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Synthesis of New Black Pigment; Carbon Black Pigment Capsulated into the Meso-pore of Silica as Black Pigment in Cosmetic  

Hye-in, Jang (Department of Make Up of Skin Science Institute, Enprani Co. Ltd.,)
Kyung-chul, Lee (Sungkyunkwan University)
Hee-chang , Ryoo (Department of Make Up of Skin Science Institute, Enprani Co. Ltd.,)
Publication Information
Journal of the Society of Cosmetic Scientists of Korea / v.30, no.2, 2004 , pp. 189-195 More about this Journal
Abstract
Carbon black have not been used as pigment material in cosmetic because of very low density and dispersity, but carbon black have applicable character as black pigment because of non-toxic, stable physico-chemical property, and black colority. In this study, mesoporous silica samples were synthesized by sol-gel reaction using surfactants-template method; TEOS (tetraethoxysilane) - a) PEO/lecithin, b) PEO/polyethylene glycol, c) lecithin/polyethylene glycol in ethanol/water solution. Synthesized organic-inorganic hybrid - silica were heat-treated in N2 condition at 500$^{\circ}C$. Mesoporous silica with black carbon in pore have the effective density and show the good dispersity in both hydrophilic and hydrophobic solvent. Properties of the samples were measured; specific surface area (750㎡/g) and pore size (4-6nm) using BET, pore structure (cylindrical type) using XRD, morphology (spherical powder with 0.1-0.5$\mu\textrm{m}$ partical size) of the samples using SEM. Carbon-silica black color applied to mascara, it shows a dark black colority and good dispersity as compared with the general black color titania pigment. Moreover, it is possible to control the density of black color pigment because it is possible to control pore volume and particle size of mesoporous silica properly. It show the good volume effects in mascara. That is why possible to apply all kinds of cosmetic products.
Keywords
new matrials; organic/inorganic hybrid silica; carbon-silica pigment; mesoporous silica; SEM;
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