• Title/Summary/Keyword: Size control of the particles

Search Result 370, Processing Time 0.031 seconds

Crystallographic and Magnetic Properties of Iron Oxide Nanoparticles for Applications in Biomedicine

  • Lee, Sang-Won;Woo, Kyoung-Ja;Kim, Chul-Sung
    • Journal of Magnetics
    • /
    • v.9 no.3
    • /
    • pp.83-85
    • /
    • 2004
  • Magnetic nanoparticles have been investigated for use as biomedical purposes for several years. For biomedical applications the use of particles that present superparamagnetic behavior at room temperature is preferred [1-4]. To control the magnetic materials by magnetic field is essential locate particle to the suitable destination on feeding by injection. In order to use them properly, the particles should be nano size. However there are many difficulties in applications, because there is lack of identifications in nano magnetic properties. In our studies, structural and magnetic properties of iron oxide nanoparticles were investigated by XRD, VSM, TEM, and Mossbauer spectroscopy. At 13 K, hyperfine fields of ${\gamma}-Fe_2O_3$ were 516 kOe and 490 kOe, that of $Fe_3O_4$ were 517 kOe and 482 kOe. The saturation magnetizations were 21.42 emu/g and 39.42 emu/g. The particle size of powders is 5~19 nm.

Temperature distribution in VX-2 hepatoma heated with thermoseed hyperthermia (열소자 온열요법시 VX-2 hepatoma내의 온도 변화에 대한 연구)

  • Choi, Ihl-Bohng;Bahk, Yong-Whee
    • Radiation Oncology Journal
    • /
    • v.12 no.3
    • /
    • pp.295-300
    • /
    • 1994
  • It was the purpose of present study to develop a new thermoseed for heating deep-seated tumors and assessment of the effect of magnetic control on thermoseeds. Aqueous suspension of iron micro spheres (Ferropolysaccharide) was injected directly into the VX-2 hepatoma and heated with 1.2 MHz inductive radiofrequency unit. Aqueous thermoseed suspension was delivered to the tumor by simple percutaneous injection. The limitation of the thermoseed heating method is the positional change of thermoseed particles in the tumor after implantation. The thermoseed particles could enter the systemic blood circulation and cause a severe embolization of a critical organ. To minimize this limitation, we have used the magnetic control after loading the thermoseed in the tumor, W hen ferropolysaccharides were exposed to a strong magnetic field, they magnetized and subsequently exerted a magnetic force on each other, forming larger aggregates of particles. The size of aggregated Particles were too big to enter the systemic blood circulation. Thus, unlike other thermoseed method, we hold the thermoseed particles stationary in the tumor. The temperature of the injected site and immediate vicinity elevated by $4-5^{\circ}C$. The temperature of the surrounding normal hepatic tissue elevated by $1-2^{circ}C$ only. The heating effect within the tumor was variable depending on the density of ferromagnetic aqueous suspension. Our results suggest that inductive heating of tumor injected with ferropolysaccharide solution offers the possibility of effective heat delivery to the defined tumor volume, which is difficult to heat with other heating devices.

  • PDF

Effect of Process Conditions on the Microstructure of Particle-Stabilized Al2O3 Foam

  • Ahmad, Rizwan;Ha, Jang-Hoon;Hahn, Yoo-Dong;Song, In-Hyuck
    • Journal of Powder Materials
    • /
    • v.19 no.4
    • /
    • pp.278-284
    • /
    • 2012
  • $Al_2O_3$ foam is an important engineering material because of its exceptional high-temperature stability, low thermal conductivity, good wear resistance, and stability in hostile chemical environment. In this work, $Al_2O_3$ foams were designed to control the microstructure, porosity, and cell size by varying different parameters such as the amount of amphiphile, solid loading, and stirring speed. Particle stabilized direct foaming technique was used and the $Al_2O_3$ particles were partially hydrophobized upon the adsorption of valeric acid on particles surface. The foam stability was drastically improved when these particles were irreversibly adsorbed at the air/water interface. However, there is still considerable ambiguity with regard to the effect of process parameters on the microstructure of particle-stabilized foam. In this study, the $Al_2O_3$ foam with open and closed-cell structure, cell size ranging from $20{\mu}m$ to $300{\mu}m$ having single strut wall and porosity from 75% to 93% were successfully fabricated by sintering at $1600^{\circ}C$ for 2 h in air.

Dispersion stability of ultra-fine $BaTiO_3$ suspensions in aqueous medium

  • Chun, M.P.;Chung, Y.B.;Ma, Y.J.;Cho, J.H.;Kim, B.I.
    • Journal of the Korean Crystal Growth and Crystal Technology
    • /
    • v.15 no.6
    • /
    • pp.239-243
    • /
    • 2005
  • The effect of pH and particle size on the dispersion stability of ultra-fine $BaTiO_3$ suspensions in aqueous medium have been investigated by means of zeta potential, sediment experiments, and powder properties (particle analysis, specific surface area) etc. Zeta potential as a function of pH for two particles of different size increases from -75 to +10 mV with decreasing pH from 8.5 to 1.4. The curve of zeta potential for small particle (150 nm) has slow slope than that of large particle (900nm), giving IEP (isoelectric point) value of pH=1.6 for small particle and pH=1.9 for large particle respectively, which means that it is more difficult to control zeta potential with pH fur small particle than large particle. The dispersion stability of $BaTiO_3$ particles in aqueous medium was found to be strongly related with the agglomeration of colloidal suspensions with time through the sedimentation behaviors of colloidal particles with time and pH value.

A Study on Performance Evaluation for Oil Mist Removal using a High-speed Centrifugal Cyclone (고속원심분리 사이클론을 이용한 오일 미스트 제거 성능 연구)

  • Kim, SooYeon;Kim, Jin-Seon;Sung, Jin-Ho;Han, Bangwoo;Kim, Yong-Jin;Kim, Hak-Joon
    • Particle and aerosol research
    • /
    • v.15 no.4
    • /
    • pp.139-148
    • /
    • 2019
  • This study was performed for the application of a high-speed centrifugal cyclone to shale gas mining process. This device uses the centrifugal force to control particles similar to typical cyclones, and the disk located inside the cyclone is forced to rotate using a motor. The pressure difference occurred during the rotating of disk. Hence, inflow rate was generated without a blower fan. In addition, flow rate increased with elevating rpm of motor. The installing the disk in multiple stages on the inner rotor increased the instantaneous disk outlet flow. Hence, the control efficiency of oil particle increased from 1.05% to 31.2%. By modifying the structure of the disk so that the air flow to the opposite direction of the cyclone, the control efficiency of oil particles increased to 81.5%. By increasing the capacity of the motor and the size of the disk, the flow rate was increased to 2.5 ㎥/min because the rpm of motor and pressure difference increased. As rpm of motor increased, the cut-off diameter (dpc) became smaller. Unlike the Lapple's equation, dpc was inversely proportional to the effective number of rotations (Ne). The control efficiency was maintained even if the concentration of oil particles increased, for this reason, the higher the oil concentration, the more particles were accumulated and controlled.

Formation of Nanoparticles by Spark Discharge in Liquid (용액 내 스파크 방전을 이용한 나노입자 제조 및 특성 평가)

  • Choi, Hoomi;Kim, Jangah;Jung, Seungkyo;Yoon, Juho;Kim, Taesung
    • Particle and aerosol research
    • /
    • v.8 no.1
    • /
    • pp.37-43
    • /
    • 2012
  • In this study, we designed a 'spark in liquid' system. The spark discharge between two electrodes were used to generate particles by using sufficient temperature to evaporate a part of electrodes. The power supply system provides a continuous spark discharge by discharging of the capacitor to ionize the electrodes in liquid. The DC spark discharge system operates with 1-10 kV voltage. Processed copper and graphite rods were used to both electrodes with 1-3 mm diameter. There are several variables which can control the particle size and concentration such as gap distance between electrodes, applied voltage, operating liquid temperature, electrode type and liquid type. So we controlled these variables to confirm the change of particle size distribution and concentration of particles contained in liquid as wt%. 'spark in liquid' system is expected to apply nanoink by control of concentration with analysis of characteristics.

Experimental Study on the Microencapsulated PCM as a Thermal Storage Medium (미립잠열재를 이용한 축열 특성에 관한 실험적 연구)

  • 이효진;이재구
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
    • /
    • v.13 no.2
    • /
    • pp.80-87
    • /
    • 2001
  • Microencapsulated PCM particles are mixed with distilled water and utilized to evaluate its characteristics and performance as a thermal storage medium transporting heat. For the present study, tetradecane(C$_14H_30, T_m=5.5^{\circ}C$) is capsulated in the core with the melamine of its surface. The size of particles is well-controlled under 10${\mu}{\textrm}{m}$ in the way of in-situ polymerization with melamine-formaldehyde resin. For the experiment, the concentrations of slurries are prepared for 20wt%, 30wt%, and 40wt%. The results are compared with those of water and 100% tetradecane oil. The pure water and tetradecane start solidifying within 20 minutes after introducing cooling water into the thermal storage tank whose tank whose flow rates are varied by 125cc/min, 250cc/min, and 500cc/min. However, MicroPCM slurries are required relatively longer period of time for their phase change than pure phase change materials. That is, the entrained MicroPCM particles control its heat transfer in terms of natural convection and conducting to them.

  • PDF

Particle Attachment in Granular Media Filtration (입상여과에서 입자물질의 부착)

  • Kim, Jinkeun
    • Journal of Korean Society of Water and Wastewater
    • /
    • v.18 no.5
    • /
    • pp.666-672
    • /
    • 2004
  • Granular media filtration is used almost universally as the last particle removal process in conventional water treatment plants. Therefore, superb particle removal efficiency is needed during this process to ensure a high quality of drinking water. However, every particle can not be removed during granular media filtration. Besides the pattern of particle attachment is different depending on physicochemical aspects of particles and suspension. Filtration experiments were performed in a laboratory-scale filter using spherical glass beads with a diameter of 0.55 mm as collectors. A single type of particle suspension (Min-U-Sil 5) and pH control was used to destabilize particles. The operating conditions were similar to those of standard media filtration practice: a filtration velocity of 5 m/h. More favorable particles, i.e., particles with smaller surface charge, were well attached to the collectors especially during the early stage of filtration. This selective attachment of the lower charged particles caused the zeta potential distribution (ZPD) of the effluent to move to a more negative range. On the other hand, the ZPD of the effluent did not keep moving from less negative to more negative during the later stages of filtration, and this result was thought to be caused by two reasons: ripening effects and the detachment of flocs.

Effect of Si Particle Size on the Thermal Properties of Hyper-eutectic Al-Si Alloys (과공정 Al-Si 합금의 열팽창 특성에 미치는 Si 입자 크기의 영향)

  • Kim, Chul-Hyun;Joo, Dae-Heon;Kim, Myung-Ho;Yoon, Eui- Pak;Yoon, Woo-Young;Kim, Kwon-Hee
    • Journal of Korea Foundry Society
    • /
    • v.23 no.4
    • /
    • pp.195-203
    • /
    • 2003
  • Hyper-eutectic Al-Si alloy is used much to automatic parts and material for the electronic parts because of the low coefficient of thermal expansion, superior thermal stability and superior wear resistance. In this work, A390 alloy specimens were fabricated for control of the Si particle size by various processes, such as spray-casting, permanent mold-casting and squeeze-casting. To minimize the effect of microporosity of the specimens, hot extrusion was carried out under equal condition. Each specimens were evaluated tensile properties at room temperature and thermal expansion properties in the range from room temperature to 400$^{\circ}C$. Ultimate tensile strength and elongation of the spray-cast and extruded specimens which have fine and well distributed Si particles were improved greatly compare to the permanent mold-cast and extruded ones. Specimens which have finer Si particles showed higher ultimate tensile strength and elongation than those having large Si particle size, and coefficient of thermal expansion of the specimens increased linearly with Si particle size. In case of the repeated high temperature exposures, thermal expansion properties of the spray-cast and extruded specimens were found to be more stable than those of the others due to the effect of fine and well distributed Si particles.

Analysis of Grain Size Controlled Rheology Materials Dynamics for Prediction of Solid Particles Behavior (레오로지 소재의 고상입자 거동 예측을 위한 결정립 동력학 해석)

  • Kim H.I.;Kang C.G.
    • Proceedings of the Korean Society of Precision Engineering Conference
    • /
    • 2005.06a
    • /
    • pp.1337-1340
    • /
    • 2005
  • A rheology casting technology has some advantages compared with conventional forming processes such as die casting, squeeze casting and hot/cold forming. The liquid segregation is important on mechanical properties of materials using rheology casting. In this study, so, molecular dynamics simulations were performed for the control of liquid segregation. Because the dynamics of fluid flow about nano-scaled materials is completely different from continuum, molecular dynamics simulations were used. The behavior of particles was far from the truth according to boundary conditions in simple flow. But various movement of particles appear at two or more molecular simulations.

  • PDF