• The Bulletin of The Korean Astronomical Society
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• v.44 no.1
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• pp.39.1-39.1
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• 2019

Not all stars in the Universe are gravitationally bounded to galaxies. Since first discovered in 1951, observations have revealed that a significant fraction of stars fills the space between galaxies in local (low-redshift) galaxy clusters, observed as diffuse intracluster light (ICL). Theoretical models provide mechanisms for the production of intracluster stars as tidally stripped material or debris generated through numerous galaxy interactions during the hierarchical growth of the galaxy cluster. These mechanisms predict that most intracluster stars in local galaxy clusters are long-accumulated material since z~1. However, there is no observational evidence to verify this prediction. Here we report observations of abundant ICL for a massive (above $10^{14}$ solar masses) galaxy cluster at a redshift of z=1.24, when the Universe was 5 billion years old. We found that more than 10 per cent of the total light of the cluster is contributed by the diffuse ICL out to 110 kpc from the center of the cluster, comparable to 5-20 per cent in local, massive galaxy cluster. Furthermore, we found that the colour of the brightest cluster galaxy located in the core of the cluster is consistent with that of the ICL out to 200 kpc. Our results demonstrate that the majority of the intracluster stars present in the local Universe, contrary to most previous theoretical and observational studies, were built up during a short period and early (z>1) in the history of the Virgo-like massive galaxy cluster formation, and might be concurrent with the formation of the brightest cluster galaxy.

• Korean Journal of Materials Research
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• v.32 no.1
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• pp.30-35
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• 2022

The development of advanced materials to improve the efficiency of photoelectrochemical (PEC) water splitting paves the way for widespread renewable energy technologies. Efficient photoanodes with strong absorbance in visible light increases the effectiveness of solar energy conversion systems. MoS₂ in a two-dimensional semiconductor that has excellent absorption performance in visible light and high catalytic activity, showing considerable potential as an agent of PEC water splitting. In this study, we successfully modulated the MoS₂ morphology on indium tin oxide substrate by using the metalorganic chemical vapor deposition method, and applied the PEC application. The PEC photocurrent of the vertically grown MoS₂ nanosheet structure significantly increased relative to that of MoS₂ nanoparticles because of the efficient transfer of charge carriers and high-density active sites. The enhanced photocurrent was attributed to the efficient charge separation and improved light absorption of the MoS₂ nanosheet structure. Meanwhile, the photocurrent property of thick nanosheets decreased because of the limit imposed by the diffusion lengths of carriers. This study proposes a valuable photoelectrode design with suitable nanosheet morphology for efficient PEC water splitting.

• Journal of the Korean Solar Energy Society
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• v.32 no.6
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• pp.100-105
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• 2012

In previous study, to investigate the impression of the compound lighting based on the AC-Model at the full-size room, the impressions of various compound lighting were completed as compared with that of the uniform lightings through the comparison method (a paired comparison) by Semantic Differential scaling. Also, we examined the effect of the supplementary lighting type increasing the lights at the side of the window and the blind-control lighting type, and they were compared with the existing compound lighting type. In results, pared comparison of the compound lighting and the uniform lighting, indicates that the impression of the compound lighting is generally similar to that of the uniform lighting when there are same ratios of the light from the window. Based on these results, we suggest that the AC-Model might be applied to various conditions. And we also introduce the method for daylighting that it is possible to reduce discomfort glare and to improve visual impressions as the supplementary type and blind-control type on the compound lighting. And it was found that electric power consumption of the compound lighting room was lower than that of the uniform lighting room when as same lighting ratio of the compound lighting and the uniform lighting from the window was provided or there was the lighting distribution simulated to same light ratio from the window. Since the method of the ACModel was described in the experimental condition, additional studies should be performed to determine if this model could be applied to different window configurations, lighting layout and types of a room.

• Proceedings of the Korean Vacuum Society Conference
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• 2016.02a
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• pp.414.1-414.1
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• 2016

스크린 프린팅법을 이용한 태양전지의 전극은 주로 고가의 은을 사용하기에 태양전지의 저가화에 한계를 가지고 있다. 고효율 결정질 실리콘 태양전지의 원가절감의 문제 해결방안으로 박형 웨이퍼 연구개발이 많은 관심을 받고 있다. 본 연구에서는 은 전극을 대체 할 수 있는 니켈/구리 전극을 사용하였고, 박형 웨이퍼에서도 전극 공정이 가능한 도금법을 사용하여 전극을 형성 하였다. 니켈 전극형성은 광유도 도금법(Light-Induced Plating), 구리 전극형성은 광유도전해도금법(Light-Induced Electro Plating)을 이용하여 실험을 진행 하였다. 니켈 광유도 도금 공정시 공정시간 3 ~ 9분까지 가변하였다. 니켈실리사이드 형성 위해 열처리 공정을 $300{\sim}450^{\circ}C$까지 가변하였고 유지시간 30초 ~ 3분까지 가변하여 실험을 진행하였다. 니켈 도금 수용액의 pH 6 ~ 7.5까지 가변하여 실험하였다. 구리 광유도 전해도금 공정 전류밀도를 $1.6mA/cm^2{\sim}6.4mA/cm^2$까지 가변하여 실험을 진행 후, 전류밀도 $3.2mA/cm^2$로 시간 5 ~ 7분까지 가변하여 실험 하였다. 니켈 도금 공정 시간 5분, 니켈실리사이드 형성 열처리 온도 $350^{\circ}C$, 유지시간 1분에서 DIV(Dark I-V) 분석결과 가장 적은 누설전류를 확인하였다. 니켈 도금액 pH 6.5에서 니켈입자 및 구리입자의 균일성이 좋은 최적의 조건임을 확인하였다. 구리 도금 공정 전류밀도 $3.2mA/cm^2$, 시간 5분에서 TLM(Transmission Line Method) 측정결과 접촉 저항 $0.39{\Omega}$과 접촉 비저항 $12.3{\mu}{\Omega}{\cdot}cm^2$의 저항을 확인하였다. 도금법을 이용하여 전극을 형성함으로써 접촉저항 및 접촉 비저항이 낮고 전극 품질이 향상됨으로서 셀의 전류밀도 $42.49mA/cm^2$를 얻을 수 있었다.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2009.06a
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• pp.28-28
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• 2009

Fabrications of antireflection structures on solar cell were investigated to trap the light and to improve quantum efficiency. Introductions of patterned substrate or textured layer for Si solar cell were performed to prevent reflectance and to increase the path length of incoming light. However, it is difficult to deposit conformally flat electrode on perpendicular plane. ZnO is II-VI compound semiconductor and well-known wide band-gap material. It has similar electrical and optical properties as ITO, but it is nontoxic and stable. In this study, Al-doped ZnO thin films are deposited as transparent electrode by atomic layer deposition method to coat on Si substrate with micro-scale structures. The deposited AZO layer is flatted on horizontal plane as well as perpendicular one with conformal 200 nm thickness. The carrier concentration, mobility and resistivity of deposited AZO thin film on glass substrate were measured $1.4\times10^{20}cm^{-3}$, $93.3cm^2/Vs$, $4.732\times10^{-4}{\Omega}cm$ with high transmittance over 80%. The AZO films were coated with polyimide and performed selective polyimide stripping on head of column by reactive ion etching to measure resistance along columns surface. Current between the micro-columns flows onto the perpendicular plane of deposited AZO film with low resistance.

• Korean Journal of Materials Research
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• v.28 no.4
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• pp.214-220
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• 2018

We report on the fabrication and photoelectrochemical(PEC) properties of a $Cu_2O$ thin film/ZnO nanorod array oxide p-n heterojunction structure with ZnO nanorods embedded in $Cu_2O$ thin film as an efficient photoelectrode for solar-driven water splitting. A vertically oriented n-type ZnO nanorod array was first prepared on an indium-tin-oxide-coated glass substrate via a seed-mediated hydrothermal synthesis method and then a p-type $Cu_2O$ thin film was directly electrodeposited onto the vertically oriented ZnO nanorods array to form an oxide semiconductor heterostructure. The crystalline phases and morphologies of the heterojunction materials were characterized using X-ray diffraction and scanning electron microscopy as well as Raman scattering. The PEC properties of the fabricated $Cu_2O/ZnO$ p-n heterojunction photoelectrode were evaluated by photocurrent conversion efficiency measurements under white light illumination. From the observed PEC current density versus voltage (J-V) behavior, the $Cu_2O/ZnO$ photoelectrode was found to exhibit a negligible dark current and high photocurrent density, e.g., $0.77mA/cm^2$ at 0.5 V vs $Hg/HgCl_2$ in a $1mM\;Na_2SO_4$ electrolyte, revealing an effective operation of the oxide heterostructure. In particular, a significant PEC performance was observed even at an applied bias of 0 V vs $Hg/HgCl_2$, which made the device self-powered. The observed PEC performance was attributed to some synergistic effect of the p-n bilayer heterostructure on the formation of a built-in potential, including the light absorption and separation processes of photoinduced charge carriers.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.31 no.3
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• pp.182-187
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• 2018

In this study, 20.8% of a p-type Si bifacial solar cell was used to develop a photovoltaic (PV) module to obtain the maximum power under a limited installation area. The transparent back sheet material was replaced during fabrication with a white one, which is opaque in commercial products. This is very beneficial for the generation of more electricity, owing to the additional power generation via absorption of light from the rear side. A new model is suggested herein to predict the power of the bifacial PV module by considering the backside reflections from the roof and/or environment. This model considers not only the frontside reflection, but also the nonuniformity of the backside light sources. Theoretical predictions were compared to experimental data to prove the validity of this model, the error range for which ranged from 0.32% to 8.49%. Especially, under $700W/m^2$, the error rate was as low as 2.25%. This work could provide theoretical and experimental bases for application to a distributed and microgrid network.

• Proceedings of the Materials Research Society of Korea Conference
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• 2011.05a
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• pp.42.2-42.2
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• 2011

$TiO_2$ films were modified by adding a glass frit as a light scattering particle and applied to an anode electrode in dye-sensitized solar cells (DSSCs) to enhance the adhesion between $TiO_2$ and fluorine doped transparent oxide (FTO). Low melting point glass frits at contents of (3 to 7wt%) were added to the nano crystalline $TiO_2$ films. The light scattering properties, photovoltaic properties and microstructures of the photo electrodes were examined to determine the role of the low glass transition temperature ($T_g$) glass frit. Electrochemical impedance spectroscopy, Brunauer-Emmett-Teller method and scratch test were conducted to support the results. The DSSC with the $TiO_2$ film containing 3wt% low Tg glass frit showed optimal performance (5.1%, energy conversion efficiency) compared to the $TiO_2$-based one. The photocurrent density slightly decreased by adding 3wt% of the frit due to its large size and non conductivity. However, the decrease of current density followed by the decrease of electron transfer due to the large frit in $TiO_2$ electrode was compensated by the scattering effect, high surface area and reduced the electron transfer impedance at the electrolyte-dye-$TiO_2$ interface. The stability of the photo electrodes was improved by the frit, which chemically promoted the sintering of $TiO_2$ at relatively low temperature ($450^{\circ}C$).

• The Bulletin of The Korean Astronomical Society
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• v.42 no.2
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• pp.49.1-49.1
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• 2017

Comets are one of the most primordial solar system objects that hold the information of the early days of solar system formation inside their nuclei. Orbiting the Sun, they spew such ancient materials that have been buried for many years, creating dust and gas comae. Cometary dust grains absorb and scatter sunlight radiating the continuous light, while gas molecules form the line emissions. Eachof the comets has its own light patterns, which depends on the physical and chemical properties of the dust and gas components. In this regard, spectropolarimetrycan be a powerful tool to study the properties of cometary constituents free from contamination of each other. This methodology offers a series of information on the polarization degrees of the dust and gas components as well as on wavelength dependence of the polarization degree and polarization angle of cometary dust simultaneously. Herein, we will report the results of the spectropolarimetric study of comet 2P/Encke, which is one of the well-known objects for its shortest orbital period and its prominent aging signals. We performed a spectropolarimetric observation of comet 2P/Encke in its inbound orbit using the Higashi-Hiroshima Optical and Near-Infrared Camera (HONIR) at the Higashi-Hiroshima Observatory, Japan, on UT 2017 February 21 at high phase angle of =75.7 deg. Ourstudy of this interesting comet is the first and only one done through spectropolarimetry in a referred publication. We will discuss the most recent polarimetric results of our study in terms of 2P/Encke' scurrent evolutionary status.

• Rapid Communication in Photoscience
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• v.2 no.2
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• pp.42-45
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• 2013

Natural photosynthesis utilizes solar energy to convert carbon dioxide and water to energy-rich carbohydrates. Substantial use of sunlight to meet world energy demands requires energy storage in useful fuels via chemical bonds because sunlight is intermittent. Artificial photosynthesis research focuses the fundamental natural process to design solar energy conversion systems. Nicotinamide adenine dinucleotide ($NAD^+$) and $NADP^+$ are ubiquitous as electron transporters in biological systems. Enzymatic, chemical, and electrochemical methods have been reported for NADH regeneration. As photochemical systems, visible light-driven catalytic activity of NADH regeneration was carried out using platinum nanoparticles, molecular rhodium and cobalt complexes in the presence of triethanolamine as a sacrificial electron donor. Pt nanoparticles showed photochemical NADH regeneration activity without additional visible light collector molecules, demonstrating that both photoactivating and catalytic activities exist together in Pt nanoparticles. The NADH regeneration of the Pt nanoparticle system was not interfered with the reduction of $O_2$. Molecular cobalt complexes containing dimethylglyoxime ligands also transfer their hydrides to $NAD^+$ with photoactivation of eosin Y in the presence of TEOA. In this photocatalytic reaction, the $NAD^+$ reduction process competed with a proton reduction.