• Title/Summary/Keyword: Si(IV)

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Occurrence and Chemical Composition of White Mica from Zhenzigou Pb-Zn Deposit, China (중국 Zhenzigou 연-아연 광상의 백색운모 산상과 화학조성)

  • Yoo, Bong Chul
    • Korean Journal of Mineralogy and Petrology
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    • v.35 no.2
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    • pp.83-100
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    • 2022
  • The Zhenzigou Pb-Zn deposit, which is one of the largest Pb-Zn deposit in the northeast of China, is located at the Qingchengzi mineral field in Jiao Liao Ji belt. The geology of this deposit consists of Archean granulite, Paleoproterozoinc migmatitic granite, Paleo-Mesoproterozoic sodic granite, Paleoproterozoic Liaohe group, Mesozoic diorite and Mesozoic monzoritic granite. The Zhenzigou deposit which is a strata bound SEDEX or SEDEX type deposit occurs as layer ore and vein ore in Langzishan formation and Dashiqiao formation of the Paleoproterozoic Liaohe group. White mica from this deposit are occured only in layer ore and are classified four type (Type I : weak alteration (clastic dolomitic marble), Type II : strong alteration (dolomitic clastic rock), Type III : layer ore (dolomitic clastic rock), Type IV : layer ore (clastic dolomitic marble)). Type I white mica in weak alteration zone is associated with dolomite that is formed by dolomitization of hydrothermal metasomatism. Type II white mica in strong alteration zone is associated with dolomite, ankerite, quartz and alteration of K-feldspar by hydrothermal metasomatism. Type III white mica in layer ore is associated with dolomite, ankerite, calcite, quartz and alteration of K-feldspar by hydrothermal metasomatism. And type IV white mica in layer ore is associated with dolomite, quartz and alteration of K-feldspar by hydrothermal metasomatism. The structural formulars of white micas are determined to be (K0.92-0.80Na0.01-0.00Ca0.02-0.01Ba0.00Sr0.01-0.00)0.95-0.83(Al1.72-1.57Mg0.33-0.20Fe0.01-0.00Mn0.00Ti0.02-0.00Cr0.01-0.00V0.00Sb0.02-0.00Ni0.00Co0.02-0.00)1.99-1.90(Si3.40-3.29Al0.71-0.60)4.00O10(OH2.00-1.83F0.17-0.00)2.00, (K1.03-0.84Na0.03-0.00Ca0.08-0.00Ba0.00Sr0.01-0.00)1.08-0.85(Al1.85-1.65Mg0.20-0.06Fe0.10-0.03Mn0.00Ti0.05-0.00Cr0.03-0.00V0.01-0.00Sb0.02-0.00Ni0.00Co0.03-0.00)1.99-1.93(Si3.28-2.99Al1.01-0.72)4.00O10(OH1.96-1.90F0.10-0.04)2.00, (K1.06-0.90Na0.01-0.00Ca0.01-0.00Ba0.00Sr0.02-0.01)1.10-0.93(Al1.93-1.64Mg0.19-0.00Fe0.12-0.01Mn0.00Ti0.01-0.00Cr0.01-0.00V0.00Sb0.00Ni0.00Co0.05-0.01)2.01-1.94(Si3.32-2.96Al1.04-0.68)4.00O10(OH2.00-1.91F0.09-0.00)2.00 and (K0.91-0.83Na0.02-0.01Ca0.02-0.00Ba0.01-0.00Sr0.00)0.93-0.83(Al1.84-1.67Mg0.15-0.08Fe0.07-0.02Mn0.00Ti0.04-0.00Cr0.06-0.00V0.02-0.00Sb0.02-0.01Ni0.00Co0.00)2.00-1.92(Si3.27-3.16Al0.84-0.73)4.00O10(OH1.97-1.88F0.12-0.03)2.00, respectively. It indicated that white mica of from the Zhenzigou deposit has less K, Na and Ca, and more Si than theoretical dioctahedral mica. Compositional variations in white mica from the Zhenzigou deposit are caused by phengitic or Tschermark substitution [(Al3+)VI+(Al3+)IV <-> (Fe2+ or Mg2+)VI+(Si4+)IV] substitution. It means that the Fe in white mica exists as Fe2+ and Fe3+, but mainly as Fe2+. Therefore, white mica from layer ore of the Zhenzigou deposit was formed in the process of remelting and re-precipitation of pre-existed minerals by hydrothermal metasomatism origined metamorphism (greenschist facies) associated with Paleoproterozoic intrusion. And compositional variations in white mica from the Zhenzigou deposit are caused by phengitic or Tschermark substitution [(Al3+)VI+(Al3+)IV <-> (Fe2+ or Mg2+)VI+(Si4+)IV] substitution during hydrothermal metasomatism depending on wallrock type, alteration degree and ore/gangue mineral occurrence frequency.

Ring-opening Polymerization of L-Lactide with Silica Supported Titanium Alkoxide Catalysts

  • Kim, Eon-Ah;Shin, Eun-Woo;Yoo, Ik-Keun;Chung, Jin-Suk;Hong, Youn-Jin;Kim, Young-Jo
    • Macromolecular Research
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    • v.17 no.5
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    • pp.346-351
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    • 2009
  • $TiCl(O-i-Pr)_3/SiO_2$ and $Ti(O-i-Pr)_4/SiO_2$ were prepared by immobilizing chlorotitanium (IV) isopropoxide ($TiCl(O-i-Pr)_3$) and titanium (IV) isopropoxide ($Ti(O-i-Pr)_4$), to pretreated silica. The effect of the polymerization reaction conditions on the catalytic activity and characteristics of the resulting PLA were investigated. The catalytic conversion, molecular weight and polydispersity index (PDI) of the PLA produced on the titanium alkoxide supported catalysts increased proportionally with the reaction temperature. When the PLA was synthesized in bulk polymerization, the PLA produced with the supported catalysts had higher molecular weight than those with homogeneous catalysts. The melting temperature of the polymer produced with silica supported alkoxide catalysts was approximately $170-180^{\circ}C$.

Ground-based and On-satellite Observations of Be and B Stars (인공위성관측과 지상관측에 의한 Be성과 B성의 연구)

  • 정장해
    • Journal of Astronomy and Space Sciences
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    • v.5 no.1
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    • pp.9-18
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    • 1988
  • Gamma Cassiopeae has been observe at Yonsei University Observatory(YUO) for 31 nights in the period 1983-1987 and a total of 312 UBV observations(104 in each colour) was secured. Light curves of ${\gamma}$ Cas in V, B-V, and U-B have been constructed with the YUO data; among them we present selected light curves of 5 different long nights. Discussed are the general photometric behaviour of ${\gamma}$ Cas, especially in connection with B-V changes, V/R variations of $H\alpha$ and H$\beta$, and high velocity narrow component(hvnc) exhibited in the far UV. Six spectral image sets of $\varepsilon$Per archived on IUE satellite are reduced and their line profiles in C IV and Si IV resonance lines are analyzed to find out any change, but the evidence is unlikely.

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Fabrication of High Permeable Nanoporous Carbon-SiO$_2$ Membranes Derived from Siloxane-containing Polyimides

  • Kim, Youn Kook;Han, Sang Hoon;Park, Ho Bum;Lee, Young Moo
    • Korean Membrane Journal
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    • v.6 no.1
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    • pp.16-23
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    • 2004
  • The silica containing carbon (C-SiO$_2$) membranes were fabricated using poly(imide siloxane) (PIS) having -CO- swivel group. The characteristics of porous C-SiO$_2$ structures prepared by the pyrolysis of poly(imide siloxane) were related with the micro-phase separation between the imide block and the siloxane block. Furthermore, the nitrogen adsorption isotherms of the CMS and the C-SiO$_2$ membranes were investigated to define the characteristics of porous structures. The C-SiO$_2$ membranes derived from PIS showed the type IV isotherm and possessed the hysteresis loop, which was associated with the mesoporous carbon structures, while the CMS membranes derived from PI showed the type I isotherm. For the molecular sieving probe, the C-SiO$_2$ membranes pyrolyzed at 550, 600, and 700$^{\circ}C$ showed the O$_2$ permeability of 924, 1076, and 367 Barrer (1 ${\times}$ 10$\^$-10/㎤(STP)cm/$\textrm{cm}^2$$.$s$.$cmHg) and O$_2$/N$_2$ selectivity of 9, 8, and 12.

Integrated Nano Optoelectronics

  • Jo, Moon-Ho
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.117-117
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    • 2012
  • Si:Ge alloy semiconductor nanocrystals (NCs) offer challenging opportunities for integrated optoelectronics/optoplasmonics, since they potentially allow unprecedentedly strong light-matter interaction in the wavelength range of the optical communication. In this talk, we discuss the recent research efforts of my laboratory to develop optoelectronic components based on individual group IV NCs. We present experimental demonstration of the individual NC optoelectronic devices, including broadband Si:Ge nanowire (NW) photodetectors, intra NW p-n diodes, Ge NC electrooptical modulators and near-field plasmonic NW detectors, where the unique size effects at the nanometer scales commonly manifest themselves. In particular, we demonstrated a scanning photocurrent imaging technique to investigate dynamics of photocarriers in individual Si:Ge NWs, which provides spatially and spectrally resolved local information without ensemble average. Our observations represent inherent size-effects of internal gain in semiconductor NCs, thereby provide a new insight into nano optoplasmonics.

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Nanostructured Bulk Ceramics (Part IV. Polymer Precursor Derived Nanoceramics)

  • Han, Young-Hwan;Mukherjee, Amiya K.
    • Journal of the Korean Ceramic Society
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    • v.47 no.3
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    • pp.205-209
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    • 2010
  • In the last (fourth) section, the discussion will entail a silicon-nitride/silicon-carbide nanocomposite, produced by pyrolysis of liquid polymer precursors, demonstrating one of the lowest creep rates reported so far in ceramics at the comparable temperature of $1400^{\circ}C$. This was first achieved by avoiding the oxynitride glass phase at the intergrain boundaries. One important factor in the processing of these nanocomposites was the use of the electrical field assisted sintering method.

GRB 140304A at z=5.283: Implications on the high redshift universe and the observed flaring activities

  • Jeong, Soomin
    • The Bulletin of The Korean Astronomical Society
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    • v.41 no.1
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    • pp.38.1-38.1
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    • 2016
  • Gamma ray burst, the most brightest explosion phenomena in the current universe is well suited for study of high redshift universe. We report the afterglow multi-wavelength observation and GTC spectroscopy follow up of GRB 140304A which was exploded at z=5.283. The spectrum was shown damped Lyman alpha features and a series of absorption lines S, Si, SiII*, Oi, CII, CII*, SiIV are clearly detected at common redshift. Clear optical flares are detected when X-ray flare happened and a possible gamma-ray excess also. At this conference, we report on implications for the GRB host and environments using its absorption features which place the results in context to other well studied high redshift GRBs and studies about the ejecta using its observed flaring activities.

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Electrical Characteristics of the Packaged SiGe Hetero-Junction Bipolar Transistors Fabricated with Various Conditions of the Collector Formation (패키지된 실리콘-게르마늄 이종접합 바이폴라 트랜지스터의 콜렉터 형성 조건에 따른 전기적 특성)

  • Lee, Seung-Yun;Lee, Sang-Heung;Kim, Hong-Seung;Park, Chan-U;Kim, Sang-Hun;Lee, Ja-Yeol;Sim, Gyu-Hwan;Gang, Jin-Yeong
    • Korean Journal of Materials Research
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    • v.12 no.6
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    • pp.470-475
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    • 2002
  • The effects of the conditions of the collector formation on electrical characteristics of the packaged SiGe hetero-junction bipolar transistors (HBT) were investigated. While the DC characteristics of SiGe HBTs such as IV characteristic, forward current gain, Early voltage, and breakdown voltage were hardly changed after packaging, the AC characteristics such as $f_{\tau}\; and\; f_{max}$ were degraded severely. With the rise of the collector concentration, the break-down voltage decreased but the $f_{\tau}$ increased. Additionally, $\beta$ and $f_{\tau}$ values were kept high in the range of elevated collector current due to the increase of the critical current density for the onset of the Kirk effect. The devices As implanted before the collector deposition showed lower breakdown voltage and higher $f_{\tau}$ than the others, which seems to be originated from the As up-diffusion resulting in the thinner collector.

A Study on the Over-current Characteristics of IV Insulated Wire Sheath According to Accelerated Degradation (가속열화에 따른 IV절연전선 피복의 과전류 특성에 관한 연구)

  • Kim, Si-Kuk;Choi, Su-Gil
    • Fire Science and Engineering
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    • v.32 no.2
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    • pp.48-56
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    • 2018
  • This paper reports the results of a study on the over-current characteristics of IV insulated wire sheath according to accelerated degradation. In order to examine the degradation of a IV insulated wire sheath through insulation, acceleration degradation experiments were performed using the Arrhenius equation of acceleration life test models; test samples with equivalent lives of 0, 10, 20, 30 and 40 years were prepared. Then allowed currents with over-current of 100%~500% were introduced to measure the times of first generation of smokes and carbonization in the wire sheath, and it was found that the times of first generation of smokes and carbonization in the wire sheath decreased as the equivalent life increased. In more detail, when 270% over-current is applied, the electrical fire risk of equivalent life of 40 years increased by approximately 3.2 times based on equivalent life of 0 years. Also, when the over-current was 255% and 260%, carbonization occurred only in the equivalent life of 40 years, and the fire risk according to the accelerated degradation was increased dramatically. In addition, FT-IR and SEM analyzes were used to confirm the characteristics and surface changes of IV insulated wire sheath according to the equivalent life.

A Study on the Performance Change of Insulation Sheath Due to Accelerated Degradation of IV and HIV Insulated Wire (IV 및 HIV 절연전선의 가속열화에 따른 절연피복의 성능변화에 관한 연구)

  • Choi, Su-Gil;Kim, Si-Kuk
    • Fire Science and Engineering
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    • v.33 no.2
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    • pp.114-123
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    • 2019
  • The paper relates to a study on the changes in performance of insulation sheath resulting from accelerated degradation of IV and HIV insulated wire. To assume insulation degradation of IV and HIV insulated wire, accelerated life tests using Arrhenius equation were conducted among accelerated life test models, and experimental samples of 0 year, 10 years, 20 years, 30 years, and 40 years in equivalent life were produced. Whereas the maximum tensile load were increased as accelerated degradation of IV and HIV insulated wire progressed, elongation percentage, rupture time, and flexibility of insulated wires were found to be gradually reduced. According to the additional surface analysis results for the insulated wires per equivalent life using a scanning electron microscope, mechanical properties of the insulator were observed to be reduced as insulation degradation resulting from aging progressed since phenomena such as formation of crystalline structures and perforation, etc. occurred on the sample surface with progression of accelerated degradation. Consequently, institutional replacement of insulated wires and preparation of repair times considering performance degradation of the insulator installed inside buildings are considered necessary in order to prevent in advance the risks of electrical fire resulting from degradation in insulation performance.