• 제목/요약/키워드: Soil Reaction

검색결과 835건 처리시간 0.028초

잠재성 특이산성토중 강관말뚝의 부식 (Steel Pile Corrosion in Potential Acid Sulfate Soil)

  • 이승헌;박미현;윤경섭
    • 한국농공학회:학술대회논문집
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    • 한국농공학회 2003년도 학술발표논문집
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    • pp.559-562
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    • 2003
  • The results and discussions of surveyed case site at constructed steel pile in potential acid sulfate soil were as follows. Topography at surveyed site was local alluvial valley and that site soils was classified as BanGog and YuGye series as detailed soil surveyed results in RDA and soil texture was Clay/Clay Loam. Soils pH was neutral, which was average 7.5 but much decreased to average 4.2 after $H_2O_2$ treatment. Organic matter and sulfate ions contents were very rich. The corrosion was severe at ground water fluctuation depth. Deposits colored black were attached to steel pile surface, which because of violent reaction in treatment HCI solution, were guessed as corrosion products (FeS) reduced by sulfate reducing bacteria(SRB). Consequently, main cause was thought microbiologically induced corrosion at this site where there is ground water fluctuation occurring oxidation and reduction reactions in turn and the soil is potential acid sulfate soil.

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토양 중 mineral에 의한 염소계 유기화합물 분해 특성 연구

  • 최정윤;심상규;이우진
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2006년도 총회 및 춘계학술발표회
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    • pp.33-36
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    • 2006
  • The reductive dechlorination of chlorinated organic compounds by soil minerals in soil and groundwater were carried out in this study. FeS, green rust, and magnetite were chosen as the representative soil minerals which were capable of degrading chlorinated compound in soil system. FeS was the most effective reductant in degradation of carbon tetrachloride. The reductive degradation of CT and 1,1,1-TCA by FeS was much faster than that of 1,2-DCB and 2,4-DCP. The reactivity of FeS was effectively improved by the addition of trace metals. The addition of Co to FeS suspension enhanced the reaction rate of 1,2-DCB by a factor of 46 compared to that by FeS without Co.

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펜톤 산화공법을 통해 디젤로 오염된 토양 처리 시에 과산화수소와 디젤의 주입비 영향에 관한 연구

  • 임명희;손영규;윤준기;김지형
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2006년도 총회 및 춘계학술발표회
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    • pp.37-40
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    • 2006
  • The batch tests were performed to determine the ratio of hydrogen peroxide on diesel contaminated soil. The objective of test was to determine and optimize the hydrogen peroxide requirements for the remediation of a soil contaminated with diesel fuel. The batch test were done on 5g diesel contaminated soil containing hydrogen peroxide (34.5%). Initial diesel concentration were 2,000mg/kg, 5,000mg/kg, and 10,000mg/kg. The $Diesel(g):H_2O_2(g)$ ratio varied 1:1, 1:10, 1:50, 1:100, with contact reaction time 120 min. Results the batch test, effective ratio of $Diesel(g):H_2O_2(g)$ is 1:100.

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토양 제염에 있어서 magnetite 용해 거동 연구

  • 원휘준;김민길;김계남;박진호;오원진
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2003년도 총회 및 춘계학술발표회
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    • pp.393-396
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    • 2003
  • Soil contains the several kinds of metal oxides. Magnetite in soil may contribute the generation of secondary waste during the decontamination of soil by citric acid. Dissolution of magnetite powders by citric acid was investigated in the pH range between 2.0 and 5.0. The dissolution behaviour of magnetite was well described by the equation, A[1 - $e^{-B(x-c)}$]. The parameters of the equation were optimized by the iteration method, and the physical meaning of each parameter was explained. Concentration of each of the dissociated chemical species of citric acid was calculated using the ionization constants. The dissolution reaction was explained by the concentration of the dissociated chemical species of citric acid.d.

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Reliability analysis of steel cable-stayed bridges including soil-pile interaction

  • Cheng, Jin;Liu, Xiao-luan
    • Steel and Composite Structures
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    • 제13권2호
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    • pp.109-122
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    • 2012
  • An efficient and accurate algorithm is proposed to evaluate the reliability of cable-stayed bridges accounting for soil-pile interaction. The proposed algorithm integrates the finite-element method and the response surface method. The finite-element method is used to model the cable-stayed bridge including soil-pile interaction. The reliability index is evaluated based on the response surface method. Uncertainties in the superstructure, the substructure and load parameters are incorporated in the proposed algorithm. A long span steel cable-stayed bridge with a main span length of 1088 m built in China is considered as an illustrative example. The reliability of the bridge is evaluated for the strength and serviceability performance functions. Results of the study show that when strength limit states for both girder and tower are considered, soil-pile interaction has significant effects on the reliability of steel cable-stayed bridges. Further, a detailed sensitivity study shows that the modulus of subgrade reaction is the most important soil-pile interaction-related parameter influencing the reliability of steel cable-stayed bridges.

Na2S를 이용한 EDTA 토양세척수로부터의 중금속 분리 (Separation of Heavy Metals from Metal-EDTA in Spent Soil Washing Solution by using Na2S)

  • 오상화;신원식
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제20권7호
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    • pp.103-111
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    • 2015
  • Soil washing with ethylenediaminetetraacetic acid (EDTA) is highly effective in the remediation of soils contaminated with heavy metals. The EDTA recycling process is a requisite for reducing the operating cost. The applicability of Na2S addition on the precipitation of heavy metals from the spent soil washing solution and thereby recycling of EDTA was investigated. Addition of Na2S into the single metal-EDTA and the mixed metal-EDTA solutions ([Na2S]/[metal-EDTA] ratio = 30, reaction time = 30 min and pH = 7~9) was highly effective in the separation of Cu and Pb from metal-EDTA complexes, but not for Ni. The Zn removal efficiency varied with pH and slightly increased upto 40% as the reaction time increased from 0 to 240 min which was longer than those for Cu and Pb. Ca(OH)2 was subsequently added to induce further precipitation of Zn and Ni and to reduce the Na2S dose. At the [Na2S]/[metal-EDTA] ratio of 10, the removal efficiencies of all heavy metals excluding Ni were above 98% with the dose of Ca(OH)2 at 0.002, 0.006 and 0.008 g into 100 mL of Cu-, Pb- and Zn-EDTA solutions, respectively. However, Ca(OH)2 addition was not effective for Ni-EDTA solution. A further research is needed to improve metal removal efficiency and subsequent EDTA recycling for the real application in field-contaminated soils.

요소의 암모니아화 및 질산화와 토양반응에 미친 수종 유기물의 영향 (Effect of a Number of Organic Sources on the Ammonification and Nitrification of Urea and Soil Reaction)

  • 오왕근;허지희;김재영
    • 아시안잔디학회지
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    • 제5권1호
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    • pp.47-53
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    • 1991
  • A laboratory experiment was conducted in order to learn the effect of a number of organic matters on the ammonification and nitrification of urea, and the reaction of soil, applied to a loamy upland soil poor in orgnic matter(<1.5%, without plants 1.The ammonification of urea was most pronounced in one week period immediatly after fertilizer and water treated, after which a rapid decrease of it was followed showing no accumulation at the end of 3rd week. Owing to the accumlation of ammonium, pHs of treated soils were read 7.0 to 7.3 from 6.8~6.9. 2.Nitrification was also progressed rapidly in the first one week period so that the accumulation of NO$_3$-N surpassed that of ammonia during this period. After the 1st week the accumulation of N0$_3$-N was continuously increased showing the maximum at the end of 4 weeks following a sharp decrease at the end of 5th weeks. The accumulation of NO$_3$-N dropped soil pH from 6.8-7.0 to 6. 0-6.2,but the decrease of NO-N at the end of 5th weeks brought up soil pH to 6.4-6.6. again. 3.Amino acid fermentation byproduct rich in salt, paticularly chloride, slowed down the ammonification and nitrification of urea. 4.The application of organic matter diminished the acidifying effect of chemical fertilizers. The diminishing effect of soluble humic acid and amion acid fermentation byproduct showed greater than that of solid organic matter in this experiment, which might be own to the application of a rather small amount of water soluble organic matters. Rice straw powder among solid organic matters appeared to be the least in the diminishing effect above. It may be reasoned that these soluble organic matters decomposes rapidly so as to affect Soil pH, but solid organic matters, particularly the rice straw powder, form acidic humus.

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유류오염대수층 공기분사공정상의 미생물 제한효소다형성법 적용 평가 (Analysis of Microbial Community in the TPH-Contaminated Groundwater for Air Sparging using Terminal-Restriction Fragment Length Polymorphism)

  • 이준호;이상훈;조재창;박갑성
    • 한국물환경학회지
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    • 제22권4호
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    • pp.590-598
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    • 2006
  • In-situ Air sparging (IAS) is a groundwater remediation technique, in which organic contaminants volatilize into air form the saturated to vadose zone. This study was carried out to evaluate the effect of sludge and soil microbial community structure on air sparging of Total Petroleum Hydrocarbons (TPH) contaminated groundwater soils. In the laboratory, diesel (10,000 mg TPH/kg) contaminated saturated soil. The Air was injected in intermittent (Q=1500 mL/min, 10 minute injection and 10 minute idle) modes. For Terminal-Restriction Fragment Length Polymorphism (T-RFLP) analysis of eubacterial communities in sludge of wastewater treatment plants and soil of experiment site, the 16S rDNA was amplified by Polymerase Chain Reaction (PCR) from the sludge and the soil. The obtained 16S rDNA fragments were digested with Msp I and separated by electrophoresis gel. We found various sequence types for experiment with sludge soil samples that were closely related to Agrococcus, Flavobacterium, Thermoanaerobacter, Flexibacter and Shewanella, etc, in the clone library. The results of the present study suggests that T-RFLP method may be applied as a useful tool for the monitoring in the TPH contaminated soil the fate of microorganisms in natural microbial community.

과황산나트륨과 제일철 촉매를 이용한 나프탈렌 산화 시 토양이 미치는 영향 평가 (Effect of the Presence of Soil on the Ferrous Catalyzed Sodium Persulfate Oxidation of Naphthalene)

  • 한대성;윤여복;고석오
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제15권1호
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    • pp.29-38
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    • 2010
  • Batch tests were carried out to examine the influence of the presence of soil and Fe(II) sorption capacity of soil on the ferrous catalyzed sodium persulfate oxidation for the destruction of organic pollutants in the application of in-situ chemical oxidation. Laboratory column tests were also conducted to investigate the transport of oxidant and catalyst in contaminated groundwater. Test results proved that Fe(II) was adsorbed on soil surface, and thus soil behaved as a heterogeneous catalyst, enhancing the naphthalene removal rate up to 50%. Column tests that were conducted with and without dissolved Fe(II) showed that naphthalene removal ratio were 24% and 25%, respectively. The removal efficiency was not enhanced with dissolved Fe(II), since the dissolved Fe(II) flew out of the column as the oxidant progressively injected into the column saturated with Fe(II). It indicates that the injected oxidant could not interact with dissolved Fe(II). But target organic pollutant was degraded in soil column system, implying that sulfate radical was produced by the reaction of dissolved persulfate with Fe(II) adsorbed on soil.

매설관과 지반의 상호작용을 고려한 보-스프링 모델과 연속체 모델의 수치해석적 비교 연구 (Numerical Analysis for Comparing Beam-spring and Continuum Model for Buried Pipes Considering Soil-pipe Interaction)

  • 양정훈;신영진;최항석
    • 한국지반환경공학회 논문집
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    • 제24권9호
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    • pp.15-24
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    • 2023
  • 지중 매설관 거동은 주변 지반의 비선형성과 복합거동 특성의 영향을 직접적으로 받게 되나, 실무에서는 지반의 복잡한 거동 특성을 단순화한 보-스프링 모델이 현재까지도 널리 활용되고 있다. 따라서, 연구 분야에서는 지반의 비선형 특성과 복합거동 특성을 반영하기 위한 연속체해석 방법을 활용하려는 다양한 연구들이 진행되어 왔고, 본 논문에서도 기존에 연구된 다양한 연속체 해석기법을 활용하여 수치해석을 수행하고, 변위-반력 결과 및 지반파괴 형상을 기존 실대형시험 결과와 비교·검토하였다. 지반과 매설관의 상호작용을 적용한 접촉면 특성을 적용한 경우, 실대형시험에 근접한 반력 결과를 도출할 수 있음을 확인하였으며, 실대형 시험과 유사한 파괴 형상도 확인하였다. 지반과 매설관의 상호작용을 무시한 매설관과 지반 절점 공유 방법의 경우, 과도한 반력 값을 도출하고, 파괴양상도 상이하였다. 또한, 대변형 해석에서 수렴성이 좋은 동적해석 explicit 방법, ALE 방법, CEL 방법을 각각 적용한 결과, 정적해석과 유사한 변위-반력 관계 및 파괴 형상이 확인되어, 향후 지반분야 대변형 해석에서 동적해석법도 충분히 활용될 수 있을 것으로 판단하였다.