• Elastomers and Composites
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• v.51 no.2
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• pp.81-92
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• 2016

1,3-Diphenylguanidine (DPG) is commonly used as a secondary accelerator which not only acts as booster of cure but also activating silanization reaction. The aim of this study is to increase the interaction between silica and rubber by using DPG. In this study, mixing was proceeded in two steps. The T-1 compound is mixed DPG with silica and silane coupling agent in the kneader at high temperature which is named as $1^{st}$ mixing step. T-3 compound is mixed DPG with curatives in the two-roll mill at low temperature which is named as $2^{nd}$ mixing step. The T-2 compound is mixed a half of DPG in $1^{st}$ mixing step and the remainder is mixed in $2^{nd}$ mixing step. Total DPG content was equal for all compounds. When DPG is mixed with silica, silane coupling agent during the $1^{st}$ mixing step, a decrease in cure rate and an increase in scorch time can be seen. This indicates that DPG is adsorbed on the surface of silica. during rubber processing. However, bound rubber content is increased and dynamic properties are improved. These results are due to the highly accelerated silanization reaction. However, there are no significant difference in 100%, 300% modulus.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.04a
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• pp.765-768
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• 2008

Silica fume is a very important gradient in UHPC(Ultra High Performance Concrete) and its amount is normally over 25% of cement(wt.%). But we surely need to comprehend the influence of the amount of silica fume on the UHPC. In this paper, it was investigated how the amount of silica fume influence on the properties such as fluidity, compressive strength, elastic modulus, and flexural strength. Furthermore, it was examined the internal micro structure on UHPC through the test of SEM and MIP. In results, If we properly use silica fume in UHPC, fluidity and strength of UHPC was increased. It can be ascertained through the test of MIP that silica fume effectively increased density of UHPC by posolanic reaction and acting as filler. Especially, In case of Cement to silica fume ratio$0.1{\sim}0.25%$, we can be concluded that UHPC has similar to mechanical property.

• Elastomers and Composites
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• v.37 no.1
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• pp.14-20
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• 2002

Silica-filled rubber compound needs longer mixing time compared to carbon black-filled one since it has poor dispersion or the filler. Influence of the mixing procedure on the properties of natural rubber compound filled with both silica and carbon black was studied. The discharge temperature of the master batch (MB) mixing was $150^{\circ}C$. The mixing time was longer when silica and carbon black were loaded separately than when loaded simultaneously. The mixing time was longer when silica was loaded first than when carbon black is loaded first. The compounds prepared by one MB step (conventional mixing) were compared with the compounds prepared by two MB steps (two-step mixing). Scorch times of the two-step mixing compounds were longer than those by the conventional mixing ones. Bound rubber contents of the formers were lower than those of the tatters. The two-step mixing vulcanizates had longer elongation at break, higher tensile strength, and better fatigue life.

• Elastomers and Composites
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• v.40 no.1
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• pp.22-28
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• 2005

In this work, the effect of oxygen plasma treatment of nano-scaled silica on the mechanical interfacial properties and thermal stabilities of the silica/rubber composites was investigated. The surface properties of the silica were studied in X-ray photoelectron spectroscopy (XPS) and contact angles. And, their mechanical interfacial properties and thermal stabilities of the composites were characterized by tearing energy ($G_{IIIC}$) and thermogravimetric analysis (TGA), respectively. As a result, it was found that the introduction rate of oxygen-containing polar functional groups onto the silica surfaces was increased by increasing the plasma treatment time, resulting in improving the tearing energy. Also, the thermal stabilities of the composites were increased by increasing the treatment time. These results could be explained that the polar rubber, such as acrylonitrile butadiene rubber (NBR), showed relatively a high degree of interaction with oxygen-containing functional groups of the silica surfaces in a compounding system.

• Journal of the Korean Ceramic Society
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• v.31 no.12
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• pp.1507-1512
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• 1994

High strength cement hardened body was prepared by ordinary portland cement, silica-fume, super-plasticizer and the industrial by-product powder such as tailing, paper sludge ash and granulated slag. These raw materials were mixed and formed with w/c=0.18. The cement hardened body is cured in the autoclave at 18$0^{\circ}C$, 10atm. These admixtures made the compressive strength of all specimens develope by 170~230%. The highest compressive strength could be obtained by 236 MPa when mix composition was 14 wt% of silica-fume and 26 wt% of granulated slag. The compressive strength increased with decreasing the average pore size and the amount of the poe over the size of 50 nm by which the appearance of high compressive strength of the cement hardened body were mainly influenced. In the result, the hydration products were C-S-H, tobermorite and ettringite and it was realized that the reason why the cement hardened body became dense and revealed the higher strength was that those hydrates were formed inside of the pore and filled in it and the unhydrated materials played the role of an inner-filler.

• Journal of Powder Materials
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• v.26 no.3
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• pp.195-200
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• 2019

Whisker-type magnesium hydroxide sulfate hydrate ($5Mg(OH)_2{\cdot}MgSO_4{\cdot}3H_2O$, abbreviated 513 MHSH), is used in filler and flame-retardant composites based on its hydrate phase and its ability to undergo endothermic dehydration in fire conditions, respectively. In general, the length of whiskers is determined according to various synthetic conditions in a hydrothermal reaction with high temperature (${\sim}180^{\circ}C$). In this work, high-quality 513 MHSH whiskers are synthesized by controlling the concentration of the raw material in ambient conditions without high pressure. Particularly, the concentration of the starting material is closely related to the length, width, and purity of MHSH. In addition, a ceramic-coating system is adopted to enhance the mechanical properties and thermal stability of the MHSH whiskers. The physical properties of the silica-coated MHSH are characterized by an abrasion test, thermogravimetric analysis, and transmission electron microscopy.

• Journal of the Semiconductor & Display Technology
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• v.12 no.4
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• pp.55-59
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• 2013

Mold die sticking arises from silica filler abrasion to the cavity surface. Ni-P electroplating was examined to substitute conventional hard Cr plating. More than 4% of Phosphorus in the electroplated film produces nano crystal structure and annealing makes $Ni_3P$ precipitated to get hardness values equivalent to hard Cr.

• Proceedings of the Korean Institute of Industrial Safety Conference
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• 2002.05a
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• pp.65-70
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• 2002

난연$\cdot$다기능성 복합성형체는 기계부품, 구조물, 차량, 선박, 항공기 및 산업 분야에 널리 사용되고 있다. 안전성이 확보된 신소재 개발의 일환으로서 본 연구진은 난연특성, 정전기 방지특성, 내식특성의 기능성 복합성형체 개발을 수행해 왔으며, 본 연구에서는 Recycled PE, Phenolic resin 및 PPS resin과 같은 재활용 제품에 고기능성을 부여하기 위하여 용도에 따라 alumina, silica, flyash 등의 무기질 filler를 최대 70wt(%) 이상으로 고충진한 복합 폴리머 성형체를 개발하고자 하였다.(중략)

• Elastomers and Composites
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• v.54 no.1
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• pp.22-29
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• 2019

Chitosan-polyvinyl alcohol (PVA) -bamboo charcoal/silica (CS-PVA-BC/SI) hybrid fillers with compatibilized styrene-butadiene rubber (SBR) composites were fabricated by the interpenetrating polymer network (IPN) method. The structure and composition of the composite samples were characterized by scanning electron microscope (SEM) and Fourier transform infrared spectroscopy (FT-IR). The viscoelastic behaviors of the rubber composites and their vulcanizates were explored using a rubber processing analyzer (RPA) in the rheometer, strain sweep and temperature sweep modes. The storage and loss moduli of SBR increased significantly with the incorporation of different hybrid fillers, which was attributed to the formation of an interphase between the hybrid fillers and rubber matrix, and the effective dispersion of the hybrid fillers. The mechanical properties (hardness, tensile strength, oxygen transmission rate, and swelling rate) of the composite samples were characterized in detail. From the results of the mechanical test, it was found that BC-CS-PVA0SBR had the best mechanical properties. Therefore, the BC-CS-PVA hybrid filler provided the best reinforcement effects for the SBR latex in this research.

• Journal of the Korean Wood Science and Technology
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• v.52 no.4
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• pp.331-342
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• 2024

Rubberwood (Hevea brasiliensis) has excellent physical and mechanical properties and is one of the most widely used species in Southeast Asia. However, it has poor resistance to subterranean termite attacks due to its high sugar and starch contents. The objective of this study was to evaluate the termite resistance of experimental wood-plastic composite (WPC) panels manufactured from rubberwood flour, polyethylene terephthalate, and silica in three different weight ratios (1/2/7, 1/3/6, and 1/4/5). The panels were exposed to Coptotermes curvignathus subterranean termites in a no-choice test under laboratory conditions based on Indonesian standards. Solid rubberwood used as control samples presented poor resistance, exhibiting 23.1% weight loss due to subterranean termite attack, as indicated by low termite mortality and high wood weight loss. In contrast, the WPC samples demonstrated extreme resistance, with weight loss ranging from 0.19% to 0.23%. Based on the findings of this study, the high termite mortality and overall low mass loss of the samples indicate that such manufactured panels could provide a high level of protection with regard to Indonesian standards.