• Title/Summary/Keyword: Si Content

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The Effects of Si and Mo on the Structures and Mechanical Properties in High Si Spheroidal Graphite Cast Iron (고 Si 구상흑연주철의 조직과 기계적성질에 미치는 Si과 Mo의 영향)

  • Kim, Jong-Yeon;Ra, Hyung-Yong
    • Journal of Korea Foundry Society
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    • v.10 no.3
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    • pp.225-234
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    • 1990
  • Spheroidal graphite cast irons which are Fe-3%C-(4-6)%Si-(0-0.5)%Mo were studied to improve not only heat resistance but also mechanical properties. With increasing Mo content, the graphitization was decreased and carbide volume fraction was increased. The graphite spheroidization ratio was not decreased in Fe-3%C-6%Si-Mo system cast iron with increasing Mo content, but that was decreased in Fe-3%C-4%Si-Mo system and Fe-3%C-5%Si-Mo system cast irons. Hardness was increased with the Si and Mo contents. At constant Si content, tensile strength was increased with increasing Mo content, but that was decreased at 6%Si. In the experiment of oxidation, weight gain was decreased as the Si and/or Mo content increased, but increased at 1.5%Mo content.

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Microstructure and Mechanical Properties of SiC-BN Composites with Oxynitride Glass

  • Lee, Young-Il;Kim, Young-Wook
    • Journal of the Korean Ceramic Society
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    • v.40 no.3
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    • pp.229-233
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    • 2003
  • By using an oxynitride glass as a sintering additive, the effects of BN content on microstructure and mechanical properties of the hot-pressed and subsequently annealed SiC-BN composites were investigated. The microstructures developed were analyzed by image analysis. The morphology of SiC grains was strongly dependent on BN content in the starting composition. The aspect ratio of SiC decreases with increasing BN content and the average diameter of SiC shows a maximum at 5 wt% BN and decreases with increasing BN content in the starting powder. The fracture toughness increased with increasing BN content while the strength decreased with increasing BN content. The strength and fracture toughness of SiC or SiC-TiC composites were strongly dependent on the morphology of SiC grains, but the strength and fracture toughness of SiC-BN composites were strongly dependent on BN content rather than morphology of SiC grains. These results suggest that fracture toughness of SiC ceramics can be tailored by manipulating BN content in the starting composition. Typical fracture toughness and strength of SiC-10 wt% BN composites were 8 MPa$.$m$\^$1/2/ and 445 MPa, respectively.

Co-deposition of Si Particles During Electrodeposition of Fe in Sulfate Solution (황산철 도금액 중 Si 입자의 공석 특성)

  • Moon Sung-Mo;Lee Sang-Yeal;Lee Kyu-Hwan;Chang Do-Yon
    • Journal of Surface Science and Engineering
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    • v.37 no.6
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    • pp.319-325
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    • 2004
  • Fe thin films containing Si particles were prepared on metallic substrates by electrodeposition method in sulfate solutions and the content of codeposited Si particles in the films was investigated as a function of applied current density, the content of Si particels in the solution, solution pH, solution temperature and concentration of $FeSO_4$$7H_2$O in the solution. The amount of Si codeposited in the film was not dependent on the applied current density, solution pH and solution temperature, while it was dependent on the content of Si particles in the solution and the concentration of $FeSO_4$$7H_2$O in the solution. The amount of Si codeposited in the film increased with increasing content of Si particles in the solution but reached a maximum value of about 6 wt% when the content of Si particles in the solution exceeds 100 g/l. On the other hand, the content of Si codeposited in the film increased up to about 17 wt% with decreasing concentration of $FeSO_4$$7H_2$O in the solution. These results would be applied to the fabrication of very thin Fe-6.5 wt% Si sheets for electrical applications.

Effects of Ca on the Refinement of Microstructure in Aluminum B390 Alloy (알루미늄 B390합금의 조직미세화에 미치는 Ca의 영향)

  • Kim, Heon-Joo
    • Journal of Korea Foundry Society
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    • v.22 no.5
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    • pp.257-264
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    • 2002
  • Effects of Ca content on the refinement of primary Si of Aluminum B390 alloy have been examined. Ca was found to have an effect on the refinement of primary Si particle. Primary Si particle size has been refined as Ca content of the melts decreased and cooling rate increased. A control of Ca content by the addition of $CuCl_2$ to the melt was the most efficient in the refinement of primary Si particles. The minimum size of primary Si particles in this study was $15.0\;{\mu}m$ when a residual content of Ca element in the alloy was 5ppm, Primary Si particle size was refined as primary Si crystallization temperature increased, which was attributed to the decrease of Ca content in the melts.

Effects of the SiC Particle Size and Content on the Sintering and Mechanical Behaviors of $Al_2O_3$/SiC Particulate Composites

  • Ryu, Jung-Ho;Lee, Jae-Hyung
    • The Korean Journal of Ceramics
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    • v.3 no.3
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    • pp.199-207
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    • 1997
  • $Al_2O_3$/SiC particulate composites were fabircated by pressureless sintering. The dispersed phase was SiC of which the content was varied from 1.0 to 10 vol%. Three SiC powders having different median diameters from 0.28 $\mu\textrm{m}$ to 1.9 $\mu\textrm{m}$ were used. The microstructure became finer and more uniform as the SiC content increased except the 10 vol% specimens, which were sintered at a higher temperature. Under the same sintering condition, densification as well as grain growth was retarded more severly when the SiC content was higher or the SiC particle size was smaller. The highest flexural strength obtained at 5.0 vol% SiC regardless of the SiC particle size seemed to be owing to the finer and more uniform microstructures of the specimens. Annealing of the specimens at $1300^{\circ}C$ improved the strength in general and this annealing effect was good for the specimens containing as low as 1.0 vol% of SiC. Fracture toughness did not change appreciably with the SiC content but, for the composites containing 10 vol% SiC, a significantly higher toughness was obtained with the specimen containing 1.9$\mu\textrm{m}$ SiC particles.

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Effect of Fe, Mn Content on the Tensile Property of Al-4 wt%Mg-0.9 wt%Si Alloy System for High Pressure Die Casting (고압 금형 주조용 Al-4 wt%Mg-0.9 wt%Si계 합금의 인장특성에 미치는 Fe, Mn함량의 영향)

  • Kim, Heon-Joo
    • Journal of Korea Foundry Society
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    • v.33 no.3
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    • pp.103-112
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    • 2013
  • Effect of Fe and Mn contents on the tensile properties of Al-4 wt%Mg-0.9 wt%Si alloy system has been studied. Common phases of Al-4 wt%Mg-0.9 wt%Si alloy system were ${\alpha}$-Al, $Mg_2Si$, ${\alpha}-Al_{12}(Fe,Mn)_3Si$ and ${\beta}-Al_5FeSi$. As Fe content of Al-4 wt%Mg-0.9 wt%Si alloy system increased from 0.15 wt% to above 0.3 wt%, ${\beta}-Al_5FeSi$ compound appeared. When Mn content of the alloy increased from 0.3 wt% to 0.5 wt%, morphology of plate shaped ${\beta}-Al_5FeSi$ compound changed to chinese script ${\alpha}-Al_{12}(Fe,Mn)_3Si$. As Fe content of Al-4 wt%Mg-0.9 wt%Si-0.3 wt%Mn alloy increased from 0.15 wt% to 0.4 wt%, tensile strength of the as-cast alloy decreased from 191 MPa to 183 MPa and, elongation of the alloy also decreased from 8.0% to 6.2%. Decrease of these properties can be explained as the formation of plate shape, ${\beta}-Al_5FeSi$ phase with low Mn/Fe ratio of the alloy. However, when Mn content of Al-4 wt%Mg-0.9 wt%Si-0.3 wt%Fe alloy increased from 0.3 wt% to 0.5 wt%, tensile strength of as-cast alloy increased from 181 MPa to 194 MPa and, elongation of the alloy increased from 6.8% to 7.0%. These improvements attribute to the morphology change from ${\beta}-Al_5FeSi$ phase to chinese script, ${\alpha}-Al_{15}(Fe,Mn)_3Si_2$ phase shape-modified from with high Mn/Fe ratio of the alloy.

Syntheses and Mechanical Properties of Quaternary Cr-Si-O-N Coatings by Hybrid Coating System (하이브리드 코팅시스템에 의한 Cr-Si-O-N 코팅막 합성 및 기계적 성질)

  • Lee, Jeong-Doo;Wang, Qi Min;Kim, Kwang-Ho
    • Journal of Surface Science and Engineering
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    • v.43 no.5
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    • pp.238-242
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    • 2010
  • In the present work, the influence of oxide on the Cr-Si-N coatings was investigated for the Cr-Si-O-N coatings on AISI 304 and Si wafer deposited by hybrid system, which combines the DC magnetron sputtering technique and arc ion plating (AIP) using Cr and Si target in an $Ar/N_2/O_2$ gaseous mixture. As the O content in the Cr-Si-N coatings increased, the diffraction patterns of the Cr-Si-O-N coatings showed CrN and $Cr_2O_3$ phases. However, as the O content increased to 28.8 at.%, diffraction peak of $Cr_2O_3$ was disappeared in the Cr-Si-O-N coating. The $d_{200}$ value was decreased with increasing of O content. The average grain size increased from about 40 nm to 65 nm as the O content increased. The maximum micro-hardness of the Cr-Si-O-N coating was obtained 4507 Hk at the O content of 24.8 at.%. The average friction coefficient of the Cr-Si-O-N coatings was gradually decreased by increasing the O content and the average friction coefficient decreased from 0.37 to 0.25 by increasing the O content. These results indicated that amorphous phase was increased in the Cr-Si-O-N coatings by increasing of O content.

Tribological Behavior of Si-DLC/DLC Coatings with Various Si Contents (Si 함유량에 따른 Si-DLC/DLC 코팅의 건조마찰 특성)

  • Ahn, Hyo-Sok
    • Transactions of the Korean Society of Machine Tool Engineers
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    • v.16 no.6
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    • pp.212-216
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    • 2007
  • Although DLC coatings have good tribological properties, these are dependent on the deposition method, property of contact surface, and test condition. Si-DLC/DLC coatings with various Si content were deposited on Si substrates and tested using a reciprocating friction tester against steel balls. The results revealed that the tribological behavior of Si-DLC/DLC coatings was dependent on the Si content. The formation of transfer film and wear particles on the contact surface was greatly influenced by the Si content in DLC coatings. In particular, silicon oxide transfer film formed by tribochemical reaction contributed to reduce wear and friction.

Effect of Fe, Mn Content on the Castability of Al-4%Mg-0.9%Si Alloys for High Pressure Die Casting (고압 금형 주조용 Al-4%Mg-0.9%Si 합금의 주조특성에 미치는 Fe, Mn 함량의 영향)

  • Kim, Heon-Joo
    • Journal of Korea Foundry Society
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    • v.33 no.2
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    • pp.55-62
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    • 2013
  • Effect of Fe and Mn contents on the castability of Al-4wt%Mg-0.9wt%Si system alloy has been studied. According to the analysis of cooling curve for Al-4wt%Mg-0.9wt%Si-0.3wt%Fe-0.3/0.5wt%Mn alloy, ${\alpha}-Al_{15}(Fe,Mn)_3Si_2$ and ${\beta}-Al_5FeSi$ phases crystallized above eutectic temperature of $Mg_2Si$. Therefore, these phases affected both the fluidity and shrinkage behaviors of the alloy during solidification. As Fe and Mn contents of Al-4wt%Mg-0.9wt%Si system alloy increased from 0.1 wt% to 0.4 wt% and from 0.3 wt% to 0.5 wt% respectively, the fluidity of the alloy decreased by 26% and 33%. When Fe content of the alloy increased from 0.1 wt% to 0.4 wt%, 23% decrease of macro shrinkage and 19% increase of micro shrinkage appeared. Similarly, Mn content of the alloy increased from 0.3 wt% to 0.5 wt%, 11% decrease of macro shrinkage and 14% increase of micro shrinkage appeared. Judging from the castability of the alloy, Al-4wt%Mg-0.9wt%Si alloy with low content of Fe and Mn, 0.1 wt% Fe and 0.3 wt% Mn, is recommendable.

Effect of Fe, Mn Content on the Castability in Al-9wt%Si-Mg System Alloys for High Elongation (고신율 금형주조용 Al-9wt%Si-Mg계 합금의 주조특성에 미치는 Fe, Mn함량의 영향)

  • Kim, Heon-Joo;Jeong, Chang-Yeol
    • Journal of Korea Foundry Society
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    • v.33 no.6
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    • pp.233-241
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    • 2013
  • Effect of Fe and Mn contents on the castability of Al-9wt%Si-xMg-yFe-zMn alloy has been studied. The alloy was composed of ${\alpha}$-Al phase, Al+eutectic Si phase, ${\beta}$-Al5FeSi compound and chinese script ${\alpha}$-$Al_{15}(Mn,Fe)_3Si_2$ compound. ${\beta}$-$Al_5FeSi$ and ${\alpha}$-$Al_{15}(Mn,Fe)_3Si_2$ compounds assumed to effect the fluidity and shrinkage behaviors of the alloy during solidification due to the crystallization of ${\alpha}$-$Al_{15}(Fe,Mn)_3Si_2$ and ${\beta}$-$Al_5FeSi$ compounds above eutectic temperature. As Fe and Mn contents of Al-9wt%Si-0.3wt%Mg system alloy increased from 0.15wt% to 0.6wt% and from 0.3wt% to 0.7wt%, fluidity of the alloy decreased by 5.7% and 3.3%, respectively. And as Mg content of Al-9wt%Si-0.45wt%Fe-0.5wt%Mn system alloy increased from 0.3wt% to 0.4wt%, fluidity of the alloy decreased by 8.6%. When Fe content of the alloy increased from 0.15wt% to 0.6wt%, macro shrinkage ratio decreased from 6.1% to 4.1%, and micro shrinkage ratio increased from 0.04% to 0.24%. Similarly, Mn content of the alloy increased from 0.3wt% to 0.7wt%, macro shrinkage ratio decreased from 6.0% to 4.5% and micro shrinkage ratio increased from 0.12% to 0.18%. Judging from the castability of the alloy, Al-9wt%Si-0.3wt%Mg alloy with low content of Fe and Mn, 0.1wt% Fe and 0.3wt% Mn, is recommendable.