• Title/Summary/Keyword: Silver complex

Search Result 159, Processing Time 0.028 seconds

Occurrence and Geochemistry of Argyrodite, a Germanium-Bearing Mineral(Ag8GeS6), from the Weolyu Ag-Au Hydrothermal Vein Deposits (월류(月留) 은(銀)-금(金) 열수광상(熱水鑛床)에서 산출된 함(含) Ge 광물(鑛物)인 Argyrodite의 산상(産狀)과 지구화학(地球化學))

  • So, Chil-Sup;Yun, Seong-Taek;Choi, Seon-Gyu
    • Economic and Environmental Geology
    • /
    • v.26 no.2
    • /
    • pp.117-127
    • /
    • 1993
  • Ag-Au vein ores from the Weolyu mine, Youngdong district, contain significant germanium (up to 145g/t, average 34.9g/t), in the form of argyrodite ($Ag_8GeS_6$). Mineral chemistries of argyrodite and its associated minerals were determined by electron probe microanalysis. Twenty eight elements in thirteen ore samples were analyzed using an ICP mass spectrometer. Argyrodite occurs in the paragenetically later mineral assemblage consisting of carbonates+quartz+native silver+argentite+Ag-sulfosalts, indicating that the germanium mineralization represents the culmination of a complex mineral sequence which includes early gold and late silver deposition. The mean formula of the argyrodite is $Ag_{7.90}\;(Ge_{0.76}Sn_{0.04})S_6$, with minor amounts of Cu, Fe, Sb, As, Sn, and Zn. The Weolyu argyrodite shows systematic substitutions of Ag by Cu, and of Ge by Sb. Chemical analyses of vein ores indicate that metals were precipitated in the order of $Fe{\rightarrow}Pb$, $Zn{\rightarrow}Cu{\rightarrow}Ag$, Sb, As, Ge. Germanium has a strong geochemical affmity with As and Sb, and Cu, Pb, Zn, Mo, and Sr show weak positive correlations with Ge. Germanium deposition at Weolyu was mainly a result of cooling of hydrothermal fluids (down to $175^{\circ}C{\sim}210^{\circ}C$, due to increasing involvement of cooler meteoric waters in the epithermal system.

  • PDF

Application of Precipitate Flotation Technique to Separative Preconcentration and Determination of Arsenic in Water Samples (물시료 중 비소의 분리 정량을 위한 침전 부선기술의 응용)

  • Park Sang-Wan;Choi Hee-Seon;Kim Young-Man;Kim Young-Sang
    • Journal of the Korean Chemical Society
    • /
    • v.35 no.4
    • /
    • pp.389-396
    • /
    • 1991
  • The pre-concentration and determination of ultratrace arsenic in water samples was studied by the precipitate flotation technique. The arsenic in 1.0l of water sample, in which all suspended materials were filtered out, was coprecipitated together with La(OH)$_3$ precipitates at pH 8.5${\pm}$0.1. After the precipitate was made to be hydrophobic by adding mixed surfactant of 1 : 8 mole ratio of sodium oleate and sodium dodecyl sulfate, it was floated with the aid of tiny bubbles of nitrogen gas in a flotation cell. The floated precipitate was quantitatively collected on a micropore glass filter by the suction, dissolved with small volume of 1.0M sulfuric acid, and accurately diluted to 25.00ml with a de-ionized water. Total arsenic was spectrophotometrically determinated by forming silver diethyldithiocarbamate complex of arsine generated from arsenic in the concentrated solution. The calibration curve was linear up to 20ng/ml in the original solution. Analytical results showed that contents of arsenic in a campus wastewater and a river water were 8.2ng/ml and l.0ng/ml, respectively, and their recoveries were 93${\%}$ and 90${\%}$ in water samples which a given amount of arsenic was added into. From above result, it could be concluded that this method was applicable to the determination of arsenic in various kinds of water at low ng/ml levels.

  • PDF

한국 금-은광화작용과 천열수 광상의 성인모델: 탐사에의 적용

  • 최선규;박상준;김창성
    • Proceedings of the KSEEG Conference
    • /
    • 2002.10a
    • /
    • pp.119-136
    • /
    • 2002
  • Contrasts in the style of the gold-silver mineralization in geologic and tectonic settings in Korea, together with radiometric age data, reflect the genetically different nature of hydrothermal activities, coinciding with the emplacement age and depth of Mesozoic magmatic activities. It represents a clear distinction between the plutonic settings of the Jurassic Daebo orogeny and the subvolcanic environments of the Cretaceous Bulgugsa igneous activities. Dunng the Daebo igneous activities (c.a. 200~150 (\ulcorner) Ma) coincident with orogenic time, gold mineralization took place between c.a. 195 and 135 (127 \ulcorner) Ma. The Jurassic Au deposits commonly show several characteristics; prominent association with pegmatites, low Ag/Au ratios In the ore-concentrating parts, massive vein morphology and a distinctively simple mineralogy including Fe-rich sphalerite, galena, chalcopyrite, arsenopyrite, Au-rich electrum, pyrrhotite and/or pyrite. During the Bulgugsa igneous activities (110~50 Ma), the precious-metal deposits are generally characterized by such features as complex vein morphology, medium to high Ag/Au ratios in the ore concentrates, and diversity of ore minerals including base-metal sulfides, pyrite, arsenopyrite, Ag-rich eletrum and native silver with Ag sulfides, Ag-Sb-As sulfosalts and he tellurides. Vein morphology, mineralogical, fluid inclusion and stable isotope results indicate the diverse genetic natures of hydrothermal systems in Korea. The Jurassic Au-dominant deposits (orogenic type) were formed at the relatively high temperature (about 300$^{\circ}$ to 45$0^{\circ}C$) and deep-crustal level (4.0$\pm$1.5 kb) from the hydrothermal fluids containing more amounts of magmatic waters ($\delta$$^{18}$ $O_{H2O}$; 5~10$\textperthousand$). It can be explained by the dominant ore-depositing mechanisms as $CO_2$ boiling and sulfidation, suggestive of hypo- to mesothermal environments. In contrast, the Cretaceous Au-dominant (l13~68 Ma), Au-Ag (108~47 Ma) and AE-dominant (103~45 Ma) deposits, which correspond to volcanic-plutonic-related type, occurred at relatively low temperature (about 200$^{\circ}$ to 35$0^{\circ}C$) and shallow-crustal level (1.0$\pm$0.5 kb) from the ore-forming fluids containing more amounts of less-evolved meteonc waters ($\delta$$^{18}$ $O_{H2O}$;-10~5$\textperthousand$). These characteristics of the Cretaceous precious-metal deposits can be attributed to the complekities in the ore-precipitating mechanisms (mixing, boiling, cooling), suggestive of epi- to mesothermal environments. Therefore, the differences of the emplacement depth between the Daebo and the Bulgugsa igneous activities directly influence the unique temporal and spatial association of the deposit styles.les.

  • PDF

Secretory Proteins from Goat Oocytes Matured in Culture

  • Malakar, Dhruba;Majumdar, A.C.
    • Asian-Australasian Journal of Animal Sciences
    • /
    • v.15 no.3
    • /
    • pp.340-345
    • /
    • 2002
  • In this experiment, oocytes were collected from goat ovaries available in slaughterhouse by follicle puncture method. Morphologically culturable type of oocytes which having compact, multilayered cumulus granulosa cell complex and evenly granulated cytoplasm, was separated under a stereozoom microscope. Oocytes were washed thoroughly in maturation medium containing TCM-199, $1{\mu}g/ml$ estradiol-$17{\beta}$, 0.5 ${\mu}g/ml$ FSH, $100{\mu}g/ml$ LH, 3 mg/ml BSA and 10% estrus goat serum. Washed oocytes were cultured into maturation medium on granulosa cell monolayer. Culture plate was then kept into $CO_2$ incubator at $38{\pm}1^{\circ}C$, maximum humidity and 5% $CO_2$ for 18 h. After maturation the oocytes were washed thoroughly with maturation medium containing polyvinyl alcohol (PVA) without serum and BSA and further cultured for 12 h for secretory proteins of oocytes. PVA medium was collected, pooled and concentrated by 5000 cut off centrisart. Secretory proteins were separated on 12.5% SDS-PAGE. A total number of 3.41 oocytes per ovary were obtained and 2.17 culturable oocytes per ovary were cultured into maturation medium. After 18 h of maturation, 4,567 oocytes (1.82 oocytes per ovary) were further cultured into serum and BSA free PVA medium for its secretory proteins. Four secretory proteins of oocytes with approximately molecular weight of 45, 55, 65 and 95 kDa were obtained on SDS-PAGE in silver staining and three proteins with approximately molecular weight of 45, 55 and 65 kDa in Coomassie brilliant blue staining. In conclusion, four secretory proteins with approximately molecular weight of 45, 55, 65 and 95 kDa was obtained from in vitro cultured oocytes of goats.

Relationship between Sleep and Mental Health in Middle School Female Students (여중생의 수면과 정신건강의 상호관련성)

  • Kim, Nam Jun;Kim, Sang-A;Park, Woong-Sub
    • Journal of agricultural medicine and community health
    • /
    • v.42 no.4
    • /
    • pp.244-253
    • /
    • 2017
  • Objectives: The purpose of this study was to examine the relationship between sleep and mental health in middle school female students. Methods: For this purpose, We analyzed the data of 15,477 for middle school female students among the 2016 Korea Youth Risk Behavior Web-based Survey by multiple logistic regression based on the complex sample design. Results: Sleep duration of middle school female students in Korea were significantly associated with perceived stress, depressive experience, and suicidal idea, and subjective sleep satisfaction were significantly associated with perceived stress, depressive experience in results of multiple logistic regression. Conclusion: Sleep duration and subjective sleep satisfaction have a significant impact on the mental health of middle school female students. Therefore, in-depth research and policies to mental health of middle school female students through sleep duration and subjective sleep satisfaction increase are required.

Relationship between Health Behavior and Subjective Unhappiness in High School Students (고등학생의 건강행태와 주관적 불행감의 상호관련성)

  • Park, Sunu;Kim, Sang-A;Park, Woong-Sub
    • Journal of agricultural medicine and community health
    • /
    • v.42 no.2
    • /
    • pp.87-96
    • /
    • 2017
  • Objectives: We studied the relationship between health behavior and subjective unhappiness in high school students. Methods: Using 27,097 responses from the 2015 Korea Youth Risk Behavior Web-based Survey for general high school students. we analyzed by multiple logistic regression based on the complex sample design Results: Unhappiness was positively related with the low economic status, smoking, drinking, fast foods intake, and negatively related with fruit intake in results of multiple logistic regression. Conclusion: Health behaviors have a significant impact on the unhappiness of high school students. Therefore, in-depth research and policies to decrease unhappiness of high school students through health promotion are required.

Effects of ZnO Composition on the Thermal Emission Properties for LTCC Type of High Power LED Package (고전력 LED용 적층형 LTCC 패키징의 ZnO 조성 변화가 방열 특성에 미치는 영향)

  • Kim, Woojeong;Kim, Hyung Soo;Shin, Daegyu;Lee, Hee Chul
    • Journal of the Microelectronics and Packaging Society
    • /
    • v.19 no.4
    • /
    • pp.79-83
    • /
    • 2012
  • LTCC (Low temperature co-fired ceramic) package have been paid much attention due its good reliability, miniaturization, and application of silver paste with complex wiring and printing. Therefore, LTCC package has been expected to replace vulnerable plastic package in the field of high power LED device. Currently, LTCC ceramic package is mainly made up of aluminum oxide powder. In this study, zinc oxide powder is added or replaced for the fabrication of LTCC ceramic body. By adding small amount of ZnO, thermal conductivity of the LTCC ceramic body could be remarkably increased by 25% leading to the extension of LED life time. The LTCC package structure with composition including ZnO has an increased thermal flux by 56% as a result of ANSYS simulation. Actually, the fabricated LED package with the addition of ZnO exhibits a decreased thermal resistivity by 14.9%.

Development of Usability Evaluation Criteria for Senior-Friendly Autonomous Transportation Robot

  • Kim, Seon Chil;Kim, Sun Jung;Choi, Kyongon
    • Journal of the Ergonomics Society of Korea
    • /
    • v.33 no.5
    • /
    • pp.407-422
    • /
    • 2014
  • Objective: The purpose of the study is to develop quantitative usability evaluation criteria for senior-friendly autonomous transportation robot. Background: The Republic of Korea has become the most rapidly aging society, and is anticipated to enter the post-aged society in 2026. To raise the quality of life of a senior with limited mobility and to reduce the burden of caregivers, many high-tech assistive products with information technologies are developed nowadays. The senior-friendly autonomous transportation robot is one person robot vehicle to move a senior to the destination for hospitals, nursing homes or silver town complex. With built-in navigation system and environmental monitoring censors, it automatically seeks the path to the destination and avoids collision to obstacles and pedestrians on the way. Due to the early stage of the product, few usability studies in this field have been done, mostly on general service robots to assist seniors, power wheelchairs and delivery robots. ISO and KS standards for the service robots are focused on safety. Method: Based on the reference usability index, the early draft of the usability evaluation questionnaires was developed. After small group tests and interviews, the experts modified the initial draft to the Usability Evaluation Criteria for Senior-Friendly Autonomous Transportation Robot (UEC-SFATR). Result: UEC-SFATR consisted of 4 subscales - Safety, Controllability, Efficiency and Satisfaction. All of the 4 subscales of UEC-SFATR were passed the reliability criteria by 4 groups of seniors, divided by gender and familiarity of smart-devices. Conclusion: UEC-SFATR covers wider area of user experiences of the SFATR and is a good measurement tool to help both the users and developers of the robot. Application: This study provides guide to the future product development and product competitiveness evaluation by quantifying user experiences for the SFATR.

Facilitated Transport Membrane for Ethylene/Ethane and Propylene/Propane Separation (SPEEK-Ag 촉진 수송 분리막을 이용한 $C_2,\;C_3$ 계 올레핀/파라핀 분리)

  • Kim, Ji-Yeon;Lee, Hyun-Joo;Kim, Hoon-Sik;Jung, Hyun-Wook;Choi, Dae-Ki
    • Clean Technology
    • /
    • v.13 no.1 s.36
    • /
    • pp.79-84
    • /
    • 2007
  • Separation of ethylene from ethane and propylene from propane have been conducted using facilitated olefin transport membrane with SPEEK-Ag (Ag substituted sulfonated poly(ether ether ketone)). SPEEK was prepared by the sulfonation of PEEK using cone. $H_2SO_4$ and the reaction time affected the degree of sulfonation (DS) of the resulting SPEEK. SPEEK-Ag composite membrane was formed by soaking SPEEK in the polyester support into the Ag salt solution. With increasing the concentration of SPEEK in MeOH, the thickness of SPEEK on the polyester increased. The selectivity and the flux of SPEEK-Ag membrane for the separation of ethylene/ethane and propylene/propane were changed by the thickness of SPEEK layer on the top of polyester support. The anion of silver salt also affects the membrane performance.

  • PDF

Development of modern women's Hanbok design by analyzing design elements (디자인 요소 분석을 통한 현대여자한복 디자인 개발)

  • Park, Eunju;Rhee, Youngju
    • The Research Journal of the Costume Culture
    • /
    • v.30 no.3
    • /
    • pp.348-365
    • /
    • 2022
  • The purpose of this study is to develop Korean clothing designs that can satisfy future consumer's needs based on the elements extracted through the content analysis method in a study on the design elements expressed in traditional outfits in the 2010s. To this end, data analyzing Hanbok in wedding magazines were used, and after extracting design elements, research methods for empirical design development were used. After subclassifying the major design elements, factors with a steady increase in frequency and appearance rate were identified. Through this, five elements capable of aesthetic sampling were extracted by complex expression methods and expressed in a total of seven combinations. The types extracted from the design elements are items, silhouette, top shape, skirt shape, skirt length, mixed items with increasing frequency. In the element of color, the adjacent color harmony, which showed the highest frequency of color, and the white-blue harmony, which showed an increase among them, were extracted. When using materials, top and skirt have similar usage rates of the same and different materials, so both contents were extracted, and many patterns were arranged in the top and the whole, but these three were extracted because there were increasing cases where there were no patterns. In the case of decoration, embroidery, pintuck, sakdong, applique, lace, ribbon on the top, silver foil and print on the skirt were extracted. Through this study, it was possible to propose a future Korean costume design model.