• 제목/요약/키워드: Soil Contamination Investigation

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영가철 및 산업폐기물을 활용한 비소오염토양의 안정화 효과조사 (Investigation of Stabilization Effect on Arsenic Contamination Soils using Zerovalent Iron and Industrial by-products)

  • 유찬;윤성욱;백승환;박진철;이정훈;임영철;최승진;장민
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2008년도 춘계 학술발표회 초청강연 및 논문집
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    • pp.229-241
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    • 2008
  • In order to investigate stabilization effect on As-contaminated soils treated by zero-valent iron(ZVI) and industrial by-products, batch tests and column tests were carried out with As-contaminated soils collected from farmland around the abandoned mine site. In batch tests, ZVI and industrial by-products(blast furnace slag, steel refining slag and oyster shell powder) were used as treatment materials to reduce As. Industrial by-products were mixed with As-contaminated soils, in the ratio of 1%, 3%, 5% and 7% on the weight base of dried soil. After incubation, all samples showed the reduction of As concentration and it was expected that ZVI and steel refining slag were effective treatment materials to remove As among treatment materials used in batch test. In column tests, columns were made by acrylic with the dimension of diameter=10cm, height=100cm, thickness=1cm and these columns were filled with untreated soils and treated soils mixed with ZVI and steel refining slag(mixing ratio=3%). Distilled water was discharged into the columns with the velocity of 1 pore-volume/day. During test, pH, EC, Eh and As concentration were measured in the regular term(1 pore-volume). As a result, ZVI and steel refining slag were shown 93%, 62% reduction of As concentration respectively by comparison with untreated soils. Therefore, if ZVI and steel refining slag are used as treatment materials in As-contaminated soils, it is expected that the As concentration in soils is reduced effectively.

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국내의 다양한 장소에서 채취된 수질, 토양 및 저질시료의 폴리염화비페닐에 의한 오염도 (Polychlorinated Biphenyl Contaminations of Water, Soils and Sediments Sampled from Various Places of Korea)

  • 박현미;류재천;김영만;이강봉
    • 분석과학
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    • 제13권6호
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    • pp.802-809
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    • 2000
  • 국내의 다양한 장소에서 채취된 수질 43종, 토양 35종 및 저질 11종 중에 포함 되어있는 polychlorinated biphenyls (PCBs)의 congeners 성분들을 GC/MS를 이용하여 분석하였다. 분석 결과 수질시료의 평균 회수율은 $83.8{\pm}10.4%$이며, 토양 및 저질시료의 평균 회수율은 $94.9{\pm}12.2%$였으며, $^{13}C{_{12}}$-PCBs(Surlegate)에 대한 회수율도 $80.2{\pm}8.7%$로 비교적 양호하였다. 검출 한계는 수질의 경우 0.01 ng/ml이며, 토양 및 저질의 경우 0.05 ng/g로 결정되었다. 수질시료는 정량한계 범위 내에서 검출되지 않았으나, 토양 및 저질시료에서는 대부분의 시료에서 한 개 이상의 PCBs congener가 검출되었다. 이번 국내의 PCBs 생태계 오염 실태조사 결과는 미국, 유럽 및 일본과 같은 선진국에 비해 PCBs의 오염도가 상당히 낮은 것으로 평가되었다.

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지중환경 관리를 위한 부지개념모델 구축 및 개선 (Development and Enhancement of Conceptual Site Model for Subsurface Environment Management)

  • 배민서;김주희;이순재;권만재;조호영
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제27권spc호
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    • pp.1-18
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    • 2022
  • A conceptual site model is used to support decision-making of response strategy development, determination, and implementation within a risk-based contaminated site management system. It aims to provide base information of the relevant site characteristics and surface/subsurface conditions in order to understand the contaminants of concern and the associated risk they pose to the receptors. This study delineated the technical details of conceptual site model development, and discussed the possibility of applying it in domestic subsurface contamination management. Conceptual site models can be developed in various formats such as tables, diagrams, flowcharts, and figures. Contaminated sites are managed for a long period of time following the steps of investigation, remediation design, remediation, verification, and post-remedation management. The conceptual site model can be enhanced in each stage of the contaminated site management based on the continuously updated information on the site's subsurface environment. In the process of enhancement for conceptual site model, precision is gradually improved, and it can evolve from a conceptual and qualitative form to a more quantitatvive and three-dimensional model. In soil pollution management, it is desirable to incorporate the conceptual site model into the soil scrutiny system to better assess the current status of the contaminated site and support follow-up investigation and management.

환경물리탐사 기법을 이용한 유류오염 주유소 부지 특성 조사

  • 김창렬;고경석;김정호;박삼규;손정술;정지민
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2005년도 총회 및 춘계학술발표회
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    • pp.429-432
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    • 2005
  • Geophysical investigations, as a non-invasive method, were conducted at the former gas station site contaminated with fuel hydrocarbons. GPR (Ground Penetrating Radar) survey was performed to locate buried objects such as USTs (Underground Storage Tanks) and fuel pipes which might serve as a origin of the site contamination. Additional GPR investigation and a resistivity survey were conducted to map water table and to characterize shallow geologic structures of the site. The results of the study have shown that seven USTs including one unknown UST and buried fuel pipes are present, and that the groundwater elevation varies with topography from approximately 1.5 to 3m below the surface and the water table is located in the residual soils above the bedrock in the site. The results also show that the geophysical methods can be a very useful tool for the characterization of the contaminated site.

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국내토양오염 유발시설별 오염현황 조사 I -OO인근주유소 오염현황조사- (A Case Study of Site Investigation on OO Gas Station)

  • 김무훈
    • 한국토양환경학회지
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    • 제2권3호
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    • pp.81-88
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    • 1997
  • 본 조사의 목적은 적절한 조사방법이 미흡한 주유소에서의 오염현황 조사방법 및 그에 따른 주변지역으로의 오염물질이전 및 환경적 영향을 평가하는 것이다. Site assessment 방법에는 몇가지의 접근방법이 있는데, 본 OO 주유소 오염현황조사에서는 임의격자법/삼각매트릭스법을 사용하였다. 조사결과에 의하면, 주유소에서의 물질성상은 몇 가지의 형태로 분류할 수 있었다. 지층구조는 약 2.5M까지는 매립토(잡석 & 모래)로 충진하였으며, 2.5-4M 까지는 부드러운 모래와 미사토(Silty Sand)의 자연적인 토양층를 나타내고 있었다. 또한 4.0M 가까이에는 풍화토(C층)가 출현하였다(그림3. 지층구조측면도 참조).저장탱크지역의 지하수위는 약 2.0M이며 남쪽에 흐르고 있는 개천의 수위와 거의 일정하게 유 지되고 있음을 알 수 있었다. 결론적으로, 이 주유소에서의 오염현황조사에서는 실제 UST나 배관 주위에서의 누출에 의한 실제오염은 찾아낼 수 없었지만, 기름을 충진한 후 버려지는 슬러지들이 부분적인 오염의 원인이 될 수 있다는 것을 본 현황조사를 통하여 알아낼 수 있었다.

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광산지역 토양정밀조사 정도관리(QA/QC) 사례 연구 (A Case Study of Quality Assurance and Control for the Soil Environmental Assessment in Abandoned Mine)

  • 지원현;김종근
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제19권3호
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    • pp.134-141
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    • 2014
  • A testing inspection is one of the important in the industry, owing to determine the reliability and directivity of testing inspection results. Therefore, the quality assurance and quality control (QA/QC) work which performed by personnel not directly in the inventory compilation development, in testing inspection must be thoroughly considered. Some agencies for environmental test inspection, they sometimes misunderstood that the QA/QC was ended with proficiency testing performance and on-site assessment by a director. Thus, results were often calculated without QA/QC work by self manual when conducting test. The objective of this study was to improve reliability of testing and inspection agency through the QA/QC case study which basically performed to raising reliability of testing and inspection agency. In this study, it increased reliability of result by verifying calibration curve (IC, ICV, CCV), blank, accuracy (LCS, MS) and precision as QA/QC performance, while performing investigation of soil contamination in mining areas. This study suggests that reliability establishing method of test result and management method of analysis process, through the QA/QC instance of testing agency.

원자력 사고시 가축의 공기 흡입과 토양 섭취에 의한 축산물의 오염 - 우유에 대한 오염 영향을 중심으로 (Predictive Contamination of Animal Products Due th the Inhalation of Air and the Ingestion of Soil of Cattle in an Accidental Release of Radioactive Materials - Focusing on Contaminative Influence for Milk)

  • 황원태;김은한;서경석;정효준;한문희;이창우
    • Journal of Radiation Protection and Research
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    • 제28권4호
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    • pp.299-309
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    • 2003
  • 동적 섭식경로모델 DYNACON을 개선하여 원자력시설의 사고시 환경으로 누출된 방사성물질에 의한 가축의 공기 흡입과 토양 섭취에 따른 축산물의 오염 영향을 고찰하였다. 이들 두 오염경로에 대한 수학적 모델은 고려되는 모든 축산물에 대해 수립되었지만 결과에 대한 상세 고찰은 우유에 국한하였다. 젖소의 공기 흡입과 토양 섭취는 방사성물질의 환경 누출이 목초가 성장하지 않는 비방목 기간에 일어나는 경우에 우유의 중요한 오염경로가 될 수 있다는 사실을 알 수 있었다. 비방목 기간동안 방사성물질이 환경으로 누출되는_경우 초기에는 공기 흡입이 토양 섭취에 의한 영향보다 높으나, 시간이 경과할수록 토양 섭취가 우유의 오염에 있어서 지배적 영향을 미쳤다. 이러한 현상은 전반적으로 지상으로 상대적으로 많은 침적을 일어나게 하는 누출기간 중 강우가 있는 경우에 보다 뚜렷하였다. $^{137}Cs$$^{90}Sr$의 경우와 달리 $^{131}I$은 누출기간 중 강우에 거의 영향을 받지 않았다. 방목기간에 방사성물질이 환경으로 누출되는 경우 누출기간 중 강우의 유무에 관계없이 공기 흡입에 의한 우유의 오염 영향은 무시 가능한 수준이었다.

Advantages and disadvantages of renewable energy-oil-environmental pollution-from the point of view of nanoscience

  • Shunzheng Jia;Xiuhong Niu;Fangting Jia;Tayebeh Mahmoudi
    • Advances in concrete construction
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    • 제16권1호
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    • pp.69-78
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    • 2023
  • This investigation delves into the adverse repercussions stemming from the impact of arsenic on steel pipes concealed within soil designated for rice cultivation. Simultaneously, the study aims to ascertain effective techniques for detecting arsenic in the soil and to provide strategies for mitigating the corrosion of steel pipes. The realm of nanotechnology presents promising avenues for addressing the intricate intersection of renewable energy, oil, and environmental pollution from a novel perspective. Nanostructured materials, characterized by distinct chemical and physical attributes, unveil novel pathways for pioneering materials that exert a substantial impact across diverse realms of food production, storage, packaging, and quality control. Within the scope of the food industry, the scope of nanotechnology encompasses processes, storage methodologies, packaging paradigms, and safeguards to ensure the safety of consumables. Of particular note, silver nanoparticles, in addition to their commendable antibacterial efficacy, boast anti-fungal and anti-inflammatory prowess, environmental compatibility, minimal irritability and allergenicity, resilience to microbial antagonism, thermal stability, and robustness. Confronting the pressing issue of arsenic contamination within both environmental settings and the food supply is of paramount importance to preserve public health and ecological equilibrium. In response, this study introduces detection kits predicated upon silver nanoparticles, providing an expeditious and economically feasible avenue for identifying arsenic concentrations ranging from 0.5 to 3 ppm within rice. Subsequent quantification employs Hydride Atomic Absorption Spectroscopy (HG-AAS), which features a detection threshold of 0.05 ㎍/l. A salient advantage inherent in the HG-AAS methodology lies in its capacity to segregate analytes from the sample matrix, thereby significantly reducing instances of spectral interference. Importantly, the presence of arsenic in the soil beneath rice cultivation establishes a causative link to steel pipe corrosion, with potential consequences extending to food contamination-an intricate facet embedded within the broader tapestry of renewable energy, oil, and environmental pollution.

Long-Term Investigation of Regional Topographic Effects on Soil Chemical Properties and Heavy Metal Concentrations in Paddy Fields

  • Ahn, Byung-Koo;Kang, Seong-Soo;Shin, Jae-Yeon;Lee, Jin-Ho
    • 한국토양비료학회지
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    • 제45권5호
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    • pp.738-743
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    • 2012
  • Topographic conditions of agricultural fields work as a important factor to identify different soil properties. This study was conducted to investigate the selected soil chemical properties and the concentrations of heavy metals, Cd, Cr, Pb, Cu, Ni, and Zn, in the paddy fields of different topographic areas at four year intervals from 1999 to 2011. Three-hundred soil sampling sites in the paddy fields were selected from the different topographic areas that were local valley and fans, fluvio-marine deposits, alluvial plains, and diluvial terraces. The mean values of soil pH ranged 5.7~5.8 that were within optimal range for rice cultivation. The mean values of other properties such as soil organic matter (SOM) content, the concentrations of exchangeable cations, $K^+$, $Ca^{2+}$, and $Mg^{2+}$, and available silicate concentration were lower or close to the optimal values, but the mean concentrations of available phosphorus were exceeded the range of optimal value, $80{\sim}120mg\;kg^{-1}$, in many paddy fields. In particular, The concentrations of available phosphorus in the paddy fields of local valley and fans, alluvial plains, and fluvio-marine plains were mostly declined. However, in diluvial terrace areas, the phosphorus concentrations unexpectedly increased; furthermore, they were significantly higher than those in other topographic areas. The mean concentrations of 0.1 M HCl-extractable heavy metals, Cd, Cr, Pb, Cu, Ni, and Zn, in the paddy fields were slightly and gradually declined during the study years, but the Pb concentrations were not statistically changed. In addition, the concentrations of heavy metals were widely ranged depending on the different sampling sites. Nevertheless, the concentrations of heavy metals were significantly lower than the levels of Soil Contamination Warning Standard (SCWS) for agricultural lands (1-region) presented in Soil Environment Conservation Law (SECL).

오염토양의 효과적 현장조사에 대한 주요 방법론의 검토 (Key Methodologies to Effective Site-specific Accessment in Contaminated Soils : A Review)

  • 정덕영
    • 한국토양비료학회지
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    • 제32권4호
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    • pp.383-397
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    • 1999
  • 오염토양을 효과적으로 진단하고 경제적인 복원을 위해서는 오염토양의 오염원인, 오염정도, 주변 환경이나 인축에 대한 피해발생 유무, 오염물의 이동경로 등을 올바르게 평가하는 것이 대단히 중요하다. 이를 위해서는 오염토양과 토양내 가스, 주변 지하수 및 지표수, 침전물 등의 효율적 시료채취와 정확한 분석이 필수적이라 할 수 있다. 오염지역 토양의 오염도평가를 표준화하고 처리효율성을 높이기 위해서는 전문처리요원이 토양의 오염도와 위험성을 정확하게 판단 할 수 있도록 단순하면서도 경제적인 연속시험법을 필요로 한다. 이것은 오염토양의 조사와 복원시간 및 전치적일 기술의 진보를 가져오는데 상당한 시간절약을 꾀할 수 있다. 특히 효과적인 현장평가를 위해서는 오염특성을 포함한 많은 관련 요인들에 대한 표준화된 기준하에서 오염의 형태와 정도를 결정하는 것이 중요하다. 현장평가를 위한 일반적인 절차는 작업계획과 토양조사수준에 따라 Phase I, II, III의 단계적 방법으로 구성되어 있다. Phase I은 토양의 과거용도 및 오염물의 유입경로를 기초로 하여 현장의 환경여건을 파악하는 단계이다. Phase I에서 잠재적 오염물질에 의해 오염된 것이 확인되면 Phase II에서는 오염물의 존재여부와 존재정도를 파악하는 단계로 시료의 채취 및 분석과정이 여기에 포함된다. Phase III는 Phase I과 II의 결과를 바탕으로 오염토양을 복원하는 단계이다. 여기서 평가기준이 지역 특이적인 것인지 적당한 것인지를 결정하는 중요한 요인은 (1) 시료채취의 공간분포도와 지역의 크기, (2) 취해진 시료의 수, (3) 시료채취 방법, 그리고 (4) 자료를 분석요령 등이다. 선택된 분석방법이 추천할만한 것일지라도 정량방법의 선택여부는 현장조사방법에 대한 훈련이나 조사경험을 가진 사용자에 의해 결정되는 것이 바람직할 것이다.

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