Browse > Article
http://dx.doi.org/10.7473/EC.2015.50.3.210

Synthesis and Characteristic of Polyurethane Modified Silicone  

Lee, Kangseok (R&D Center, NEO CHEMS Co. Ltd.)
Shim, Sang Eun (Department of Chemistry & Chemical Engineering, Inha University)
Publication Information
Elastomers and Composites / v.50, no.3, 2015 , pp. 210-216 More about this Journal
Abstract
Polyurethane modified silicone (PUMS) was synthesized from various molecular weights of polydimethylsiloxane (PDMS 2000, PDMS 6000, PDMS 20000), polypropyleneglycol with molecular weight of 3000 g/mol (PPG 3000) and 2,4-toluenediisocyanate (TDI) under tin catalyst. Their structures were confirmed by the measurement of FT-IR and $^1H-NMR$, and the thermal properties were studied from DSC and TGA. Glass transition temperature of PUMS exhibited exothermic peak at $-63{\sim}-69^{\circ}C$, and residual weight was 19~35% at $800^{\circ}C$.
Keywords
polyurethane modified silicone (PUMS); polydimethylsiloxane (PDMS); polypropyleneglycol (PPG); 2,4-toluenediisocyanate (TDI);
Citations & Related Records
연도 인용수 순위
  • Reference
1 K. E. Polmanteer, "Current Perspectives on Silicone Rubber Technology", Rubber Chem. Technol., 54, 1051 (1981).   DOI
2 K. E. Polmanteer, "Silicone Rubber, Its Development and Technological Progress", Rubber Chem. Technol., 61, 470 (1988).   DOI
3 Hans R. Kricheldorf, Silicone in Polymer Synthesis. Springer, Berlin and Heidelberg (1996).
4 K. E. Polmanteer, Handbook of Elastomers: New Developments and Technology, A. K. Bhowmick, and H. L. Stephens, Eds., Marcel Dekker, New York, U.S.A., p. 551 (1988).
5 I. Skeist, Handbook of Adhesives, 3rd Ed, Van Nostrand Reinhold, New York, p. 522, (1989).
6 T. Gunji, Y. Iizuka, K. Arimitsu, and Y. Abe, "Preparation and Properties of Alkoxy(methyl)silsesquioxanes as Coating Agents", J. Polym. Sci. Polym. Chem., 42, 3676 (2004).   DOI
7 S. T. Lin and S. K. Huang, "Synthesis and Impact Properties of Siloxane-DGEBA Epoxy Copolymers", J. Polym. Sci. Polym. Chem., 34, 1907 (1996).
8 Stephan Pawlenko, Organosilicon Chemistry, Walter de Gruyter, Berlin (1986).
9 R. R. Mcgregor, Silicones and Their Uses. McGraw-Hill, New York (1954).
10 Y. Leterrier, J. Andersons, Y. Pitton, and J. A. E. Manson, "Adhesion of Silicone Oxide Layers on Poly(ethylene terephthalate). II: Effect of Coating Thickness on Adhesive and Cohesive Strengths", J. Polym. Sci. Polym. Phys., 35, 1463 (1997).   DOI
11 Y. Qi, X. Meng, J. Yang, Z. Zeng, and Y. Chen, "Synthesis and Properties of Ultraviolet/Moisture Dual-Curable Polysiloxane Acrylates", J. Appl. Polym. Sci., 96, 846 (2005).   DOI
12 General Electric Company, Polysiloxaneimides and their production, U. S. Patent 3,325,450 (1967).
13 A. Noshay and J. E. McGrath, Block Copolymer, Academic Press, New York (1977).
14 V. H. Kuckertz, "Siloxanmodifizierte polypyromellitimide", Makromol. Chem., 98, 101 (1966).   DOI
15 S. Maudgal and S. Clair, "Preparation and characterization of siloxane-containing thermoplastic polymides", J. Adhesion and Adhesives, 4, 87 (1984).   DOI
16 M. Itoh, K. Iwata, J. Ishikawa, and Y. Takenaka, "A heatresistant silicon-based polymer", Adv. Mater., 9, 1187 (1997).   DOI
17 I. Yilgor, J. E. McGrath, J. S. Riffle, and L. L. Wickes, "Siloxane-Urea Segmented Copolymers: I. Synthesis and Characterization of Model Polymers from MDI and ${\alpha},{\omega}$-bis(aminopropyl) poly(dimethyl-siloxane)", Polym. Bull., 8, 535 (1982).
18 G. KoBmehl, W. Neumaun, and H. Schafer, "Polymeric and Oligomeric Dimethylsiloxanes with Alcoholic Groups and Their Conversions into Polymers with Dimethylsiloxane and Urethane Moieties", Makromol. Chem., 187, 1381 (1986).   DOI
19 J. P. Pascault and Y. Camberein, "Quantitative Determination of the Phase Segregation Degree in a Poly(dimethyl siloxane)-based Urethane", Polym. Commun., 27, 230 (1986).
20 J. C. Caprino and R. F. Macander, Rubber Technology, 3rd Ed., M. Morton, Editor, Van Nostrand Reinhold, New York, Ch. 13 (1987).
21 E. L. Warrick, "Silicone Rubber-a perspective", Rubber Chem. Technol., 49, 909 (1976).   DOI
22 F. M. Lewis, "The Science and Technology of Silicone Rubber", Rubber Chem. Technol., 35, 1222 (1962).   DOI
23 W. Noll, Chemistry and Technology of Silicones, 2nd Ed., Academic Press, New York, p. 305 (1968).