer Batteries (리튬 폴리머 전지용 LiMnO$_2$의 합성조건에 따른 충방전 특성)

  • 조영재;김종욱;박계춘;위성동;구할본
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11a
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    • pp.541-544
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    • 2001
  • Orthorhombic LiMnO$_2$ was synthesized by solid-state reaction using LiOH$.$H$_2$O and Mn$_2$O$_3$ as starting material. Its electrochemical properties as cathode in lithium batteries were examined. X-ray diffraction revealed that the LiMnO$_2$ compound showed a well-defined orthorhombic phase of a space group with Pmnm. The capacity of LiMnO$_2$ agreed well with its specific surface area and grinding treatment was effective in improving cycling performance. For lithium polymer battery applications, the LiMnO$_2$ cell was characterized electrochemically by charge-discharge experiments. And the relationship between the characteristics of powder and electrochemical properties was studied in this research. A maximum discharge capacity of 160-170mAhg$^{-1}$ for LiMnO$_2$/Li cell was achieved

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Fabrication and Characterization of Thin Film Supercapacitor using $WO_3$ ($WO_3$를 이용한 박막형 슈퍼캐패시터의 제작 및 특성 평가)

  • 신호철;신영화;임재홍;윤영수
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.11a
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    • pp.575-578
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    • 2000
  • In this work, all solid-state thin film supercapacitor(TFSC) was fabricated using tungsten trioxide (WO$_3$) with a structure WO$_3$/LiPON/WO$_3$/Pt/TiO$_2$/Si (substrate). After TiO$_2$ was deposited on Si(100) wafer by d.c. reactive sputtering, the Pt current collector films were grown on TiO$_2$glue layer without breaking vacuum by d.c. sputtering. Fabrication conditions of WO$_3$ thin film were such that substrate temperature, working pressure, gas ratio of $O_2$/Ar and r.f. power were room temperature, 5 mTorr, 20% (O$_2$(8sccm)/Ar(32sccm)) and 200W, respectively. LiPON electrolyte film were grown on the WO$_3$ film using r.f. magnetron sputtering at room temperature. The XRD pattern of the as-deposited WO$_3$ thin film were shown no crystalline peak (amorphous). The SEM image of as-deposited WO$_3$ thin film showed that the surface is smooth and uniform. The capacitiy of as-fabricated TFSC was 0$\times$10$^{-2}$ F/$\textrm{cm}^2$-${\mu}{\textrm}{m}$.

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The characterization for the Ti-silicide of $N^+P$ junction by 2 step RTD (2단계 RTD방법에 의한 $N^+P$ 접합 티타늄 실리사이드 특성연구)

  • 최도영;윤석범;오환술
    • Electrical & Electronic Materials
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    • v.8 no.6
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    • pp.737-743
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    • 1995
  • Two step RTD(Rapid Thermal Diffussion) of P into silicon wafer using tungsten halogen lamp was used to fabricated very shallow n$^{+}$p junction. 1st RTD was performed in the temperature range of 800.deg. C for 60 see and the heating rate was in the 50.deg. C/sec. Phosphrous solid source was transfered on the silicon surface. 2nd RTD process was performed in the temperature range 1050.deg. C, 10sec. Using 2 step RTD we can obtain a shallow junction 0.13.mu.m in depth. After RTD, the Ti-silicide process was performed by the two step RTA(Rapid Thermal Annealing) to reduced the electric resistance and to improve the n$^{+}$p junction diode. The titanium thickness was 300.angs.. The condition of lst RTA process was 600.deg. C of 30sec and that of 2nd RTA process was varied in the range 700.deg. C, 750.deg. C, 800.deg. C for 10sec-60sec. After 2 step RTA, sheet resistance was 46.ohm../[]. Ti-silicide n+p junction diode was fabricated and I-V characteristics were measured.red.

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Characterization of LiNi1/3Co1/3Mn1/3O2 Cathode Materials Prepared from Different Precursors in Lithium Rechargeable Batteries (리튬2차전지에서 다른 전구체로부터 합성된 LiNi1/3Co1/3Mn1/3O2 양극 활물질의 특성)

  • Kim, Sung-Keun;Hong, Sung-Wan;Han, Kyeong-Sik;Lee, Hong-Ki;Shim, Joong-Pyo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.11
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    • pp.1029-1035
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    • 2008
  • $LiNi_{1/3}Co_{1/3}Mn_{1/3}O_2$ cathode materials prepared from different precursors in lithium rechargeable batteries were characterized by various analytical methods. $LiNi_{1/3}Co_{1/3}Mn_{1/3}O_2$ powders were synthesized by using solid-state reaction method and their physical and chemical properties were analyzed by XRD, SEM, particle size analyzer and TCP-AES. These materials showed different crystallinity, particle size, surface morphology and chemical composition. Also, the charge/discharge cycling of $LiNi_{1/3}Co_{1/3}Mn_{1/3}O_2$ electrodes was carried out under various cut-off voltages and it showed different behaviors. It was found that the electrochemical cyclability of $LiNi_{1/3}Co_{1/3}Mn_{1/3}O_2$ was strongly related to its crystallinity.

FUNDAMENTAL STUDY ON THE RECOVERY AND REMOVAL OF WHITE PHOSPHORUS FROM PHOSPHORUS SLUDGE

  • Jung, Joon-Oh
    • Environmental Engineering Research
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    • v.10 no.1
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    • pp.38-44
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    • 2005
  • Electro-thermal production of white phosphorus(WP, P4) generates substantial amount of highly toxic phossy water and sludges. Because of their high phosphorus contents and lack of reliable processing technology, large tonnages of these hazardous wastes have accumulated from current and past operations in the United States. In this study, two different methods for treatment of phosphorus sludge were investigated. These were bulk removal of WP by physical separation(froth flotation) and transformation of WP to oxyphosphorus compounds by air oxidation in the sludge medium. Kerosene, among other collectors, resulted in selective flotation of WP from the associated mineral gangue. Solvent action of kerosene occurring on the WP surface(by rendering WP particles hydrophobic) might produce the high selectivity of WP. The WP recovery in the froth was 79.3% from a sludge assaying 34.2% of WP. In the oxidation study, air gas was dispersed in the sludge medium by the rapid rotation of the impeller blades. The high level of sludge agitation intensity caused a fast completion of the oxidation reactions and it resulted in the high percentage conversion of WP to PO4-3 with PO3-3 making up almost all portion of oxyphosphorus compounds. The WP analysis on the treated sludge showed that supernatant solution and solid residue contained an average of 4.2 μg/L and 143 ppm respectively from the sludge containing about 26 g of WP. Further investigation will be required on operational factors to better understand the processes and achieve an optimum condition.

Polymer Nanofibers for Biomedical Engineering

  • Shin, Min-Kyoon;Kim, Seon-Jeong;Kim, In-Young;Kim, Sun-I.
    • Journal of Biomedical Engineering Research
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    • v.29 no.3
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    • pp.173-178
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    • 2008
  • Recent advancements in the electrospinning method enable the production of ultrafine solid and continuous fibers with diameters ranging from a few nanometers to a few hundred nanometers with controlled surface and morphological features. A wide range of biopolymers can be electrospun into mats with a specific fiber arrangement and structural integrity. These features of nanofiber mats are morphologically similar to the extracellular matrix of natural tissues, which are characterized by a wide pore diameter distribution, a high porosity, effective mechanical properties, and specific biochemical properties. This has resulted in various kinds of applications for polymer nanofibers in the field of biomedicine and biotechnology. The current emphasis of research is on exploiting these properties and focusing on determining the appropriate conditions for electrospinning various biopolymers for biomedical applications, including scaffolds used in tissue engineering, wound dressing, drug delivery, artificial organs, and vascular grafts, and for protective shields in specialty fabrics. This paper reviews the research on biomedical applications of electrospun nanofibers.