• Title/Summary/Keyword: Solid Phase Forming

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Semi-Solid Forming of Al-Zn-Mg-Cu Alloy Applying Low-Temperature Casting Process (저온 주조법을 응용한 Al-Zn-Mg-Cu 합금의 반응고 성형)

  • Kim, Jeong-Min;Kim, Ki-Tae;Jung, Woon-Jae
    • Journal of Korea Foundry Society
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    • v.22 no.2
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    • pp.82-88
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    • 2002
  • Al-5.5Zn-2.5Mg-l.5Cu semi-solid slurry was prepared by cooling the liquid metal with a low superheat to a solid and liquid co-existing temperature. Relatively round solid particles could be obtained in the slurry through the simple process. The prepared slurry was deformed into the metallic mold by a press and the mechanical properties of obtained specimens were investigated. Mold filling ability of the alloy slurry was also investigated and compared with that of A356 alloy. Al-Zn-Mg-Cu alloy showed lower mold filling ability than A356 alloy probably because small amount of eutectic phase is present and the heat of fusion generated during solidification is smaller than that of A356 alloy.

The Effects of Alloying Elements and Cooling Rates on the Formation of Phosphide Eutectics of Wear Resistance CV Graphite Cast Irons (내마모 CV흑연주철의 공정인화물 형성에 미치는 합금원소 및 냉각속도의 영향)

  • Park, Heung-Il;Kim, Myung-Ho
    • Journal of Korea Foundry Society
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    • v.9 no.4
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    • pp.311-319
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    • 1989
  • The effects of the alloying elements and cooling rates on the formation of phosphide eutectics of compacted vermicular graphite cast irons containing copper, tin, molybdenum for producing pearlitic matrix, and also containing phosphorus and boron for increasing wear resistance, were investigated. The liquidus phosphide eutectic was found to solidify as a pseudo-binary phosphide eutectic, but with increasing of the cooling rate non-equlibrium phosphide eutectic with needle type carbide could be formed. However, the liquidus phosphide eutectic containing both phosphorus and carbide-forming boron was found to solidify always as a non-equlibrium phosphide eutectic with coarse carbide, independent from the cooling rate. It was also confirmed that the tiny isolated phase observed by SEM was gamma iron solid solution with phosphorus, silicon, molybdenum and the matrix containing these tiny islands was phosphide phase containing manganese and molybdenum. The addition of copper was found to decrease the tendency of forming ledeburitic carbides in the phosphide eutectic.

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Analysis of the Phase Formation and the Sinterability of K+-β/β"-Al2O3 at High Temperatures (≥1600 ℃) (K+-β/β"-Al2O3의 고온 상관계와 소결성 분석)

  • Jang, Min-Ho;Kim, Seung-Gyun;Kim, Seok-Jun;Haw, Jung-Rim;Lim, Sung-Ki
    • Applied Chemistry for Engineering
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    • v.20 no.3
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    • pp.317-321
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    • 2009
  • In order to analyze the high temperature phase formation and the sinterability of super ionic conductor $K^+-{\beta}/{\beta}"-Al_2O_3$ which is commonly used as a solid oxide electrolyte, the pure $K^+-{\beta}/{\beta}"-Al_2O_3$ powder in the ternary system $K_2O-LiO_2-Al_2O_3$ was synthesized by solid state reaction and formed to tube and disk using slip casting method and cold isostatic pressing (CIP), respectively. The slip casting was conducted in an alumina mold with the slurry containing 40 wt% of solid contents and the CIP was carried out under 20 MPa. The samples were sintered at $1600^{\circ}C$, $1700^{\circ}C$ and $1750^{\circ}C$, respectively, and their phase formation and the sintering density were investigated according to the forming method. The samples produced by CIP showed far higher ${\beta}"-Al_2O_3$ fraction as compared with those by slip casting. On the other hand, the samples by slip casting showed slightly higher sintering density. The relative density reached to about 83% at $1750^{\circ}C$ and for 1 h, independent of the forming method. In the case of 90 min socking time, the density was decreased owing to the exaggerated grain growth and the pores by $K_2O$ evaporation.

The grain size control of A356 alloy by electromagnetic stirring (전자교반을 이용한 A356 합금의 결정립제어)

  • Bae J.W.;Kang C.G.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2006.05a
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    • pp.247-248
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    • 2006
  • In this study, the morphology of the change of primary Al phase in A356 alloy by two kinds of electromagnetic stirrers(vertical and horizontal) were investigated to obtain the globular structure. The effects of the stirring current, the stirring time and the pouring temperature were determined. The greater stirring current and longer stirring time were to get the finer the Al phase. However, over a certain stirring current and stirring time, the primary Al was merged together and was increased. The reason is the degree of breakdown of initial dendrites has been decreased by the collision and coalescence of particles with increasing stirring current and stirring time. The optimum conditions and difference of the two kinds of electromagnetic stirrers have been investigated for rheology forming with controlled solid fraction.

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Fabrication of Functional Nanomaterials by Peptide Self-Assembly

  • Park, Chan-Beom
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2009.05a
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    • pp.8.1-8.1
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    • 2009
  • The self-assembly of peptide-based building blocks into nanostructures is an attractive route for fabricating novel materials because of their capacity for molecular recognition and functional flexibility as well as the mild conditions required in the fabrication process. Among various peptide-based building blocks forming nanostructures, the simplest building blocks are aromatic dipeptides like diphenylalanine, which can readily self-assemble into nanotubes in aqueous solutions at ambient conditions. Recently, we have developed a high-temperature solid-phase self-assembly process for diphenylalanine. Through this novel process, we succeeded in the growth of vertically well-aligned, uniform nanowires from amorphous peptide thin film. To demonstrate the versatility of our approach, we also fabricated a micropattern of peptide nanowires by combining our solid-phase growth method and simple soft lithographic techniques. We believe that our studies on peptide self-assembly will provide a new horizon for peptide-based nanofabrication.

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Schottky Barrier Thin Film Transistor by using Platinum-silicided Source and Drain (플레티늄-실리사이드를 이용한 쇼트키 장벽 다결정 박막 트랜지스터)

  • Shin, Jin-Wook;Chung, Hong-Bay;Lee, Young-Hie;Cho, Won-Ju
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.22 no.6
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    • pp.462-465
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    • 2009
  • Schottky barrier thin film transistors (SB-TFT) on polycrystalline silicon(poly-Si) are fabricated by platinum silicided source/drain for p-type SB-TFT. High quality poly-Si film were obtained by crystallizing the amorphous Si film with excimer laser annealing (ELA) or solid phase crystallization (SPC) method, The fabricated poly-Si SB-TFTs showed low leakage current level and a large on/off current ratio larger than 10), Significant improvement of electrical characteristics were obtained by the additional forming gas annealing in 2% $H_2/N_2$ ambient, which is attributed to the termination of dangling bond at the poly-Si grain boundaries as well as the reduction of interface trap states at gate oxide/poly-Si channel.

The Stress-strain Relationship of Glass Fiber Reinforced Thermoplastic Composite (유리섬유 강화 열가소성 복합재료의 응력-변형률 관계)

  • 이중희
    • Transactions of the Korean Society of Automotive Engineers
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    • v.4 no.5
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    • pp.206-214
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    • 1996
  • Because of the wide variety of the composite materials, inherent variability in properties, and complex temperature and strain rate dependence, large strain behavior of these materials has not been well characterized. Large strain behavior under uniaxial tension is characterized over a range of temperatures and strain rates, and a modified simple linear viscoelastic model is fit to the observed data. Of particular importance is the strain rate and temperature dependence of these composites, and it is the primary focus of this study. The strain rate and temperature dependence is then used to predict limiting tensile strains, based on Marciniak imperfection theory. Excellent correlation was obtained between model and experiment and the results are summarized in maps of forming limit as a function of strain rate and temperature.

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Structural Design and Characterization of a Channel-forming Peptide

  • Krittanai, Chartchai;Panyim, Sakol
    • BMB Reports
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    • v.37 no.4
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    • pp.460-465
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    • 2004
  • A 16-residue polypeptide model with the sequence acetyl-YALSLAATLLKEAASL-OH was derived by rational de novo peptide design. The designed sequence consists of amino acid residues with high propensity to adopt an alpha helical conformation, and sequential order was arranged to produce an amphipathic surface. The designed sequence was chemically synthesized using a solid-phase method and the polypeptide was purified by reverse-phase liquid chromatography. Molecular mass analysis by electro-spray ionization mass spectroscopy confirmed the correct designed sequence. Structural characterization by circular dichroism spectroscopy demonstrated that the peptide adopts the expected alpha helical conformation in 50% acetonitrile solution. Liposome binding assay using Small Unilamellar Vesicle (SUV) showed a marked release of entrapped glucose by interaction between the lipid membrane and the tested peptide. The channel-forming activity of the peptide was revealed by a planar lipid bilayer experiment. An analysis of the conducting current at various applied potentials suggested that the peptide forms a cationic ion channel with an intrinsic conductance of 188 pS. These results demonstrate that a simple rational de novo design can be successfully employed to create short peptides with desired structures and functions.

A. Study on the PAAS(Polyamic Acid Alkylamine Salts) Langmuir Films and Langmuir-Blodgett Films using BAM(Brewster angle microscopy) (BAM(Brewster angle microscopy)을 이용한 PAAS(Polyamic Acid Alkylamine Salts)의 Langmuir막과 Langmuir-Blodgett막의 특성 연구)

  • 이승엽;강도열;김태완
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1996.11a
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    • pp.147-151
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    • 1996
  • Brewster angle microscopy(BAM) makes it possible to observe the monolayer states on the water subphase and the phase transitions from a gaseous phase via a expanded phase to a condensed phase. Also BAM can be used to observe the films on the solid substrate such as Langmuir-Blodgett(LB) films. In this Paper Polyamic Acid Alkylamine Salts(PAAS) was used for forming L films and LB films and $\pi$-A isotherm showed pressure of each phase. We obtained BAM images as surface pressure increased. Images of LB films were compared with data from ellipsometry which was used to measure the film thickness. Images of both L films and LB films were analyzed with computer in the point of brightness.

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The Effects of Pre-strainon Tensile Properties in Solid-Phase Forming of Thermoplastic Composite (고상성형시 변형률이 열가소성 복합재료의 인장특성에 미치는 영향)

  • 조현철;이중희;김병선
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 1999.11a
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    • pp.194-197
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    • 1999
  • 고분자 복합재료는 금속에 비하여 경량, 고강도, 고탄성율 등의 장점을 가지고 있어 여러 산업에서 기존의 금속 재료를 대체할 수 있는 재료로서 그 사용이 점차 증가하고 있다[1-5]. 특히 사회적으로 환경 문제가 대두되면서 열가소성 복합재료에 대한 관심이 높아지고 있으며 이에 대한 연구가 더욱 요구되고 있다. (중략)

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