• Proceedings of the Korean Society of Rheology Conference
• /
• 2000.11a
• /
• pp.78-81
• /
• 2000

• KSBB Journal
• /
• v.21 no.5
• /
• pp.360-365
• /
• 2006

The objectives of this study were to develop nano-pore silica particles and to modify its surface for use as an enzyme immobilization matrix. Sol-gel reaction was used to produce silica particles of various nano pore sizes with hydroxyl groups on their surfaces. The surface was modified with aldehyde that was confirmed by fluorescence imaging. Trypsin was covalently immobilized by reductive amination. Surface density of the immobilized trypsin was ca. $350{\mu}g/m^2$, which was approximately 17- and 35-fold higher than those from the surfaces with hydroxyl and amine group, respectively. About 90% of the initial enzyme activity was maintained after the 12th use of repeated use. When compared with the commercial matrices, the nano-pore silica particle was superior in terms of immobilization yield and specific activity. This study suggests the nano porous silica particles can be used as enzyme immobilization matrix for industrial applications.

• Korean Chemical Engineering Research
• /
• v.46 no.5
• /
• pp.880-885
• /
• 2008

Spray pyrolysis was applied to prepare spherical silica particles with mesopores of a regular structure. The physical properties such as surface area, pore size, pore structure, particle size, and morphology were studied by BET, SEM, SAXS, and DLS analysis. At a fixed gas flow rate, the BET surface area changed from 200 to $1,290m^2/g$ as changing the CTAB/TEOS molar ratio from 0.05 to 0.3. At a fixed CTAB/TEOS ratio, the surface area of silica particles was varied from 1,062 to $1,305m^2/g$ with changing the gas flow rate from 10 to 40 l/min. The average pore size measured by BJH desorption was about $21{\sim}23{\AA}$ and not significantly influenced by the CTAB/TEOS ratio and the gas flow rate. Finally, the highest surface area which was $1,305m^2/g$ were obtained when the CTAB/TEOS ratio and the gas flow rate were 0.2 and 20 l/min, respectively. According to SAXS analysis, the prepared silica particles showed a strong peak at $2{\theta}=2.6^{\circ}$ and two minor peaks around $2{\theta}=4.4^{\circ}$ and $5.1^{\circ}$, which are due to regular mesopores of hexagonal structure. The morphology of silica particles prepared were spherical shape and the average particle size was $1.0{\mu}m$.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.21 no.4
• /
• pp.20-25
• /
• 2020

As nanoscience and nanotechnology advance, techniques for selective pattern growth have attracted significant attention. Silica nanoparticles (NPs) are used as a promising nanomaterials for bio-labeling, bio-imaging, and bio-sensing. In this study, silica NPs were synthesized by a sol-gel process using a modified Stöber method. In addition, the selective pattern growth of silica NPs was achieved by the surface functionalization of the substrate using a micro-contact printing technique of a hydrophobic treatment. The particle size of the as-synthesized silica NPs and morphology of selective pattern growth of silica NPs were characterized by FE-SEM. The contact angle by surface functionalization of the substrate was investigated using a contact angle analyzer. As a result, silica NPs were not observed on the hydrophobic surface of the OTS solution treatment, which was coated by spin coating. In contrast, the silica NPs were well coated on the hydrophilic surface after the KOH solution treatment. FE-SEM confirmed the selective pattern growth of silica NPs on a hydrophilic surface, which was functionalized using the micro-contact printing technique. If the characteristics of the selective pattern growth of silica NPs can be applied to dye-doped silica NPs, they will find applications in the bio imaging, and bio sensing fields.

• Journal of the Society of Cosmetic Scientists of Korea
• /
• v.30 no.2
• /
• pp.189-195
• /
• 2004

Carbon black have not been used as pigment material in cosmetic because of very low density and dispersity, but carbon black have applicable character as black pigment because of non-toxic, stable physico-chemical property, and black colority. In this study, mesoporous silica samples were synthesized by sol-gel reaction using surfactants-template method; TEOS (tetraethoxysilane) - a) PEO/lecithin, b) PEO/polyethylene glycol, c) lecithin/polyethylene glycol in ethanol/water solution. Synthesized organic-inorganic hybrid - silica were heat-treated in N2 condition at 500$^{\circ}C$. Mesoporous silica with black carbon in pore have the effective density and show the good dispersity in both hydrophilic and hydrophobic solvent. Properties of the samples were measured; specific surface area (750㎡/g) and pore size (4-6nm) using BET, pore structure (cylindrical type) using XRD, morphology (spherical powder with 0.1-0.5$\mu\textrm{m}$ partical size) of the samples using SEM. Carbon-silica black color applied to mascara, it shows a dark black colority and good dispersity as compared with the general black color titania pigment. Moreover, it is possible to control the density of black color pigment because it is possible to control pore volume and particle size of mesoporous silica properly. It show the good volume effects in mascara. That is why possible to apply all kinds of cosmetic products.

• Journal of the Korean Geotechnical Society
• /
• v.15 no.5
• /
• pp.205-215
• /
• 1999

Crushable sandy soil grounds are widely found along the coast throughout the world. The ground composed of lime sand, which is characterized by the material with high compressibility due to particle crushing contains carbonate calcium. In this study, in order to clarify the characteristics of the particle crushing as related to the strength and deformation properties of sands, isotropic compression test was carried out on three different types of carbonate sands and a silica sand. A crushability index, K, is proposed in connection with the yielding and particle crushing stress of sands at various relative densities under isotropic compression. It is concluded that the representative crushability index, K, associated with the soil particle strength, can be a key factor in preliminary parameters in evaluating soil crushability.

• Journal of Adhesion and Interface
• /
• v.21 no.4
• /
• pp.143-155
• /
• 2020

Hydrophobic Organic-Inorganic (O-I) hybrid materials prepared by sol-gel process have been widely used at functional coating fields such as coatings for anti-corrosion, anti-icing, self-cleaning, anti-reflection. The key point for fabricating hydrophobic surface is to optimize the surface energy and roughness of the coating films. There are typical processes to control the surface energy and roughness which are 'In situ fabricating', 'Pre-fluorinating/Post-roughening', 'Pre-roughening/ Post-fluorinating'. In this study, particle-binder process was used for in-situ fabrication of hydrophobic coating films. Various O-I hybrid compounds prepared using several kinds of alkoxysilane compounds were used as a binder for silica nanoparticles at particle-binder process. To study effect of fluorine content and weight ratio of particle : binder on the hydrophobicity and surface morphology, Hydrophobic coating films were prepared onto glass substrate at various content of fluorine content of O-I hybrid binder and weight ratio of particle : binder. The coating films prepared using O-I hybrid binder (GPTi-HF10) having 10 wt% of fluorine content showed the highes water contact angle (107.52±1.6°). The coating films prepared at 1:3 weight ratio of GPTi-HF10 : silica nanoparticle exhibited the highest water contact angle (130.84±1.99°).

• Journal of the Korea institute for structural maintenance and inspection
• /
• v.24 no.5
• /
• pp.95-102
• /
• 2020

For the purpose of developing a PE fiber-reinforced highly ductile cementitious composite having high tensile strain capacity more than 2% under the condition of containing aggregates with large particle size, this study investigated the tensile behavior of composites according to the particle size and distribution of aggregates in the composite. Compared with the mixture containing silica sand of which particle size is less than 0.6 mm, mixtures containing river sand and/or gravel with the maximum particle size of 2.36 mm, 4.75 mm, 5.6 mm, 6.7 mm were considered in the experimental design. The particle size distributions of aggregates were adjusted for the optimized distribution curves obtained from modified A&A model by blending different sizes of aggregates. All the mixtures presented clear strain-hardening behavior in the direct tensile tests. The mixtures with the blended aggregates to meet the optimum curves of aggregate size distributions showed higher tensile strain capacity than the mixture with silica sand. It was also found that the tensile strain capacity was improved as the maximum size of aggregate increased which resulted in wider particle size distribution. The mixtures with the maximum size of 5.6 mm and 6.7 mm presented very high tensile strain capacities of 4.83% and 5.89%, respectively. This study demonstrated that it was possible to use coarse aggregates in manufacturing highly ductile fiber-reinforced cementitous composite by adjusting the particle size distribution.

• Korean Journal of Soil Science and Fertilizer
• /
• v.18 no.1
• /
• pp.67-71
• /
• 1985

The objective of this study was to attest the feasibility of the utilization of the blast furnace slag, quenched with water as a source of silicate fertilizer. A pot experiment was conducted to evaluate the effect of quenched slag and its particle size distribution on rice plant growth over the corresponding air-cooled slag of milled commercial silicate fertilizer. The yields of rice were slightly higher in quenched slag than in the commericial air-cooled slag, however, no significant statistical difference was observed. The silica content of rice plants through the growing period was high in quenched slag in any tested particle sizes. This indicated that the quenched slag might release silica fastly in soil. On the other hand, the available silica content retained in soil was high in air cooled slag, which implied that the silica of air-cooled slag was low acting. The results suggested that the quenched slag may be potentially utilized as a source of silicate fertilizer.

• Membrane Journal
• /
• v.25 no.1
• /
• pp.15-26
• /
• 2015

In this study, porous metal (O.D. = 10 mm, length = 10 mm, 316 L SUS, Mott Corp.) and ${\alpha}$-alumina tube (O.D. = 10 mm, length = 50 mm, Pall, German) support was modified with suspension sols, which were consisted of $3{\sim}4{\mu}m$ and 150 nm size of ${\alpha}$-alumina particle in the water or silica-zirconia colloidal sol. The porous support was fabricated by dip coating method for 5 seconds with suspension of alumina particles. After drying at $100^{\circ}C$ for 1 h, it was calcined at $550^{\circ}C$ for 30 min. It was repeated several times in order to decrease big pore on support. The surface roughness and largest pore size on the porous support was decreased by increasing coating times with $3{\sim}4{\mu}m$ size of ${\alpha}$-alumina particle and alumina coating with 150 nm size of ${\alpha}$-alumina particle served as further smoothening the surface and decreasing the pore size of the substrate. And the silica-zirconia membranes were successfully prepared on the modified porous metal and ${\alpha}$-alumina supports, and showed hydrogen permeance in the range of $1.8-8.4{\times}10^{-4}mol{\cdot}m^{-2}{\cdot}s^{-1}{\cdot}Pa^{-1}$ and $3.3-5.0{\times}10^{-5}mol{\cdot}m^{-2}{\cdot}s^{-1}{\cdot}Pa^{-1}$, respectively.