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Physical Properties of Silicone Rubber/Clay Composites According to the Clay Type and Modification  

Yoon, Jin-San (Department of Polymer Science and Engineering, Inha University)
Kim, Eung-Soo (Department of Polymer Science and Engineering, Inha University)
Kim, Eun-Jeong (Department of Polymer Science and Engineering, Inha University)
Lee, Tae-Hwa (Department of Polymer Science and Engineering, Inha University)
Publication Information
Elastomers and Composites / v.44, no.3, 2009 , pp. 260-268 More about this Journal
Abstract
Modification of clay surface was attempted by treating the clay with bis[(3-triethoxysilylpropyl)tetra sulfide (TSS) to raise the hydrophobicity and to induce a chemical reaction between the clay and the high temperature vulcanization-type silicone rubber matrix with purpose of improving the compatibility between the components, and thereby Na-$MMTS_4$ and Fe-$MMTS_4$ were synthesized by treating Na-MMT and Fe-MMT with TSS, respectively. Silicone rubber/clay composites were prepared by compounding the clays with silicone rubber. Thermal stability and mechanical properties were evaluated as a function of the clay types and the surface modification.
Keywords
silicone rubber; clay; silicone rubber/clay composites;
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1 S.D. Burnside and E.P. Giannelis, 'Synthesis and properties of new poly(dimethylsiloxane) nanocomposites', Chem. Mater., 7, 1597 (1995)   DOI
2 P.B. Messersmith and E.P. Giannelis, 'Synthesis and barrier properties of poly(-caprolactone)-layered silicate nanocomposites', J. Polym. Sci. Part A: Polym. Chem., 33, 1047 (1995)   DOI   ScienceOn
3 R. A. Vaia, H. Ishii, and E. P. Giannelis, 'Synthesis and properties of two-dimensional nanostructures by direct intercalation of polymer melts in layered silicates' Chem. Mater., 5, 1694 (1993)   DOI   ScienceOn
4 M. L. Q. A. Kaneko and I. V. P. Yoshida, 'Effect of natural and organically modified montmorillonite clays on the properties of polydimethylsiloxane rubber', J. Appl. Polym. Sci., 108, 2587 (2008)   DOI   ScienceOn
5 J. Wang, Y. Chen, and Q. Jin, 'Organic montmorillonite as a substitute for aerosilica in addition-type liquid silicone rubber systems', Macromol. Chem. Phys., 206, 2512 (2005)   DOI   ScienceOn
6 J. Brandrup and E. H. Immergut, eds., Polymer Handbook, 3rd ed., Wiley, New York, sec. VII, 176, (1989)
7 T. J. Pinnavaia, G. W. Beall, Polymer-clay nanocomposites, Wiley: NY, US, (2000)
8 T. Y. Tsai, S. T. Lu, C. J. Huang, and J. X. Liu, 'The structure-property relationship of novolac cured epoxy resin/clay nanocomposites', J. Polym. Eng. Sci., 48, 467 (2008)   DOI   ScienceOn
9 A. Usuki, A. Tukigase, and M. Kato, 'Preparation and properties of EPDM–clay hybrids', Polymer, 43, 2185 (2002)   DOI   ScienceOn
10 M. Pramanik, S. K. Srivastava, B. K. Samantaray, and A. K. Bhowmick, 'Rubber-clay nanocomposite by solution blending', J. Appl. Polym. Sci., 87, 2216 (2003)   DOI   ScienceOn
11 G. X. Chen, J. B. Choi, and J. S. Yoon, 'The role of functional group on the exfoliation of clay in poly(L-lactide)', Macromol. Rapid. Commun., 26, 183 (2005)   DOI   ScienceOn
12 E. P. Giannelis, 'Polymer layered silicate nanocomposites', Adv. Mater., 8, 29 (1996)   DOI
13 A. Usuki, Y. Kojima, M. Kawasumi, A. Okada, Y. Fukushima, T. Kurauchi, and O. Kamigaito, 'Synthesis of nylon 6-clay hybrid' J. Mater. Res., 8, 1179 (1993)   DOI   ScienceOn
14 M. Kato, A. Tsukigase, H. Tanaka, A. Usuki, and I. Inai, 'Preparation and properties of isobutylene-isoprene rubber-clay nanocomposites', J. Polym. Sci. Part A: Polym. Chem., 44, 1182 (2006)   DOI   ScienceOn
15 G. L. Wikes and J. Wen, 'Organic/inorganic hybrid network materials by the sol−gel approach', Chem. Mater., 8, 1667 (1996)   DOI   ScienceOn
16 P.B. Messersmith and E.P. Giannelis, 'Synthesis and characterization of layered silicate-epoxy nanocomposites', Chem. Mater., 6, 1719 (1994)   DOI   ScienceOn
17 D. V. Kuznetsov and A. C. Balazs, 'Phase behavior of end-functionalized polymers confined between two surfaces', J. Chem. Phys., 113, 2479 (2000)   DOI   ScienceOn
18 A. C. Balazs, C. Singh, and E. Zhulina, 'Modeling the interactions between polymers and clay surfaces through self-consistent field theory', Macromolecules, 31, 8370 (1998)   DOI   ScienceOn
19 K. Yano, A. Usuki, T. Kurauchi, and O. Kamigaito, 'Synthesis and properties of polyimide-clay hybrid', J. Polym. Sci. Part A: Polym. Chem., 31, 2493 (1993)   DOI   ScienceOn
20 M. Okamoto, 'Recent advances in polymer/layered silicate nanocomposites: an overview from science to technology', Mater. Sci. Tech. Lond., 22, 756 (2006)   DOI   ScienceOn
21 E. S. Kim, E. J. Kim, J. H. Shim, and J. S. Yoon, 'Thermal stability and ablation properties of silicone rubber composites', J. Appl. Polym. Sci., 110, 1263 (2008)   DOI   ScienceOn
22 L. Bokobza, 'Elastomeric composites. I. silicone composites', J. Appl. Polym. Sci., 93, 2095 (2004)   DOI   ScienceOn
23 B. K. G. Theng, Chemistry of Clay-Organic Reactions, Wiley, NY, US, (1974)
24 Y. Zhang, Y. Hu, L. Song, J. Wu, and S. Fang, 'Influence of Fe-MMT on the fire retarding behavior and mechanical property of (ethylene-vinyl acetate copolymer/magnesium hydroxide) composite', Polym. Adv. Technol., 19, 960 (2008)   DOI   ScienceOn
25 S. S. Ray and M. Okamoto, 'Polymer/layered silicate nanocomposites: a review from preparation to processing', Prog. Polym. Sci., 28, 1539 (2003)   DOI   ScienceOn
26 S. Joly, G. Garnaud, R. Ollitrault, L. Bokobza, and J. E. Mark, 'Organically modified layered silicates as reinforcing fillers for natural rubber', Chem. Mater., 14, 4202 (2002)   DOI   ScienceOn
27 N. N. Herrera, J. M. Letoffe, J.L. Putaux, L. David, and E. B. Lami, 'Aqueous dispersions of silane-functionalized laponite clay platelets. a first step toward the elaboration of water-based polymer/clay nanocomposites', langmuir, 20, 1564 (2004)   DOI   ScienceOn
28 Y. Wang, L. Zhang, C. Tang, and D. Yu, 'Preparation and characterization of rubber-clay nanocomposites', J. Appl. Polym. Sci., 78, 1879 (2000)   DOI   ScienceOn
29 S. Ray and A. K Bhowmick, 'Synthesis, characterization and properties of montmorillonite clay-polyacrylate hybrid material and its effect on the properties of engage-clay hybrid composite', Rubber. Chem. Technol., 74, 835 (2001)   DOI   ScienceOn
30 L. Song and Y. Hu, 'Study on the solvothermal preparation of polyethylene/organophilic montmorillonite nanocomposites', J. Mater. Chem., 12, 3152 (2002)   DOI   ScienceOn