• 제목/요약/키워드: Solid oxide fuel cell(SOFC)

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Issues Related to the Modeling of Solid Oxide Fuel Cell Stacks

  • Yang Shi;Ramakrishna P.A.;Sohn Chang-Hyun
    • Journal of Mechanical Science and Technology
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    • 제20권3호
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    • pp.391-398
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    • 2006
  • This work involves a method for modeling the flow distribution in the stack of a solid oxide fuel cell. Towards this end, a three dimensional modeling of the flow through a Solid Oxide Fuel Cell (SOFC) stack was carried out using the CFD analysis. This paper examines the efficacy of using cold flow analysis to describe the flow through a SOFC stack. It brings out the relative importance of temperature effect and the mass transfer effect on the SOFC manifold design. Another feature of this study is to utilize statistical tools to ascertain the extent of uniform flow through a stack. The results showed that the cold flow analysis of flow through SOFC might not lead to correct manifold designs. The results of the numerical calculations also indicated that the mass transfer across membrane was essential to correctly describe the cathode flow, while only temperature effects were sufficient to describe the anode flow in a SOFC.

원자층 증착법을 통한 고체산화물 연료전지의 세라믹 인터페이스 제어 (Control of solid oxide fuel cell ceramic interfaces via atomic layer deposition)

  • 서종수;정우철;김정환
    • 세라미스트
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    • 제23권2호
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    • pp.132-144
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    • 2020
  • Solid oxide fuel cell (SOFC) have attracted much attention due to clean, efficient and environmental-friendly generation of electricity for next-generation energy conversion devices. Recently, many studies have been reported on improving the performance of SOFC electrodes and electrolytes by applying atomic layer deposition (ALD) process, which has advantages of excellent film quality and conformality, and precise control of film thickness by utilizing its unique self-limiting surface reaction. ALD process with these advantages has been shown to provide functional ceramic interfaces for SOFC electrodes and electrolytes. In this article, recent examples of successful functionalization and stabilization on SOFC electrodes and electrolytes by the application of ALD process for realizing high performance SOFC cells are reported.

Solid Oxide Fuel Cells Designs, Materials, and Applications

  • Singhal Subhash C.
    • 한국세라믹학회지
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    • 제42권12호
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    • pp.777-786
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    • 2005
  • The Solid Oxide Fuel Cell (SOFC) is an electrochemical device to convert chemical energy of a fuel into electricity at temperatures from about 600 to $1000^{\circ}C$. The SOFC offers certain advantages over lower temperature fuel cells, notably its ability to use CO as a fuel rather than being poisoned by it, and high grade exhaust heat for combined heat and power, or combined cycle gas turbine applications. This paper reviews the operating principle, materials for different cell and stack components, cell designs, and applications of SOFCs. Among all designs of Solid Oxide Fuel Cells (SOFCs), the most progress has been achieved with the tubular design. However, the electrical resistance of tubular SOFCs is high, and specific power output $(W/cm^2)$ and volumetric power density $(W/cm^3)$ low. Planar SOFCs, in contrast, are capable of achieving very high power densities.

금속지지체형 고체산화물 연료전지의 열 및 물질전달 특성에 대한 전산해석 (Numerical Analysis of the Heat and Mass Transfer Characteristics in Metal-Supported Solid Oxide Fuel Cell)

  • 박준근;김선영;배중면
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2009년도 추계학술대회 논문집
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    • pp.143-146
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    • 2009
  • The metal-supported SOFC has beed developed as a new concept of SOFC which has higher mechanical strength. However, the mass transfer rate in this type of SOFC may be decreased due to the contact layer and the support layer and that can cause the low performance. Therefore, numerical analysis of the heat and mass transfer characteristics in a metal-supported solid oxide fuel cell(SOFC) is studied in this paper. Governing equations and electrochemical equations are calculated simultaneously. And the numerical results are compared with the experimental results for the code validation. The current density, temperature, and pressure drop are suggested as numerical results.

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유동 해석을 이용한 평판형 고체 산화물 연료전지의 성능 특성 분석 (I) - 등온 모델 - (Performance Predictions of the Planar-type Solid Oxide Fuel Cell with Computational Flow Analysis (I) - Isothermal Model -)

  • 현희철;손정락;이준식;노승탁
    • 대한기계학회논문집B
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    • 제27권5호
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    • pp.635-643
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    • 2003
  • Parametric study for the analysis of performance characteristics of a planar -type solid oxide fuel cell(SOFC) using computational flow analysis is conducted. A planar -type SOFC, which is composed by two gas channels (fuel and ai.) and one set of anode-electrolyte-cathode assembly, is modeled as a two -dimensional isothermal case. Results of computational analysis of flow field including distributions of mass fractions in gas channels are used to the performance analysis of the fuel cell. Flow analysis makes it possible to consider current density distributions along the length of the cell in the process of performance analysis of the SOFC. As results of parametric study, it is found that the mole fraction of fuel at the inlet of fuel channel, operating pressure and temperature are closely related to the performance characteristics of SOFC.

3D 프린팅 공정을 이용한 고체 산화물 연료전지 연구 동향 (Recent Activities of Solid Oxide Fuel Cell Research in the 3D Printing Processes)

  • 주바이르 마사우드;무하마드 주바이르 칸;암자드 후세인;하피즈 아흐마드 이시팍;송락현;이승복;조동우;임탁형
    • 한국수소및신에너지학회논문집
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    • 제32권1호
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    • pp.11-40
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    • 2021
  • Solid oxide fuel cell (SOFC) has received significant attention recently because of its potential for the clean and efficient power generation. The current manufacturing processes for the SOFC components are somehow complex and expensive, therefore, new and innovative techniques are necessary to provide a great deal of cell performance and fabricability. Three-dimensional (3D) printing processes have the potential to provide a solution to all these problems. This study reviews the literature for manufacturing the SOFC components using 3D printing processes. The technical aspects for fabrication of SOFC components, 3D printing processes optimization and material characterizations are discussed. Comparison of the SOFC components fabricated by 3D printing to those manufactured by conventional ceramic processes is highlighted. Further advancements in the 3D printing of the SOFC components can be a step closer to the cost reduction and commercialization of this technology.

고체산화물 연료전지의 동적 성능 특성 해석 (Analysis of Dynamic Performance of Solid Oxide Fuel Cells)

  • 양진식;손정락;노승탁
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2004년도 추계학술대회
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    • pp.1652-1657
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    • 2004
  • Model for the dynamic simulation of dynamic behaviors of a solid oxide fuel cell (SOFC) is provided. This model is based upon (1) coupled mass and heat transfer characteristics and (2) important chemical reactions such as electrochemical and reforming reaction in high temperature fuel cells such as SOFC. It is found that the thermal inertia of solid materials in SOFC plays an important role to the dynamic behavior of cell temperature. Dynamic characteristics of cell voltage, power and chemical compositions with different levels of load changes are investigated.

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갑작스런 부하 변동에 따른 고체산화물 연료전지의 동적 성능 거동 특성에 관한 연구 (A Study on the Dynamic Performance Behavior of Solid Oxide Fuel Cells with Stepwise Load Changes)

  • 손정락;노승탁;양진식
    • 대한기계학회논문집B
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    • 제29권4호
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    • pp.477-484
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    • 2005
  • Model fer the dynamic simulation of dynamic behaviors of a solid oxide fuel cell (SOFC) is provided. This model is based upon (1) coupled mass and heat transfer characteristics and (2) important chemical reactions such as electrochemical and reforming reactions in high temperature fuel cells such as SOFC. It is found that the thermal inertia of solid materials in SOFC plays an important role to the dynamic behavior of cell temperature. Dynamic characteristics of cell voltage, power, and chemical compositions with different levels of load change are investigated.

Thermodynamic analysis of a combined gas turbine power plant with a solid oxide fuel cell for marine applications

  • Welaya, Yousri M.A.;Mosleh, M.;Ammar, Nader R.
    • International Journal of Naval Architecture and Ocean Engineering
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    • 제5권4호
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    • pp.529-545
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    • 2013
  • Strong restrictions on emissions from marine power plants (particularly $SO_x$, $NO_x$) will probably be adopted in the near future. In this paper, a combined solid oxide fuel cell (SOFC) and gas turbine fuelled by natural gas is proposed as an attractive option to limit the environmental impact of the marine sector. It includes a study of a heat-recovery system for 18 MW SOFC fuelled by natural gas, to provide the electric power demand onboard commercial vessels. Feasible heat-recovery systems are investigated, taking into account different operating conditions of the combined system. Two types of SOFC are considered, tubular and planar SOFCs, operated with either natural gas or hydrogen fuels. This paper includes a detailed thermodynamic analysis for the combined system. Mass and energy balances are performed, not only for the whole plant but also for each individual component, in order to evaluate the thermal efficiency of the combined cycle. In addition, the effect of using natural gas as a fuel on the fuel cell voltage and performance is investigated. It is found that a high overall efficiency approaching 70% may be achieved with an optimum configuration using SOFC system under pressure. The hybrid system would also reduce emissions, fuel consumption, and improve the total system efficiency.

SOFC 스택 안전성능 평가 시스템 제작을 위한 평가항목 도출에 관한 연구 (A Study of Deduction of evaluation Items for Design of SOFC stack safety performance evaluation system)

  • 박태성;남태호;이덕권;이승국;문종삼
    • 한국가스학회지
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    • 제21권6호
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    • pp.81-87
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    • 2017
  • SOFC(Solid Oxide Fuel Cell)는 고온 연료전지 중 하나이며, SOFC 시스템과 스택은 고온 운전 특성을 가지고 있다. 이러한 특성 때문에 시스템 설계 및 재료의 선택, 내구성 확보, 안전성능 확보에 많은 어려움을 가지고 있다. 따라서 SOFC 연료전지의 상용화와 보급을 위해서는 안전성능 평가기술과 평가시스템의 개발이 병행되어야 한다. 본 연구에서는 스택 안전성능 평가시스템의 제작을 위하여 국내 외 SOFC 관련규격 및 스택의 위험요소를 분석하였다. 분석한 자료를 바탕으로 스택 안전성능 평가 시스템의 제작을 위한 평가항목을 도출하였다. 본 연구 결과를 통해 SOFC 연료전지의 보급 활성화와 안전한 사용 환경에 기여할 수 있기를 기대한다.