• Elastomers and Composites
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• 제18권1호
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• pp.21-29
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• 1983

• Elastomers and Composites
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• 제7권2호
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• pp.156-159
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• 1972

• Elastomers and Composites
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• 제6권2호
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• pp.21-24
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• 1971

• 한국소음진동공학회:학술대회논문집
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• 한국소음진동공학회 2007년도 춘계학술대회논문집
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• pp.1137-1141
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• 2007

This paper is concerned with the experimental research of magnetorheological elastomers (MREs). The modulus of the MR elastomers can be controlled by an applied magnet field, so that it can be effectively used for vibration suppression applications. The MR elastomer in this experiment is a mixture of KE-1300 silicone, carbonyl iron powder (300mesh) and a silicone hardener (CAT-1300). Three specimens were manufactured and tested by using the vibration testing instruments. The magnetic field was generated by the permanent magnets. The experimental results show that the natural frequencies of the test article with MR elastomer changes by the applied magnetic field. The performance of the MR elastomer can be increased by stronger magnetic fields. This is under investigation.

• Elastomers and Composites
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• 제51권4호
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• pp.269-274
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• 2016

Two different reactive silicone oligomers, hydroxylpropyl terminated PDMS (PDMS-L) and 1-(2,3-dihydroxy-propoxy)propyl terminated PDMS (PDMS-B), were synthesized through hydrosilylation reaction under Karstedt's catalyst. Using the reactive silicone oligomers, two different silicone-modified gel-coat series were prepared to investigate their thermal and mechanical properties as well as surface characteristics according to reactive silicone oligomer contents. In case of thermal stabilities and mechanical properties, the gel-coat series containing PDMS-B showed higher values than that of the gel-coat series containing the PDMS-L. The contact angle for the gel-coat containing both silicone oligomers/was increased with reactive silicone oligomer contents but there was similar surface tension between PDMS-L and PDMS-B.

• Elastomers and Composites
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• 제50권3호
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• pp.210-216
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• 2015

Polyurethane modified silicone (PUMS) was synthesized from various molecular weights of polydimethylsiloxane (PDMS 2000, PDMS 6000, PDMS 20000), polypropyleneglycol with molecular weight of 3000 g/mol (PPG 3000) and 2,4-toluenediisocyanate (TDI) under tin catalyst. Their structures were confirmed by the measurement of FT-IR and $^1H-NMR$, and the thermal properties were studied from DSC and TGA. Glass transition temperature of PUMS exhibited exothermic peak at $-63{\sim}-69^{\circ}C$, and residual weight was 19~35% at $800^{\circ}C$.

• Elastomers and Composites
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• 제44권3호
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• pp.260-268
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• 2009

Clay의 표면을 bis[(3-triethoxysilylpropyl)tetra sulfide (TSS)으로 처리하면 clay 표면의 소수성이 증가 될 뿐만 아니라 high temperature vulcanization 형 silicone rubber(HTV)와 화학적 반응이 가능하기 때문에 clay와 silicone rubber 사이의 상용성이 향상될 수 있을 것으로 예상되어 TSS를 이용하여 Na-MMT와 Fe-MMT의 silicate 층 표면에 tetra sulfide 그룹을 도입시킨 Na-$MMTS_4$와 Fe-$MMTS_4$를 각각 제작하였다. 이들 clay를 HTV silicone rubber와 compounding하여 silicone rubber/clay composites를 제작하였으며, clay의 종류 및 표면개질에 따른 silicone rubber 복합체의 열적안정성 및 기계적 물성을 평가하였다.

• Elastomers and Composites
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• 제31권2호
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• pp.111-121
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• 1996

The characteristic of silicone rubber can be seen from its resistance to both low and high temperature, whereas HNBR is resistant only in high temperature moderatly although it can be compounded to give good tensile properties, good oil resistance while silicone rubber severely lacks in these qualities. This study was initiated a balance of properties by blending HNBR and silicone rubber which is not considered for commercial blending; blends of HNBR with silicone rubber tend to show immiscible due to dissimilar nature of silicone and HNBR, the possibility of phase separation cannot be ruled out, in unfilled system after vulcanisation leading to premature failure. Attempt has been made to improve compatibility and minimise the layer seperation by the use of compatibilizer. Both filled and unfilled systems, in presence and absence of compatibilizer have been studied. Improvement in tensile properties of the blends or are observed as compared to the non-blended rubber. Different ratios of HNBR and silicone rubber are represented in this study. Blends of HNBR with silicone rubber were immiscible system. The tensile strength increased with filler loading.

• Elastomers and Composites
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• 제54권2호
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• pp.142-148
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• 2019

In this study, the effects of filler particle size and shape on the physical properties of silicone rubber composites were investigated using inorganic fillers (Minusil 5, Celite 219, and Nyad 400) except silica, which was already present as a reinforcing filler of silicone rubber. Fillers with small particle sizes are known to facilitate the formation of the bound rubber by increasing the contact area with the polymer. However, in this experiment, the bound rubber content of Celite 219-added silicone composite was higher than that of Minusil 5-added silicone composite. This was attributed to the porous structure of Celite 219, which led to an increase in the internal surface area of the filler. When the inorganic fillers were added, both thermal decomposition temperature and thermal stability were improved. The bound rubber formed between the silicone rubber and inorganic filler affected the degree of crosslinking of the silicone composite. It is well-known that as the size of the reinforcing filler decreases, the reinforcing effect increases. However, in this experiment, the hardness of the composite material filled with Celite 219 was the highest compared to the other three composites. Furthermore, the highest value of 2.19 MPa was observed for 100% modulus, and the fracture elongation was the lowest at 469%. This was a result of excellent interaction between Celite 219 filler and silicone rubber.

• Elastomers and Composites
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• 제45권2호
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• pp.106-111
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• 2010

천연고무와 실리콘고무에 자기장응답형 분말을(Magnetic Responsible Powder; MRP) 배합하여 자기장응답형 엘라스토머(Magneto-rheological Elastomer; MRE)를 제조하였다. MRP의 최적 사용량은 30 vol.% 였으며 천연고무 기반 MRE의 기계적 물성은 실리콘고무 기반 MRE 보다 우수했지만, magneto-rheological (MR) 효과는 실리콘고무 기반 MRE가 더욱 우수하였다. MR 효과는 Self-modified Electromagnet Applied Fast Fourier Transform Analyser (SEFFTA)를 사용하여 측정되었는데 천연고무 기반 MRE의 경우는 10%, 실리콘고무 기반 MRE의 경우는 최대 35.7%까지 나타내었다. 네오디뮴 자석을 이용하여 MRE를 경화시키기 전 MRP를 선 배향 시킬 경우 더욱 우수한 MR 효과를 얻을 수 있었으며, MRP의 배향은 주사전자현미경을 이용하여 분석하였다.