• 제목/요약/키워드: Solid Separation

검색결과 504건 처리시간 0.027초

캡슬에 고정화된 흡착제에의 Berberine의 흡착에 관한 수학적 모델 (Mathematical Model for Adsorption of Berberine on Encapsulated Adsorbent)

  • 최정우;조상원이원홍
    • KSBB Journal
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    • 제10권4호
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    • pp.358-369
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    • 1995
  • A mathematical model using local thermodynamic equilibrium isotherms for adsorption in encapsulated adsorbent is proposed in order to optimize the design parameters in situ bioproduct separation process. The model accurately follows the experimental data on the adsorption of berberine, secondary metabolite produced in Thaictrum rugosum plant cell culture. The adsorption rate on encapsulated adsorbent is compared with that on alginate-entrapped adsorbent. The result shows that the higher loading capacity in encapsulated adsorbent is mainly due to the increase in the maximum solid phase concentration. Based on the adsorption rate and loading capacity, the encapsulated adsorbent would be more useful than the entrapped adsorbent when used in situ bioproduct separation process. Design parameters in situ bioproduct separation process, such as the size of the capsule, membrane thickness, the ratio of capsule volume to bulk volume, the ratio of single capsule volume to total capsule volume and the adsorbent content in the capsule, are evaluated by using the model. The ratio of single capsule volume to total capsule volume is the most effective parameter for adsorption of berberine on encapsulated adsorbent.

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납 표준물질을 이용한 방사성동위원소 Thallium-201의 화학적 분리공정 개발 (Development of Chemical Separation Process for Thallium-201 Radioisotope with Lead Standard Material)

  • 이준영;김태현;박정훈
    • 방사선산업학회지
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    • 제17권4호
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    • pp.543-549
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    • 2023
  • Thallium-201 (201Tl) is a medical radioisotope which emits gamma rays when it decays and used in myocardial perfusion scans in single-photon emission tomography due to its similar properties to potassium. Currently, the Korea Institute of Radiological & Medical Sciences is the only institution producing 201Tl in Korea, and optimization of 201Tl production research is necessary to meet supply compared to domestic demand. To this end, technical analysis of plating target production and chemical separation methods essential for 201Tl production research is conducted. It deals with the process of generating and separating 201Tl radioisotope and target production, It can be generated through a nuclear reaction such as natHg(p,xn)201Tl, 201Hg(p,n)201Tl, natPb(p,xn)201Bi → 201Pb → 201Tl, 205Tl(p,5n)201Pb → 201Tl, and considering impure nuclide generated simultaneously with the use of proton beam energy of 35 MeV or less, it is intended to be produced using the 203Tl(p,3n)201Pb→201Tl nuclear reaction. In particular, the chemical separation of Tl is a very important element, and the chemical separation methods that can separate it is broadly divided into four types, including solid phase extraction, liquid-liquid, electrochemical, and ion exchange membrane separation. Some chemical separations require additional separation steps, such as methods using selective adsorption. Therefore, this technical report describes four chemical separation methods and seeks to separate high-purity 201Tl using a method without additional separation steps

알루미늄합금의 반용융 단조 및 주조공정에 관한 수치해석 (Numerical Analysis on Semi-Solid Forging and Casting Process of Aluminum Alloys)

  • 강충길;임미동
    • 소성∙가공
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    • 제6권3호
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    • pp.239-249
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    • 1997
  • The behaviour of alloys in the semi-solid state strongly depends on the imposed stress state and on the morphology of the phase which can vary from dendritic to globular. To optimal net shape forging of semi-solid materials, it is important to investigate for filling phenomena in forging process of arbitrarily shaped dies. To produce a automotive part which has good mechanical property, the filling pattern according to die velocity and solid fraction distribution has to be estimated for arbitrarily shaped dies. Therefore, the estimation of filling characteristic in the forging simulation with arbitrarily shaped dies of semi-solid materials are calculated by finite element method with proposed algorithm. The proposed theoretical model and a various boundary conditions for arbitrarily shaped dies is investigated with the coupling calculation between the liquid phase flow and the solid phase deformation. The simulation process with arbitrarily shaped dies is performed to the isothermal conditions of two dimensional problems. To analysis of forging process by using semi-solid materials, a new stress-strain relationship is described, and forging analysis is performed by viscoelastic model for the solid phase and the Darcy's law for the liquid flow. The calculated results for forging force and filling limitations will be compared to experimental data. The filling simulation of simple products performed with the uniform billet temperature(584$^{\circ}C$) from the induction heating by the commercial package MAGMAsoft. The initial step of computation is the touching of semi-solid material with the end of die gate and the initial concept of proposed system just fit with the capability of MAGMAsoft.

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촉진수송 및 태양전지용 분리막 (Polymer Electrolytes and their Application to Solar Cells and Separation Membranes)

  • 강용수
    • 한국막학회:학술대회논문집
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    • 한국막학회 2004년도 첨단 분리막 연구동향
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    • pp.13-35
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    • 2004
  • Metal Complexes in Macromolecules Applications of Polymer Electrolyte Membranes Facilitated Transport in Solid State Roles of Electrolytes in Solar Cells - Electrolytes :ㆍI- and $I_3$-conductor ㆍelectron barrier or hole conductor ㆍelectrochemical redox reaction media ㆍinterfacial contactor for dye, $TiO_2$ and electrode ㆍmechanical separator (omitted)

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고온 협기성 연속회분식 공정에 의한 도시하수슬러지 소화 (Thermophilic Sewage Sludge Digestion by Anaerobic Sequencing Batch Reactor)

  • 허준무;박종안;이종화;손부순;장봉기
    • 환경위생공학
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    • 제14권3호
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    • pp.130-138
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    • 1999
  • The feasibility of municipal sewage sludge digestion was investigated by using thermophilic anaerobic sequencing batch reactor(ASBR). One-day settle time was enough for the high performance of solid-liquid separation. The conversion of semi-continuous mode to sequencing batch mode is easily achieved without any adverse effects, although the large amount of sludge equal to the volume ratio of 0.3~06 to reactor volume was added in the feed step of the start-up. The ASBRs had higher conversion capability of organics to biogas than the control reactor. Gas yields of the ASBRs were increased by the average of 50% over the control reactor across a range of hydraulic retention time(HRT)s from 10days to 5days. The thermophilic reactors showed higher gas production than mesophilic reactor. Removal efficiencies of organic matter exceeded 80% on the basis of supernatants, except that at the reactor. Solid-liquid separation was essential in the performance of the ASBR, especially, at the lower HFT. The ASBRs were highly efficient in the retention of activated biomass within the reactor. thus compensating for increased equivalent organic loading rate through increased solids retention times followed by the increased solids, while maintaining shorter HRTs.

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펄스분리장치의 이중 슬릿형 파열판 매개변수 연구 (A Parametric Study on Double-Slit-Type Rupture Disc of Pulse Separation Device)

  • 한혁섭;조원만;이원복;구송회;이방업
    • 한국추진공학회지
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    • 제14권5호
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    • pp.101-110
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    • 2010
  • 이중 펄스 로켓 추진기관은 하나의 연소관 안에 특성이 다른 2개의 추진제가 격벽에 의해 2개의 공간에 분리되어 있는 고체 추진기관이다. 유한요소법을 이용한 탄소성 동적거동해석에 의하여 펄스분리 장치 파열판의 파열해석을 수행하였다. 파열판의 슬릿 크기를 변경한 해석을 수행하여 파열형상, 파열시점을 해석함으로써 슬릿의 설계 변수가 파열판에 미치는 영향을 검토하였다. 해석 결과는 펄스분리 장치 파열판 슬릿 크기의 변경을 통한 파열압력의 조절에 사용할 수 있다.

하수처리시설의 Retrofitting을 위한 파일럿 규모 공기부상공정 연구 (A Pilot Study on Air Flotation Processes for Retrofitting of Conventional Wastewater Treatment Facilities)

  • 박찬혁;홍석원;이상협;최용수
    • 상하수도학회지
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    • 제22권3호
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    • pp.329-336
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    • 2008
  • The pilot study was conducted to evaluate the applicability of air flotation(AF) processes combined with biological nutrient removal(BNR) for the retrofitting of conventional wastewater treatment facilities. The BNR system was operated in pre-denitrification and intermittent aeration; developed ceramic membrane diffusers were installed to separate the solid-liquid of activated sludge at the bottom of a flotation tank. Before performing a pilot scale study, the size distribution of microbubbles generated by silica or alumina-based ceramic membrane diffusers was tested to identify the ability of solid-liquid separation. According to the experimental results, the separation and thickening efficiency of the alumina-based ceramic membrane diffuser was higher than the silica-based ceramic membrane diffuser. In a $100m^3/d$ pilot plant, thickened and return sludge concentration was measured to be higher than 15,000mg SS/L, therefore, the MLSS in the bioreactor was maintained at over 3,000mg SS/L. The effluent quality of the AF-BNR process was 4.2mg/L, 3.7mg/L, 10.6mg/L and 1.6mg/L for $BOD_5$, SS, T-N and T-P, respectively. Lastly, it was revealed that the unit treatment cost by flotation process is lower than about $1won/m^3$ compared to a gravity sedimentation process.

Recovery and Refining Process of Gypsum from Waste Plaster Board

  • Song, Young-Jun;Hiroki Yotsumoto
    • 자원리싸이클링
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    • 제10권6호
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    • pp.43-52
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    • 2001
  • This study was conducted to obtain granular crystalline gypsum that can be used as raw material for Plaster boards or cements from waste Plaster board. Gypsum could be Preferentially disintegrated to gypsum needle in $10\mu\textrm{m}$ or less size by hydration after the dehydration of crushed waste Plaster board. The finer the gypsum needle, it is easier to remove coarse impurities and to recover the gypsum needle. The optimum conditions for obtain the finer gypsum size were dehydration rate of 75~85%, solid concentration at hydration of 10~15%, agitation speed of 250~400 rpm, crushing size before dehydration of 2 cm or less. Gypsum of 98.21% grade was recovered with 99.0% yield as the undersize of 325 mesh wet screening followed by the dehydration-hydration process performed at the conditions of dehydration rate of 80%, solid concentration at hydration of 15%, agitation speed of 300 rpm, crushing size before dehydration of 2 cm or less. After the recrystallization of recovered gypsum, Plate-like gypsum of $151\mu\textrm{m}$ size with 99.49% grade was obtained as the oversize of 270 mesh in a wet screening.

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