• Journal of Soil and Groundwater Environment
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• v.13 no.3
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• pp.21-26
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• 2008

Nitrate adsorption from aqueous solutions onto zinc chloride ($ZnCl_2$) treated coconut Granular Activated Carbon (GAC) was studied in a batch mode at two different initial nitrate concentrations (25 and 50 mg/L). The rate of nitrate uptake on prepared media was fast in the beginning, and 50% of adsorption was occurred within 10 min. The adsorption equilibrium was achieved within one hour. The mechanism of adsorption of nitrate on $ZnCl_2$ treated coconut GAC was investigated using four simplified kinetic models : the rate parameters were calculated for each model. The kinetic analysis indicated that pseudo-second-order kinetic with pore-diffusion-controlled was the best correlation of the experimental kinetic data in the present adsorption study.

• Economic and Environmental Geology
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• v.52 no.4
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• pp.291-297
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• 2019

Fluid flow through rock fractures has been quantified using equations such as Stokes equations, Reynolds equation (or local cubic law), cubic law, etc. derived from the Navier-Stokes equations under the assumption that linear flow prevails. Therefore, these simplified equations are limited to linear flow regime, and cause errors in nonlinear flow regime. In this study, causal mechanism of nonlinear flow and critical Reynolds number were presented by carrying out fluid flow modeling with both the Navier-Stokes equations and the Stokes equations for a three-dimensional rough-walled rock fracture. This study showed that flow regimes changed from linear to nonlinear at the Reynolds number greater than 10. This is because the inertial forces, proportional to the square of the fluid velocity, increased enough to overwhelm the viscous forces. This tendency was also shown for the unmated (slightly sheared) rock fracture. It was found that nonlinear flow was caused by the rapid increase in the inertial forces with increasing fluid velocity, not by the growing eddies that have been ascribed to nonlinear flow.

• Smart Structures and Systems
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• v.23 no.6
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• pp.589-613
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• 2019

Cables are prone to vibration due to their low inherent damping characteristics. Recently, negative stiffness dampers have gained attentions, because of their promising energy dissipation ability. The viscous inertial mass damper (termed as VIMD hereinafter) can be viewed as one realization of the inerter. It is formed by paralleling an inertial mass part with a common energy dissipation element (e.g., viscous element) and able to provide pseudo-negative stiffness properties to flexible systems such as cables. A previous study examined the potential of IMD to enhance the damping of stay cables. Because there are already models for common energy dissipation elements, the key to establish a general model for IMD is to propose an analytical model of the rotary mass component. In this paper, the characteristics of the rotary mass and the proposed analytical model have been evaluated by the numerical and experimental tests. First, a series of harmonic tests are conducted to show the performance and properties of the IMD only having the rotary mass. Then, the mechanism of nonlinearities is analyzed, and an analytical model is introduced and validated by comparing with the experimental data. Finally, a real-time hybrid simulation test is conducted with a physical IMD specimen and cable numerical substructure under distributed sinusoidal excitation. The results show that the chosen model of the rotary mass part can provide better estimation on the damper's performance, and it is better to use it to form a general analytical model of IMD. On the other hand, the simplified damper model is accurate for the preliminary simulation of the cable responses.

• Structural Engineering and Mechanics
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• v.77 no.1
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• pp.137-149
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• 2021

In engineering design, the axial equivalent elastic modulus of laminated FRP pipe was mostly calculated by the average elastic modulus method or the classical laminated plate theory method, which are based on relatively simplified assumptions, and may be not accurate enough sometimes. A new analytical calculation method for the axial equivalent elastic modulus of laminated FRP pipe was established based on three-dimensional stress state. By comparing the results calculated by this method with those by the above two traditional analytical methods and the finite element method, it is found that this method for the axial equivalent elastic modulus fits well not only for thin-walled pipes with orthotropic layers, but also for thick-walled pipes with arbitrary layers. Besides, the influence of the layer stacking on the axial equivalent elastic modulus was studied with this method. It is found that a proper content of circumferential layer is beneficial for improving the axial equivalent elastic modulus of the laminated FRP pipe with oblique layers, and then can reduce its material quantity under the premise that its axial stiffness remains unchanged. Finally, the meso-mechanical mechanism of this effect was analyzed. The improving effect of circumferential layer on the axial equivalent elastic modulus of the laminated FRP pipe with oblique layers is mainly because that, the circumferential fibers can restrain the rigid body rotations of the oblique fibers, which tend to cause the significant deformations of the pipe wall units and the relatively low axial equivalent elastic modulus of the pipe.

• Advances in nano research
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• v.13 no.3
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• pp.207-216
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• 2022

In this paper, a novel model is developed for frequency behavior of single walled carbon nanotubes. The governing equation of motion is constructed method based on the Sander theory using Rayleigh-Ritz's method The frequencies enhances on increasing the power law index using simply supported, clamped and clamped free end conditions. The frequency curve for C-F is less than other conditions. It is due to the physical constraints which are applied on the edge of the CNT. It is observed that the C-F boundary condition have less frequencies from the other two conditions. The frequency phenomena for zigzag are insignificant throughout the aspect ratio. Moreover when index of power law is increased then frequencies increases for all boundary conditions. The natural frequency mechanism for the armchair (10, 10) for various values of power law index with different boundary conditions is investigated. Here frequencies decrease on increases the aspect ratio for all boundary conditions. The frequency curves of SS-SS edge condition is composed between the C-C and C-F conditions. The curves of frequency are less significant from small aspect ratio (L/d = 4.86 ~ 8.47) and decreases fast for greater ratios. It is found that the frequencies via aspect ratios, armchair (10, 10) have higher values from zigzag (10, 0). It is due to the material structure which is made by the carbon nanotubes. The power law index have momentous effect on the vibration of single walled carbon nanotubes. The present frequency result is also compared numerically experimentally with Raman Spectroscopy.

• The Korea Journal of Herbology
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• v.33 no.5
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• pp.19-37
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• 2018

Objectives : Oryeong-san was composed of Alismatis Rhizoma, Atractylodis Rhizoma Alba, Poria Sclerotium, Polyporus, Cinnamomi Cortex, and known to have hundreds of chemical compounds. The aim of this study was to screen chemical compounds constituting Oryeong-san with the drug-likeness and oral bioavailability from the analysis of their physicochemical properties. Methods : A list of chemical compounds of Oryeong-san was obtained from TM-MC(database of medicinal materials and chemical compounds in Northeast Asian traditional medicine). To remove redundant compounds, the SMILES (Simplified Molecular Input Line Entry System) strings of each compound were identified. All of the physicochemical properties for the compounds were calculated using the DruLiTo(Drug Likeness Tool). Drug-likeness was estimated by QED(Quantitative Estimate of Druglikeness) and OB(Oral bioavailability) was checked based on the Veber's rules. Results : A total of 475 compounds were obtained by eliminating duplication among 544 compounds of 5 medicinal materials. Analysis of the physicochemical properties revealed that the most common values were MW(molecular weight) 200~300 g/mol, ALOGP(octanol-water partition coefficient) 1~2, HBA(number of hydrogen bond acceptors) 0~1, HBD(number of hydrogen bond donors) 0, PSA(polar surface area) 0~50 angstrom, ROTB(number of rotatable bonds) 1, AROM(number of aromatic rings) 0, and ALERT(number of structural alerts) 1. QED had 93% of the values between 0.2 and 0.7, and OB had 90% of the value of TRUE. Conclusions : We in this paper screened the candidate active compounds of Oryeong-san using the QED and Veber's rules. In the future, we will use the screening results to analyze the mechanism of Oryeong-san based on systems pharmacology.

• Journal of Korean Society of Steel Construction
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• v.24 no.3
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• pp.337-348
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• 2012

This study investigated the characteristics of bifurcation and the instability due to the initial imperfection of the space truss, which is sensitive to the initial conditions, and the calculated buckling load by the analysis of Eigen-values and the determinant of tangential stiffness. A two-free nodes model, a star dome, and a three-ring dome model were selected as case studies in order to examine the unstable phenomenon due to the sensitivity to Eigen mode, and the influence of the rise-span ratio and the load parameter on the buckling load were analyzed. The sensitivity to the imperfection of the two-free nodes model changed the critical path after reaching the limit point through the bifurcation mode, and the buckling load level was reduced by the increase in the amount of imperfection. The two sensitive buckling patterns for the model can be explained by investigating the displaced position of the free node, and the asymmetric Eigen mode was a major influence on the unstable behavior due to the initial imperfection. The sensitive mode was similar to the in-extensional mechanism basis of the simplified model. Since the rise-span ratio was higher, the effect of local buckling is more prominent than the global buckling in the star dome, and bifurcation on the equilibrium path occurring as the value of the load parameter was higher. Additionally, the buckling load levels of the star dome and the three-ring model were about 50-70% and 80-90% of the limit point, respectively.

• Journal of the Korea Concrete Institute
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• v.18 no.5 s.95
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• pp.611-620
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• 2006

In the shear failure mechanism of a beam, beam and arch actions always exist simultaneously. According to the shear span to depth ratio, the proportion between these two actions is varied and the contribution of these actions to shear capacity is changed. Moreover, the current codes provide recommendations based on experimental results of normal strength concrete, so the application range of concrete strength must be extended. Based on this mechanism and new requirement, a simplified analytical equation for shear capacity prediction of reinforced high strength concrete beams without stirrups is proposed. To reflect the change in the contribution between these actions, stress variation in the longitudinal reinforcement along the span is considered by use of the Jenq and Shah Model. Dowel action with horizontal splitting failure and shear friction between cracks are also taken into account. ize effect is included to derive a more precise equation. Regression analysis is performed to determine each variable and simplify the equation. And, the formula derived from theoretical approaches is evaluated by comparison with numerous experimental data, which are in broad range of concrete strength(especially in high strength concrete), shear span to depth ratio, geometrical size and longitudinal steel ratio. It is shown that the proposed equation is more accurate and simpler than other empirical equations, so a wide range of a/d can be considered in one equation.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.29 no.1
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• pp.73-83
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• 1997

Most of the materials used in various industrial fields and also in our daily life are multi-component materials or composite materials, and it is well known that there are many cases where adhesion between the constituents within the bonded systems plays an important role. There are various types of performance evaluation tests for the bonded materials, among which tests for evaluating the bond performance under various conditions may be regarded as the most interesting ones for those engaged in work related to adhesion. I have studied on the mechanism of adhesion form the rheological standpoint with my colleagues, including some students from Korea, and I am very happy to be able to have a talk on some of our research works. In Japan, the so-called "adhesives" are usually classified into two categories;adhesives and pressure sensitive adhesives (PSA). Adhesives are the materials which solidify after bonding and are after used as the structural adhesives because the adhesive strength is comparatively strong. On the other hand, the pressure sensitive adhesives never solidify and are used as PSA tapes, labels or decals. About the adhesives, we have examined the dependence of adhesive strength(shear, tensile, peel) upon both temperature and rate of deformation, and found out some empirical rules which are applicable to most of the adhesive systems. We have also developed a simplified theory of adhesion, which is deseribed in terms of mechanical equivalent mode1 and a few failure criteria. Although some of the common rules can be accounted for according to this theory, it must be pointed out that a fracture mechanical approach ms inevitable especially in the region where the meehanical relaxation time of the adhesive is extremely large [W. W. Lim and H. Mizumachi]. About the pressure sensitive adhesives, we have studied on the PSA performance (peel, tack, holding power) as a function of both the viscoelastic properties and surface chemical properties of the materials, and found out some rules, and again we have developed a theory which deseribes the mechanism. And in addition, we have studied on the miscibility between linear polymers and oligomers, because PSA is generally manufactured by blending gums and tackifier resins. Many phase diagrams have been found and some of them have been analyzed on thermodynamic basis, and it became evident that the miscibility is a very important factor in PSA [H. J. Kin and H. Mizumachi]. In this presentation, I want to emphasize the fact that the adhesion performance is closely related to the structure/property of the adhesives.adhesives.

• Journal of Korean Society of Steel Construction
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• v.16 no.6 s.73
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• pp.793-805
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• 2004

The main objective of this paper is to evaluate the ductility and strength factors that are key components of the response modification factor for special steel moment-resistant frames. The ductility factors for special steel moment-resistant frames were calculated by multiplying the ductility factor for SDOF systems and the MDOF modification factors. Ductility factors were computed for elastic and perfectly plastic SDOF systems undergoing different levels of inelastic deformation and periods when subjected to a large number of recorded earthquake ground motions. Based on the results of the regression analysis, simplified expressions were proposed to compute the ductility factors. Based on previous studies, the MDOF modification factors were also proposed to account for the MDOF systems. Strength factors for special steel moment resisting frames were estimated from the results of the nonlinear static analysis. A total of 36 sample steel frames were designed to investigate the ductility and strength factors considering design parameters such as number of stories (4, 8, and 16 stories), seismic zone factors (Z = 0.075, 0.2, and 0.4), framing system (Perimeter Frames, PF and Distributed Frames, DF), and failure mechanism (Strong-Column Weak Beam, SCWB, and Weak-Column Strong-Beam, WCSB). The effects of these design parameters on the ductility and strength factors for special steel moment-resisting frames were investigated.