• Title/Summary/Keyword: Solid Oxide Fuel Cell

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Issues Related to the Modeling of Solid Oxide Fuel Cell Stacks

  • Yang Shi;Ramakrishna P.A.;Sohn Chang-Hyun
    • Journal of Mechanical Science and Technology
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    • v.20 no.3
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    • pp.391-398
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    • 2006
  • This work involves a method for modeling the flow distribution in the stack of a solid oxide fuel cell. Towards this end, a three dimensional modeling of the flow through a Solid Oxide Fuel Cell (SOFC) stack was carried out using the CFD analysis. This paper examines the efficacy of using cold flow analysis to describe the flow through a SOFC stack. It brings out the relative importance of temperature effect and the mass transfer effect on the SOFC manifold design. Another feature of this study is to utilize statistical tools to ascertain the extent of uniform flow through a stack. The results showed that the cold flow analysis of flow through SOFC might not lead to correct manifold designs. The results of the numerical calculations also indicated that the mass transfer across membrane was essential to correctly describe the cathode flow, while only temperature effects were sufficient to describe the anode flow in a SOFC.

Numerical Analysis of the Heat and Mass Transfer Characteristics in Metal-Supported Solid Oxide Fuel Cell (금속지지체형 고체산화물 연료전지의 열 및 물질전달 특성에 대한 전산해석)

  • Park, Joon-Guen;Kim, Sun-Young;Bae, Joong-Myeon
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.11a
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    • pp.143-146
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    • 2009
  • The metal-supported SOFC has beed developed as a new concept of SOFC which has higher mechanical strength. However, the mass transfer rate in this type of SOFC may be decreased due to the contact layer and the support layer and that can cause the low performance. Therefore, numerical analysis of the heat and mass transfer characteristics in a metal-supported solid oxide fuel cell(SOFC) is studied in this paper. Governing equations and electrochemical equations are calculated simultaneously. And the numerical results are compared with the experimental results for the code validation. The current density, temperature, and pressure drop are suggested as numerical results.

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Performance behavior of solid oxide fuel cell with various anode gas (개질 가스특성에 따른 고체산화물 연료전지의 성능 변화)

  • Park, Kwang-Jin;Bae, Joong-Myeon
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.10a
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    • pp.59-62
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    • 2008
  • The performance behavior of solid oxide fuel cell using reformate gas as fuels was investigated. When the pre-reformate gas was used without steam, the maximum power density was 50% lower than that using H2. This may be due to carbon deposition caused by the pyrolysis of remaining hydrocarbons. However, when the steam was added, the maximum power density showed a relatively small variation according to reformate gas. When pre-reformate gas with steam was fed into anode, the SOFC showed the stable performance without sharp voltage drop during 10h operation.

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Control of solid oxide fuel cell ceramic interfaces via atomic layer deposition (원자층 증착법을 통한 고체산화물 연료전지의 세라믹 인터페이스 제어)

  • Seo, Jongsu;Jung, WooChul;Kim, Jeong Hwan
    • Ceramist
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    • v.23 no.2
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    • pp.132-144
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    • 2020
  • Solid oxide fuel cell (SOFC) have attracted much attention due to clean, efficient and environmental-friendly generation of electricity for next-generation energy conversion devices. Recently, many studies have been reported on improving the performance of SOFC electrodes and electrolytes by applying atomic layer deposition (ALD) process, which has advantages of excellent film quality and conformality, and precise control of film thickness by utilizing its unique self-limiting surface reaction. ALD process with these advantages has been shown to provide functional ceramic interfaces for SOFC electrodes and electrolytes. In this article, recent examples of successful functionalization and stabilization on SOFC electrodes and electrolytes by the application of ALD process for realizing high performance SOFC cells are reported.

Concept, Manufacture and Results of the Microtubular Solid Oxide Fuel Cell

  • Sammes, Nigel;Galloway, Kevin;Yamaguchi, Toshiaki;Serincan, Mustafa
    • Transactions on Electrical and Electronic Materials
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    • v.12 no.1
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    • pp.1-6
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    • 2011
  • This paper summarized concept, manufacture and results of the micro-tubular solid oxide fuel cells (SOFCs). The cells were fabricated by co-sintering of extruded micro-tubular anode support and electrolyte coating layer, and then additional cathode coating. The cells showed quick voltage rising within 1 minute, and the electrochemical performances were closely related to the balance of fuel utilization and performance loss. And a thermal-fluid simulation model was also reported in combination with the electrochemical evaluation results on the GDC-based micro-tubular SOFCs.

Performance Predictions of the Planar-type Solid Oxide Fuel Cell with Computational Flow Analysis (II) - Non-isothermal Model - (유동 해석을 이용한 평판형 고체 산화물 연료전지의 성능 특성 분석 (II) - 비등온 모델 -)

  • Hyun, Hee-Chul;Sohn, Jeong L.;Lee, Joon-Sik;Ro, Sung-Tack
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.27 no.7
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    • pp.963-972
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    • 2003
  • Performance characteristics of the planar-type solid oxide fuel cell (SOFC) are investigated by the analysis of flow fields coupled with heat and mass transfer phenomena in anode and cathode channels. For these purposes, performance analysis of the SOFC is conducted based on electrochemical reaction phenomena in electrodes and electrolyte coupled with flow fields in anode and cathode channels. In the present study, the isothermal model adopted in the previous paper prepared by the same authors is extended to the non-isothermal model by solving energy equation additionally with momentum and mass transfer equations using CFD technique. It is found that the difference between isothermal and non-isothermal models come from non-uniform temperature distribution along anode and cathode electrodes by solving energy equation in non-isothermal model. Non-uniform temperature distribution in non-isothermal model contributes to the increase of average temperature of the fuel cell and influences its performance characteristics.

Development of Tubular Solid Oxide Fuel Cells with Advanced Anode Current Collection (연료극 집전체 최적화를 적용한 원통형 고체산화물 연료전지 단전지 성능 향상)

  • Kim, Wanje;Lee, Seungbok;Song, Rakhyun;Park, Seokjoo;Lim, Takhyoung;Lee, Jongwon
    • Transactions of the Korean hydrogen and new energy society
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    • v.24 no.6
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    • pp.480-486
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    • 2013
  • In this study, tubular SOFC unit cell with advanced anode current collector was fabricated to improve the cell performance. First, we prepared two types of single cells having the same manufacture processes such as the same electrolyte, electrode coating condition and sintering processes. And then to compare the developed single cell performance with conventional cells, we changed the anode current collecting methods. From the impedance analysis and I-V curve analysis, the cell performance of advanced cell is much higher than that of conventional cell.

Characterization of Redox Cycles of NI-YSZ Porous Anode Support for Tubular SOFCs (원통형 고체산화물연료전지용 다공성 NI-YSZ 연료극의 Redox 사이클 특성)

  • Heo, Yeon-Hyuk;Park, Kwang-Yeon;Lee, Jong-Won;Lee, Seung-Bok;Lim, Tak-Hyoung;Park, Seok-Joo;Song, Rak-Hyun;Shin, Dong-Ryul
    • Transactions of the Korean hydrogen and new energy society
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    • v.21 no.6
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    • pp.526-532
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    • 2010
  • The anode may inevitably undergo a number of reduction.oxidation (redox) cycles during solid oxide fuel cells (SOFCs) operation. The re-oxidation of Ni to NiO causes significant mechanical stress to be developed across the anode, which may destroy the integrity of the whole cell. In this study, the redox behavior of Ni-YSZ composite was examined at $800^{\circ}C$ using various characterization techniques.

Performance evaluation method for Solid Oxide Fuel Cell (고체 전해질형 연료전지의 특성평가법 연구)

  • Kim, G.Y.;Eom, S.W.;Moon, S.I.
    • Proceedings of the KIEE Conference
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    • 1997.07d
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    • pp.1389-1390
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    • 1997
  • The object of this research is to develop various composing material for Solid Oxide Fuel Cell generation system, and to test single cell performance manufactured. So we try to present a guidance for developing mass power generation system. We concentrated on development of manufacturing process for cathode, anode and electrolyte.

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Analysis of Dynamic Performance of Solid Oxide Fuel Cells (고체산화물 연료전지의 동적 성능 특성 해석)

  • Yang, Jin-Sik;Sohn, Jeong-L.;Ro, Sung-Tack
    • Proceedings of the KSME Conference
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    • 2004.11a
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    • pp.1652-1657
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    • 2004
  • Model for the dynamic simulation of dynamic behaviors of a solid oxide fuel cell (SOFC) is provided. This model is based upon (1) coupled mass and heat transfer characteristics and (2) important chemical reactions such as electrochemical and reforming reaction in high temperature fuel cells such as SOFC. It is found that the thermal inertia of solid materials in SOFC plays an important role to the dynamic behavior of cell temperature. Dynamic characteristics of cell voltage, power and chemical compositions with different levels of load changes are investigated.

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