• Journal of Powder Materials
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• v.3 no.4
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• pp.253-259
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• 1996

The efficiency of thermoelectric devices for different applications is known to depend on the thermoelectric effectiveness of the material which tends to grow with the increase of its chemical homogeneity. Thus an important goal for thermal devices is to obtain chemically homogeneous solid solutions. In this work, the new process with rapid solidification (melt spinning method) followed by hot pressing was investigated to produce homogeneous material. Characteristics of the material were examined with HRD, SEM, EPMA-line scan and bending test. Property variations of the materials were investigated as a function of variables, such as dopant ${CdCl}_{2}$ quantity and hot pressing temperature. Quenched ribbons are very brittle and consist of homogeneous $Bi_2Te_3$, ${Bi}_{2}{Se}_{3}$ solid solutions. When the process parameters were optimized, the maximum figure of merit was 2.038$\times$$10^{-3}K^{-4}. The bending strength of the material hot pressed at 50$0^{\circ}C$ was 8.2 kgf/${mm}^2$.

• Structural Engineering and Mechanics
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• v.76 no.1
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• pp.17-26
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• 2020

The objective of this paper is to study the deformation in transversely isotropic thermoelastic solid using new modified couple stress theory subjected to ramp-type thermal source and without energy dissipation. This theory contains three material length scale parameters which can determine the size effects. The couple stress constitutive relationships are introduced for transversely isotropic thermoelastic solid, in which the curvature (rotation gradient) tensor is asymmetric and the couple stress moment tensor is symmetric. Laplace and Fourier transform technique is applied to obtain the solutions of the governing equations. The displacement components, stress components, temperature change and couple stress are obtained in the transformed domain. A numerical inversion technique has been used to obtain the solutions in the physical domain. The effects of length scale parameters are depicted graphically on the resulted quantities. Numerical results show that the proposed model can capture the scale effects of microstructures.

• Structural Engineering and Mechanics
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• v.76 no.3
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• pp.379-393
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• 2020

In this paper, we propose an automatic procedure to improve the accuracy of finite element solutions using enriched 2D solid finite elements (4-node quadrilateral and 3-node triangular elements). The enriched elements can improve solution accuracy without mesh refinement by adding cover functions to the displacement interpolation of the standard elements. The enrichment scheme is more effective when used adaptively for areas with insufficient accuracy rather than the entire model. For given meshes, an error for each node is estimated, and then proper degrees of cover functions are applied to the selected nodes. A new error estimation method and cover function selection scheme are devised for the proposed adaptive enrichment scheme. Herein, we demonstrate the proposed enrichment scheme through several 2D problems.

• International Journal of Naval Architecture and Ocean Engineering
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• v.6 no.1
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• pp.132-150
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• 2014

In this study, the inertial properties of fully filled liquid in a tank were studied based on the potential theory. The analytic solution was obtained for the rectangular tank, and the numerical solutions using Green's 2nd identity were obtained for other shapes. The inertia of liquid behaves like solid in recti-linear acceleration. But under rotational acceleration, the moment of inertia of liquid becomes small compared to that of solid. The shapes of tank investigated in this study were ellipse, rectangle, hexagon, and octagon with various aspect ratios. The numerical solutions were compared with analytic solution, and an ad hoc semi-analytical approximate formula is proposed herein and this formula gives very good predictions for the moment of inertia of the liquid in a tank of several different geometrical shapes. The results of this study will be useful in analyzing of the motion of LNG/LPG tanker, liquid cargo ship, and damaged ship.

• Journal of the Korean Ceramic Society
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• v.37 no.5
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• pp.491-496
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• 2000

Single phae Pb(Mg1/3Nb2/3)O3-based solid solutions, the Mg2+ of which are replaced by 20mol% of Ni2+, Zn2+, Cd2+, and the Pb2+ of which are replaced by 0∼20 mol% of La3+, were synthesized and their ordering structures of B-site cations were investigated by XRD and TEM. The B'-site cations (Mg2+, Ni2+, Zn2+, Cd2+) are disordered while these B'-site cations and the B"-site cations (Nb5+) are nonstoichiometrically 1:1 ordered within the ordered nano-domains dispersed in the Nb5+-rich disordered matrix. The charge imbalance between the B'-rich ordered nano-domains and the B"-rich disordered matrix are compensated by the doping of electron donor such as La3+, which enhances the degree of nonstoichiometric 1:1 ordering. For a given La3+ content, the degree of nonstoichiometric 1:1 ordering increases as the average ionic size difference between the B'-and B"-site cations increases, Ni2+

• Applied Science and Convergence Technology
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• v.26 no.5
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• pp.143-147
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• 2017

Structural studies on the addition characteristics of Nb ions to $BaTiO_3$ solid solutions were performed by XRD and SEM/EDS technique. The X-ray diffraction peaks of the (111), (200) and (002) planes of Nb-doped $BaTiO_3$ solid solutions with different mole% of Nb were analyzed. We also investigated the relationship between the dielectric and structural properties of Nb-doped $BaTiO_3$. The transition temperatures of $BaTiO_3$ solid solution doped with 0.5mole%Nb and 1.0 mole%Nb were ${\sim}116^{\circ}C$ and ${\sim}87^{\circ}C$, respectively, which were found to be shifted to very low temperature from the transition temperature of pure $BaTiO_3$ (about $125^{\circ}C$). As a result of analysis of 1/K versus T and ln[$(1/K)-(1/K_m)$ versus ($T-T_m$)] of the two compositions used in this experiment, the diffusivity slightly differs from that of pure $BaTiO_3$ at temperatures above Curie temperature. And this characteristic was analyzed by applying the modified Curie-Weiss law.

• Journal of the Korean Ceramic Society
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• v.43 no.11 s.294
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• pp.693-699
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• 2006

Textured $Bi_{0.5}(Na,K)_{0.5}TiO_3-BiFeO_3$ ceramics were prepared by the reactive-templated grain growth process, using platelike $Bi_4Ti_3O_{12}$ particles. The effects of chemical composition in $Bi_{0.5}(Na,K)_{0.5}TiO_3$ on texture development and densification were examined. Textured ceramics were obtained by using $Bi_{0.5}K_{0.5}TiO_3$ as an end member of the solid solution but densification was limited. Dense ceramics were obtained by using $Bi_{0.5}Na_{0.5}TiO_3$ but texture did not develop. Dense, textured ceramics were obtained by using $Bi_{0.5}(Na_{0.5}K_{0.5})_{0.5}TiO_3$.

• Tribology and Lubricants
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• v.35 no.5
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• pp.310-316
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• 2019

This paper presents two methods for designing a high-speed air spindle operated over the rotational speed of 50,000 rpm. The first method is an approximate method, which assumes a symmetric spindle shape even though it is not symmetric in reality. The second is an analysis of rotordynamics using beam and solid models. The approximate method can be used to calculate the bearing load capacities, stiffness and damping coefficients, stability of the shaft system, and response of the forced excitation from the unbalanced mass. Designers can use this method to determine the dimensions of the desired spindle at the first stage of the design. The more detailed behavior of the spindle can be calculated using the rotordynamics theory using beam and solid models based on the Finite Element Method. In this paper, a spindle, with two air bearings, one motor at the end, and two air thrust bearings, is newly developed. The solutions from the two rotordynamics theories are compared with the solution obtained using the approximate method. The three calculations are in agreement, and the procedure for the design of a spindle system, supported on the externally pressurized air bearings, ispresented and discussed.

• Bulletin of the Korean Chemical Society
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• v.6 no.6
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• pp.344-347
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• 1985

Perovskite type oxides of $SrTiO_3,SrZrO_3,and\;SrTi_{1-x}Zr_xO_3$ have been systematically synthesized at $1250^{\circ}C$and $1550^{\circ}C$ with specimens containing additions of up to x=0.9 of zirconium by solid state reactions and characterized by X-ray diffraction. X-ray diffraction studies showed that the compound $SrTi_{1-x}Zr_xO_3$ has cubic structure. The lattice paramters of $SrTi_{1-x}Zr_xO_3$ solid solutions obey the Vegard's law and fairly large increase in volume can acompany the formation of this solution with increasing Zr content(X). Assuming the lattice constants of perovskite type compounds $A(B_{1-x}B'_x)O_3$where $B_{1-x}B'_x$ is $Ti_{1-x}Zr_x$, to be a linear function of the ionic radii of B and B' ions, the disordered ion pair of $Ti^{4+}$and $Zr^{4+}$ was verified from the lattice constants of a series compounds varying x=0,0.05, 0.25, 0.5, 0.75, 0.9, and 1.0 with known isovalent pairs.

• Journal of Electrochemical Science and Technology
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• v.10 no.1
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• pp.55-60
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• 2019

Herein, the effect of counter anions on the formation of a solid electrolyte interphase (SEI) in a propylene carbonate (PC)-based electrolyte solution was investigated. Although the reversible capacities were different, reversible intercalation and de-intercalation of lithium ions occurred in the graphite negative electrode in the PC-based electrolyte solutions containing 1 M $LiClO_4$, $LiPF_6$, $LiBF_4$, and $LiCF_3SO_3$ at low temperature ($-15^{\circ}C$). This indicated that the surface films acted as an effective SEI to suppress further co-intercalation and decomposition reactions at low temperature. However, the SEIs formed at the low temperature were unstable in 1 M $LiPF_6$ and $LiBF_4/PC$ at room temperature ($25^{\circ}C$). On the other hand, increasing reversible capacity was confirmed in the case of $LiCF_3SO_3/PC$ at room temperature, because the SEI formed at the low temperature was still maintained. These results suggest that counter anions are an important factor to consider for the formation of effective SEIs in PC-based electrolyte solutions.