• 제목/요약/키워드: Si distribution

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반응로내 이온주입에 의한 초미세입자의 합성 및 응집제어 (Synthesis and Control of Ultrafine Particles by Ion-Injection in Furnace)

  • 윤진욱;김영원;안강호
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2001년도 춘계학술대회논문집D
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    • pp.91-96
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    • 2001
  • Ultrafine particles have been widely used in many high technology industrial areas. The spherical nonagglomerated and uniform nanometer-size $SiO_{2}$ particles are synthesized by the injection of TEOS vapor, ions and reaction gas in furnace. Ions were generated by Corona discharge electrode and these ions charge $SiO_{2}$ particles. As a result, spherical, nonagglomerated and ultrafine particles are generated in various conditions, it's morphology, charging portion and size distribution are examined by using TEM, ESP and SMPS. As the applied voltage of electrode changes from 0 kV to 5.0 kV, it is observed that the mean diameter of $SiO_{2}$ particle decreases from 94 nm to 42 nm.

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PECVD로 증착된 $SiO_2$의 non-uniformity 특성 연구 (The study on the $SiO_2$ film non-uniformity by Plasma Enhanced Chemical Vapor Deposition)

  • 함용현;권광호
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 추계학술대회 논문집 Vol.21
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    • pp.73-73
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    • 2008
  • In this work, the study on the $SiO_2$ film non-uniformity by PECVD (Plasma Enhanced Chemical Vapor Deposition) was performed. Plasma diagnostics was analyzed by a DLP(Double Langmuir Probe) and a probe-type QMS(Quadrupole Mass Spectrometer) in order to investigate the spatial distribution of the plasma species in the chamber. The relationship between the plasma species and the depositing rate of the films was examined. On the basis of this work, it was confirmed that O radical density mainly contributed to the increase in the depositing rate of the $SiO_2$ films and the electron temperature in the plasma had a main effect on the formation of the oxygen radicals.

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Mg-Al-Si 합금에서 진동감쇠능의 변형진폭 의존성 (Strain Amplitude Dependence of Damping Capacity in Mg-AI-Si Alloy)

  • 전중환
    • 열처리공학회지
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    • 제24권3호
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    • pp.144-148
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    • 2011
  • Change in damping capacity with strain amplitude was studied in Mg-Al-Si alloy in as-cast, solution-treated and aged states, respectively. The as-cast microstructure of the alloy is characterized by eutectic ${\beta}$($Mg_{17}Al_{12}$) phase and Chinese script type $Mg_2Si$ particles. The solution treatment dissolved the ${\beta}$ phase into the matrix, while the aging treatment resulted in the distribution of continuous and discontinuous type ${\beta}$ precipitates. The solution-treated microstructure showed better damping capacity than as-cast and aged microstructures both in strain-dependent and strain-independent damping regions. The decrease in second-phase particles which weakens the strong pinning points on dislocations and distribution of solute atoms in the matrix, would be responsible for the enhanced damping capacity after solution treatment.

Al-xSi 합금의 인장특성에 미치는 공정 Si 입자의 파단과 미소기공율의 영향 (Effects of Damage Evolution of Eutectic Si Particle and Microporosity to Tensile Property of Al-xSi Alloys)

  • 이충도
    • 한국주조공학회지
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    • 제41권5호
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    • pp.434-444
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    • 2021
  • 본 연구에서는 미소기공과 Si석출상의 파단으로 구성되는 유효기공 면적분율에 대한 인장특성의 결함민감도 관점에서 Al-Si합금의 인장특성을 공정 Si입자의 분포양상 변화에 대하여 평가하고자 하였다. Al-xSi(x=2,5,8,11)합금의 주방상태 미세조직인 망상구조의 공정 Si입자는 T4처리를 통하여 과립형태로 변형시켰으며, CT분석과 주사전자현미경 관찰을 통하여 미소기공의 분포와 크기를 평가하였다. CT분석과 주사전자현미경의 비교분석을 통하여 인장변형과정에서의 균열성장이 최대 기공율을 포함하는 국부영역에서 발생함을 확인할 수 있었다. 그럼에도 불구하고 이들 분석방법에는 미소기공 인접영역에서의 소성변형집중과 미소기공의 분포양상에 의해 파생되는 실제적인 차이를 포함하기 때문에 정확히 일치된 결과를 얻을 수 없었다. 유효기공 면적분율의 변화에 대한 인장강도와 연신율의 변화는 과립형태보다 망상구조 정출상의 분율변화에 더욱 민감한 의존도를 가진다.

PTA법에 의한 Al 합금표면의 Si 합금층 형성과 내마모성 개선 (Improvement of Wear Resistance and Formation of Si Alloyed Layer on Aluminum Alloy by PTA Process)

  • 박성두;이영호
    • Journal of Welding and Joining
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    • 제15권5호
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    • pp.134-143
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    • 1997
  • The formation of thick alloyed layer with high Si content have been investigated on the surface of Al alloy (A5083) plate by PTA process with Si powder. Hardening characteristics and wear resistance of alloyed layer was examined in relation to the microstructure of alloyed layer. Thick hardened layer in mm-order thickness on the surface of A5083 plate can be formed by PTA process with wide range of process condition by using Si powder as alloying element because of eutectic reaction of Al-Si binary alloy. High temperature and rapid solidification rate of molten pool, which are features of PTA process, enable the formation of high Si content alloyed layer with uniform distribution of fine primary Si paticle. High plasma arc current was beneficial to make the alloyed layer with smooth surface appearance in wide range of powder feeding rate, because enough volume of molten pool was necessary make alloyed layer. Uniform dispersion of fine primary Si particle with about 30${\mu}{\textrm}{m}$ in particle size can be obtained in layer with Si content ranging from 30 to 50 mass %. Hardness of alloyed layer increased with increasing Si content, but increasing rate of hardness differed with macrostructure of alloyed layer. Wear resistance of alloyed layer depended on $V_{si}$(volume fraction of primary Si) and was remarkably improved to two times of base metal at 20-30% $V_{si}$ without cracking, but no more improvement was obtained at larger $V_{si}$.

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태양광 발전의 분포 변화: 시군구 단위에서의 분석 (Change in Spatial Distribution of Photovoltaic Power Generation )

  • 이정섭;이강원;지상현
    • 한국경제지리학회지
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    • 제25권4호
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    • pp.484-498
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    • 2022
  • 이 연구의 목적은 전국 229개 시군구를 공간 단위로 설정하여 태양광 발전의 입지, 분포 그리고 변화를 분석하는 것이다. 이를 위해서 첫째, 2020년 시군구별 발전량과 발전설비 용량을 통해서 태양광 발전의 분포를 분석했고, 둘째 2017년부터 2021년까지 시군구별 발전설비 증가량을 확인하여 시계열적 변화를 추적했다. 분석 결과, 발전량, 발전설비 용량 및 증가량 모두 몇몇 시군구에 집중되었는데, 그 정도는 상위 5개 시군구가 차지하는 비중이 12% 이상, 상위 10개 및 20개 시군구로는 각각 20%와 33% 이상이었고, 태양광 발전에 대한 지니 계수는 약 0.6이었다. 따라서 시군구 단위에서 태양광 발전의 불균등한 분포가 확인되었다.

A New Approach to Synthesis and Photoluminescence of Silicon Nanoparticles

  • Kim, Beomsuk
    • 통합자연과학논문집
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    • 제2권1호
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    • pp.28-31
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    • 2009
  • We describe the synthesis and characterization of silicon nanoparticles prepared by the soluton reduction of SiCl4. These reactions produce Si nanoparticles with surfaces that are covalently terminated. The resultant organic derivatized Si nanoparticles as well as a probable distribution of Water-soluble Si nanoparticles are observed and characterized by photoluminescence(PL) spectroscopy. This work focuses originally on the organic- and water-soluble silicon nanoparticles in terms of the photoluminescence. Further this work displays probably the first layout of hydrogen terminated Si nanoparticles synthesized in solution at room temperature.

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분말 충전 성형법을 이용한 SiC-Al Alloy 복합체의 제조 (Preparation of SiC-Al alloy Composite by Pressureless Powder Packing Forming Method)

  • 박정현;송준광;백승수;염강섭;강민수
    • 한국세라믹학회지
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    • 제34권4호
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    • pp.343-350
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    • 1997
  • To fabricate the ceramic/metal(SiC/ Al alloy) composite, SiC preform was prepared by Pressureless Powder Packing Forming Method and 6061 Al alloy was infiltrated into the preform. Uniform compact having an average pore size of 10 ${\mu}{\textrm}{m}$ and narrow pore size distribution was prepared. Phenolic resin solution(40 wt%) was penetrated into the SiC compact, and then the compact was preheated at the temperature of 120$0^{\circ}C$. The pore size distribution and the microstructure of the preform were not changed by preheating. An uniform microstructure without any crack in the preform was obtained in SiC-Al alloy composite. The infiltration of 6061. Al alloy into the preform began at the temperature of 130$0^{\circ}C$ and the amount of infiltration increased in proportion to the infiltration temperature and the soaking time. The increasement rate of the infiltration amount decreased after 3 h. As a result of the infiltration at 140$0^{\circ}C$ for 4 h, Al alloy was well distributed in the interparticle channels and the relative density of the composite was above 98%. The strength and the fracture toughness of the composite were 303 MPa and 21.65 MPam1/2, respectively.

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$SiCp/A\ell$ 6061 복합재료의 피로균열진전특성에 관한 통계학적 해석 (Statistical Analysis of Fatigue Crack Growth Properties for Silicon Carbide Particles Reinforced Metal Matrix Composites)

  • 권재도;문윤배;안정주
    • 한국자동차공학회논문집
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    • 제4권4호
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    • pp.130-139
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    • 1996
  • The silicon carbide particles reinforced aluminium 6061($SiCp/A\ell$) composites are generally known have wild range of applications from automobiles to airospaces. But, by the results of existing study for $SiCp/A\ell$ composites, there are reports that the fatigue life of $SiCp/A\ell$ composites has improved than $A\ell$matrixes and has not improved then $A\ell$ matrixes. Consequently, in order to perform the reliable life prediction for $SiCp/A\ell$, the properties of probability distribution of fatigue crack initiation life & fracture life, crack growth length in constant number of cycles, crack growth rate in constant stress intensity factor range and m & C value in Paris's fatigue crack growth law and the estimation of statistical parameters have been evaluated by the statistics method.

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Fe와 Hexamethyldisilabutane를 이용한 SiC 나노로드의 성장 (Growth of SiC Nanorods Using Fe and Hexamethyldisilabutane)

  • 노대호;김재수;변동진;양재웅;김나리
    • 한국표면공학회지
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    • 제36권3호
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    • pp.234-241
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    • 2003
  • SiC nanorod was synthesized directly on Si substrate using hexamethyldisilabutane and Fe catalyst with (111) direction. Fe acted a liquid catalyst at growth condition. Grown SiC nanorod has about 30nm diameter and $5{\mu}m$ length. SiC nanorod growth was divided by trro regions with diameter distribution. This diameter distribution were occurred by surface deposition at as - grown nanorod's surface by limitation of growth rate. At higher temperature, these division not occurred. Growth temperature and flow rates affected diameter and morphology of nanorods. With increasing flow rate of source gas, nanorod's diameter increased because of deactivation effect. Case of the increasing temperature, growth rate increased so deactivation did not occurred.