• 한국지하수토양환경학회지:지하수토양환경
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• 제18권7호
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• pp.1-11
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• 2013

The actively soil pollution by the toxic heavy-metals like the arsenic, cadmium, lead due to the industrialization and economic activity. The uses the electrokinetic remediation of contaminated soil has many researches against the fine soil having a small size in the on going. However, it is the actual condition which the research result that is not effective due to the low surface charge of the particle and high permeability shows in the electrokinetic remediation in comparison with the fine soil in the case of the sandy soil in which the particle size is large. In this research, the electrokinetic remediation and ultrasonic wave fetch strategy is compound applied against the sandy soil polluted by the arsenic, cadmium, and lead removal efficiency of the sandy soil through the comparison with the existing electrokinetic remediation tries to be evaluated. First of all, desorption of contaminants in soil by ultrasonic extraction in the Pre-Test conducted to see desorption effective 5~15%. After that, By conducted Batch-Test results frequency output century 200 Khz, reaction time 30 min, contaminated soil used in experiment was 500 g. Removal efficiency of arsenic, cadmium, lead are 25.55%, 8.01%, 34.90%. But, As, Cd, Pb remediation efficiency less than 1% in EK1(control group).

• 한국지하수토양환경학회지:지하수토양환경
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• 제18권6호
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• pp.8-17
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• 2013

The contamination of chlorinated ethenes at an industrial complex, Wonju, Korea, was examined based on sixteen rounds of groundwater quality data collected from 2009 to 2013. Remediation technologies such as soil vapor extraction, soil flushing, biostimulation, and pumping-and-treatment have been applied to eliminate the contaminant sources of trichloroethylene (TCE) and to prevent the migration of TCE plume from remediation target zones. At each remediation target zone, temporal monitoring data before and after the application of remediation techniques showed that the aqueous concentrations of TCE plume present at and around the main source areas decreased significantly as a result of remediation technologies. However, the TCE concentration of the plumes at the downstream area remained unchanged in response to the remediation action, but it showed a great fluctuation according to seasonal recharge variation during the monitoring period. Therefore, variations in the contaminant flux across three transects were analyzed. Prior to the remediation action, the concentration and mass discharges of TCE at the transects were affected by seasonal recharge variation and residual DNAPLs sources. After the remediation, the effect of remediation took place clearly at the transects. By tracing a time-series of plume evolution, a greater variation in the TCE concentrations was detected at the plumes near the source zones compared to the relatively stable plumes in the downstream. The difference in the temporal profiles of TCE concentrations between the plumes in the source zone and those in the downstream could have resulted from remedial actions taken at the source zones. This study demonstrates that long term monitoring data are useful in assessing the effectiveness of remediation practices.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 1999년도 추계학술발표회
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• pp.34-38
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• 1999

This paper investigated remediation options for contaminated sediments with heavy metals. Twenty three sediment samples were taken from three different depths of 0.5m, 1.5m and 2.5m. The concentration of Heavy metals Cu, Pb, and Hg were measured. The concentration of copper far exceeded the Sediment Quality Guideline in U.S.A and Interim Sediment Quality Guidelines in Canada. Therefore, remediation of the sediments is requried to protect the benthos. Two remediation options were suggested : dredging of the organic sediments as deep as about 85cm followed by surface covers with clean soil, and in-situ stabilization of tile sediments using lime or cement followed by surface cover with clean soil.

• Membrane and Water Treatment
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• 제11권3호
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• pp.189-193
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• 2020

In this study, electrokinetic remediation equipment was used to remove cesium (Cs) from clay soil and waste solution was treated with sorption process. The influence of electrokinetic process on the removal of Cs was evaluated under the condition of applied electric voltage of 15.0-20.0 V. In addition to monitoring the Cs removal, electrical current and temperature of the electrolyte during experiment were investigated. The removal efficiency of Cs from soil by electrokinetic method was more than 90%. After electrokinetic remediation, Cs was selectively separated from soil waste solution using sorbents. Various adsorption agents such as potassium nickel hexacyanoferrate (KNiHCF), Prussian blue, sodium tetraphenylborate (NaTPB), and zeolite were compared and KNiHCF showed the highest Cs removal efficiency. The Cs adsorption on KNiHCF reached equilibrium in 30 min. The maximum adsorption capacity was 120.4 mg/g at 0.1 g/L of adsorbent dosage. These results demonstrated that our proposed process combined electrokinetic remediation of soil and waste solution treatment with metal ferrocyanide can be a promising technique to decontaminate Cs-contaminated fine soil.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2001년도 총회 및 춘계학술발표회
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• pp.226-229
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• 2001

For volume reduction of the wastewater generated on washing the soil contaminated with cobalt, recycling and reuse experiments of the wastewater were executed. Also. the soil remediation efficiency by repetitive washing with fresh citric acid was analyzed. The soil around TRIGA was sampled for the experiment. Results of recycling experiment by replacement-precipitation method were as follows. The remediation efficiency of 1st recycling wastewater was 97% and that of 2nd recycling wastewater was 94%. Also, To obtain remediation efficiency over than 90%, the 5th repetitive washing with fresh citric acid was needed.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2003년도 추계학술발표회
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• pp.217-221
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• 2003

Variation of decision variables for optimal remediation using the pump-and-treat method is examined to estimate the effect of the degree of concentration constraint. Simulation-optimization method using genetic algorithm is applied to minimize the total pumping volume. In total volume minimization strategy, the remediation time increases rapidly prior to significant increase in pumping rates. When the concentration constraint is set severer, the more wells are required and the well on the down-gradient direction from the plume hot-spot gives more efficient remediation performance than that on the hot-spot position. These results show that the more profitable strategy for remediation can be achieved by increasing the required remediation time than raising the pumping rate until the time reaches a certain limitation level. So, the remediation time has to be considered as one of the essential decision variables fer optimal remediation design.

• 한국토양환경학회지
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• 제4권2호
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• pp.55-62
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• 1999

토양복원을 위한 용매 추출 실험장치를 설계 제작하였다. 핵시설 주위의 토양시료를 채취하여 코발트 이온으로 오염시킨 후, 용매추출법에 의해 코발트 이온이 제염되는 현상을 분석하였다. 한편, 용매추출법에 의한 토양 제염의 모델링을 위해 비평형 흡착 코드를 개발하였다. 모델링을 위한 입력 변수를 실험으로 측정하였다. 실험결과는 다음과 같다. 핵시설 근처의 토양은 다량의 실트와 모래를 함유한 Silt Loam이다. 용매로 물을 사용하였을 때, 수리전도도가 클수록 토양제염 효과가 높았다. 비평형 흡착코드에 의해 계산된 값들은 평형 흡착코드에 의해 계산된 값들보다 실험치에 보다 더 접근하였다. EDTA용액을 용매로 사용하였을 때가 물에 비해 제염효율이 좋았다.

• 한국지반신소재학회논문집
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• 제5권2호
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• pp.1-8
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• 2006

오염토양의 현장정화에 있어서 지반 및 오염물질의 물성치는 정화에 소요되는 시간과 함께 매우 중요한 고려사항이다. Gabr 등(1996)은 연직배수재가 설치된 오염지반에서 시 공간적 변화에 따른 초기오염농도에 대한 오염농도비($C/C_0$)를 구하는 식을 유도하였다. 본 연구에서는 Gabr 등이 유도한 식의 전산모형 FLUSH1을 이용하여 오염지반 흙의 유효입경, 간극률, 형상계수, 밀도, 지반의 온도와 오염물질의 단위중량 및 점성계수가 오염정화에 미치는 영향을 알아보기 위하여 시 공간적 변화에 따른 오염농도비($C/C_0$)를 분석 하였다. 분석결과 연직배수재가 설치된 오염지반에서 정화에 크게 영향을 미치는 인자는 오염지반 흙입자의 유효입경인 것으로 나타났으며, 그 다음으로 오염물질의 점성, 오염지반 흙의 간극율, 형상계수, 지반의 온도, 오염물질의 단위중량, 흙의 밀도 순으로 분석되었다. 오염지반 흙의 밀도는 오염정화에 미치는 영향이 아주 작은 것으로 나타났다.

• 한국철도학회논문집
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• 제3권3호
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• pp.101-108
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• 2000

In this study, we tested hybrid pilot system combined with soil vapor extraction and bioventing methods on the contaminated railroad soil. So, we found out the remediability and operating conditions. Air permeability(k) and gas phase(O$_2$/CO$_2$/VOCs) level trend are very important to determine the remediation rate of the contaminated sites. Throughout hybrid pilot test on different conditions, the range of air permeability(k) was 1985∼1194 darcy. The tests results in hybrid system was appropriate on this test sites, and the suitable injection air flow rate was 3.5㎥/hr. So, we suggested a basic data for the remediation and management of contaminated railroad soil.

• 한국지하수토양환경학회지:지하수토양환경
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• 제10권2호
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• pp.1-11
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• 2005

본 논문은 납 오염토에 대한 정회를 목적으로 EK 기법을 적용할때 기존의 EK 기법의 한계성을 극복하고자 향상기법으로써 흡착재(Apatite, Zeolite)를 이용하여 중금속의 고정화를 시도하였다. EK 추출을 위해서 우선 납에 대한 흡착능 실험을 실시하였고 오염농도, 전압조건, 가동시간 등을 달리하여 납이온을 흡착재 설치 위치로 이동시켜 고정화를 유도하였다. 그 결과 설험 조건에 따라 오염물의 이동 특성이 달라 정화 효율에 차이가 있었으며 전극교환과 흡착재의 설치 위치의 추가로 고정화 효율을 증진시켜 시료의 전 구간에서 미국 EPA의 TCLP 용출기준을 만족시킬 수 있었다. 특히 인회석의 흡착 고정화 능력은 탁월한 것으로 판명되어 EK 향상기법으로써 흡착재의 적용 기능성을 확인하였다.