• Korean Chemical Engineering Research
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• 제59권3호
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• pp.467-479
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• 2021

Abstract: A kinetic model was developed for the dehydration of ethanol to ethylene based on two parallel reaction pathways. Kinetic parameters were estimated by fitting experimental data of powder catalysts in a lab-scale test, and the effectiveness factor was determined using data from pellet-type catalysts in bench-scale experiments. The developed model was used to design a multitubular fixed-bed reactor (MTR) and an adiabatic reactor (AR) at a 10 ton per day scale. The two different reactor types resulted in different process configurations: the MTR consumed the ethanol completely and did not produce the reaction intermediate, diethyl ether (DEE), resulting in simple separation trains at the expense of high equipment cost for the reactor, whereas the AR required azeotropic distillation and cryogenic distillation to recycle the unreacted ethanol and to separate the undesired DEE, respectively. Quantitative analysis based on the equipment and annual energy costs showed that, despite high equipment cost of the reactor, the MTR process had the advantages of high productivity and simple separation trains, whereas the use of additional separation trains in the AR process increased both the total equipment cost and the annual energy cost per unit production rate.

• 대한토목학회논문집
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• 제29권5A호
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• pp.531-541
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• 2009

본 연구에서는 강도수준(30, 50 및 70 MPa)에 따른 고유동 자기충전 콘크리트의 수화발열 특성을 알아보기 위하여 2성분계 및 3성분계 고유동 자기충전 콘크리트를 제조하여 일반콘크리트와 수화열, 응결 및 역학적 특성을 분석 고찰 하였으며, 콘크리트에 사용된 분체에 대한 미소수화열량을 측정하여 얻은 분체의 열특성값, 간이단열온도실험을 실시하여 얻은 콘크리트의 열특성값 및 콘크리트에 사용된 재료의 일반적인 열특성값을 간편한 방법의 추정식을 이용하여 콘크리트 단열온도를 추정하였다. 또한, 온도해석에 의하여 얻어진 수화열 및 단열온도 특성값을 MIDAS CIVIL 06 프로그램을 이용하여 3차원 온도응력 해석을 실시하여 고유동 자기충전 콘크리트의 수화발열 특성 및 수화열에 의한 온도응력을 분석 고찰하였다.

• 한국분말재료학회지
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• 제20권5호
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• pp.332-337
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• 2013

Recently, self-propagating high-temperature synthesis (SHS), related to metallic and ceramic powder interactions, has attracted huge interest from more and more researchers, because it can provide an attractive, energy-efficient approach to the synthesis of simple and complex materials. The adiabatic temperature $T_{ad}$ and apparent activation energy analysis of different thermit systems plays an important role in thermodynamic studies on combustion synthesis. After establishing and verifying a mathematic calculation program for predicting adiabatic temperatures, based on the thermodynamic theory of combustion synthesis systems, the adiabatic temperatures of the NiO/Al aluminothermic system during self-propagating high-temperature synthesis were investigated. The effect of a diluting agent additive fraction on combustion velocity was studied. According to the simulation and experimental results, the apparent activation energy was estimated using the Arrhenius diagram of $ln(v/T_{ad}){\sim}/T_{ad}$ based on the combustion equation given by Merzhanov et al. When the temperature exceeds the boiling point of aluminum (2,790 K), the apparent activation energy of the NiO/Al aluminothermic system is $64{\pm}14$ kJ/mol. In contrast, below 2,790 K, the apparent activation energy is $189{\pm}15$ kJ/mol. The process of combustion contributed to the mass-transference of aluminum reactant of the burning compacts. The reliability of the simulation results was experimentally verified.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2004년도 춘계 학술발표회 제16권1호
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• pp.450-453
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• 2004

The present study is a basic experiment on the estimation of the compression strength of high strength concrete, aiming at estimating the compression strength of mass test pieces of high strength concrete by giving the temperature hysteresis of the mass test pieces to managerial test pieces. Thus, this study made concrete test pieces in an optimal mix ratio for each strength level, and also created adiabatic curing tank and managerial test pieces. Then it carried out comparative analysis in relation to core strength and suggested equipment and a technique that can control the strength of high strength concrete mass more conveniently and accurately.

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2001년도 춘계학술대회 논문집
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• pp.205-208
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• 2001

Localized shear band is investigated through the analysis of one-dimensional model for simple shearing deformation of thermally rate dependent material. Generally mesh size or interval of nodes play an important role in determining the overall flow behavior of the material. In order to observe these size effects we adapted non-local theory by including higher order strain gradients of the equivalent strain into the constitutive equation for the flow stress. for the ease of convergence and numerical stability the inplicit finite difference scheme is employed.

• 한국추진공학회지
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• 제10권1호
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• pp.23-29
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• 2006

환형 분사 초음속 이젝터에서는 초음속의 주유동이 벽면을 타고 분사되므로 주유동 노즐 출구(혼합 챔버 입구)에서 혼합챔버의 수축각에 의한 깔때기(funnel) 모양의 경사충격파가 발생한다. 본 연구에서는 이차원(Wedge) 경사충격파와 원뿔(Cone) 경사충격파를 이용하여 간단한 깔때기 경사충격파 모델링(Modeling)을 수행하였다. 이러한 모델링을 이용하여 기존의 이차원 경사충격파를 이용한 이론해석 보다 부유동 압력을 보다 정확히 예측할 수 있었다. 같은 해석 방법을 이용하여 유량비에 대한 초음속 이젝터의 압축비와 단열 효율을 얻을 수 있었다.

• 대한건축학회논문집:구조계
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• 제35권10호
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• pp.207-215
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• 2019

The aim of the research is analyzing the simple adiabatic temperature rising properties and the heat of hydration based on different placing timing of the mass concrete depending on various replacing ratios of blast furnace slag to comparative analyze the thermal cracking index and cracking possibility. As a result from the experiment, a suggested adiabatic temperature rising equation based on various blast furnace slag replacing ratios can be provide favorable correlation with over 0.99 of $R^2$ value by applying the initial induction period. With this relationship, more accurate prediction of the amount of the hydration heat rising and heating timing, and it is known that there is an approximately $13.1^{\circ}C$ of gap between plain concrete without blast furnace slag and concrete with 80 % of replacing blast furnace slag. To control the setting time and heat rising gap, the mix designs between top and bottom concrete casts were changed 15 cases, and D, E, H, I, and L models of controlling the heat of hydration showed 41.23 to $46.88^{\circ}C$ of core temperature and 0.98 to 1.27 of thermal cracking index. Therefore the cracking possibility was 15 to 52 % of favorable results of possibly controlling both the cracking due to the internal and external retainment and concrete temperature at early age.

• 한국터널지하공간학회 논문집
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• 제11권1호
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• pp.37-45
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• 2009

본 연구는 대형 대단면 터널 라이닝 구조물에 적용하기 위해 50 MPa급 고성능 콘크리트의 개발 및 적용을 위한 실험을 수행하였다. 이를 위해 플라이애쉬와 고로슬래그미분말을 1종 시멘트 단위량의 50%까지 치환한 8종의 배합을 선정하여, 8종의 배합의 역학적 특성에 관한 실험과 간이 단열온도 상승실험을 실시하였다. 또한 정량적인 평가를 위해 8종의 배합 중 1종 시멘트만을 사용한 배합(OPC) 및 2성분계 배합과 3성분계 배합중 각각 1종(BS30, F15S35)을 재선정하여 단열온도 상승실험과 Mock-up 실험을 수행하였다. 실물 부재 크기의 시험체의 수화열 측정결과는 유한요소해석과 비교하여 해석루틴의 신뢰도 향상을 기대할 수 있었다.

• 태양에너지
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• 제6권2호
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• pp.62-69
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• 1986

An analysis is made of the fully developed laminar flow and heat transfer in a parallel flat plate with heated rectangular block arrays to investigated the influence of bouyancy force. The shrouds is considered as adiabatic, while the heated block surface transmit a uniform rate of heat flux per unit axial length. The governing equations for velocity and temperature are solved by SIMPLE(Semi-Implicit Method Pressure Linked Equation) algorithm. Detailed velocity and temperature fields and overall heat transfer on wide range of Rayleigh number and various aspect ratios of heated rectangular blocks are computed. The result show that bouyancy leads to a significient enhancement in heat transfer along with a smaller increase in pressure drop, with the great enhancement found when the aspect ratio is 3.0.

• 대한설비공학회지:설비저널
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• 제16권2호
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• pp.204-215
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• 1987

Laminar natural convective heat transfer within a two-dimensional rectangular enclosure with horizontal conducting walls and partitions was investigated by numerical analysis and experiment. The enclosure consists of two isothermal vertical walls and two adiabatic horizontal walls. This combined heat transfer problem of conduction and natural convection was solved using finite difference method with SIMPLE algorithm, and temperature distribu-tions in the air filled enclosure was obtained using Mach-Zehnder interferometer. Good agree-ment was obtained between the predicted and measured results. The effect of geometric parameters and thermal properties on heat transfer was studied far Grashof numbers in range, $1\times10^4\;{\leqslant}\;G^r\;{\leqslant}\;6.4\times10^5.$ It was found that both velocity and temperature fields were in-fluenced significantly by thermal conductivity of the conducting walls and the partitions, and by geometry of partitions.