• 제목/요약/키워드: Shift Effect(SE)

검색결과 37건 처리시간 0.033초

Tailoring the Excited-State Intramolecular Proton Transfer (ESIPT) Fluorescence of 2-(2'-Hydroxyphenyl)benzoxazole Derivatives

  • Seo, Jang-Won;Kim, Se-Hoon;Park, Sang-Hyuk;Park, Soo-Young
    • Bulletin of the Korean Chemical Society
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    • 제26권11호
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    • pp.1706-1710
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    • 2005
  • The excited-state intramolecular proton transfer (ESIPT) fluorescence in the 2-(2'-hydroxyphenyl)benzoxazole (HBO) derivatives with different electron donor and acceptor substituents was studied by spectroscopic and theoretical methods. Changes in the electronic transition, energy levels, and orbital diagrams of HBO analogues were investigated by the semi-empirical molecular orbital calculation and were correlated with the experimental spectral position of ESIPT keto emission. It was found that the presence of substituents, regardless of their nature, resulted in the red-shifted absorption relative to HBO. However, the spectral change of the ESIPT fluorescence was differently affected by the nature of substituent: hypsochromic shift with electron donor and bathochromic shift with electron acceptor.

PPS 제어기법을 적용한 48V-400V 비절연 양방향 DC-DC컨버터 (A 48V-400V Non-isolated Bidirectional Soft-switching DC-DC Converter for Residential ESS)

  • 정현주;권민호;최세완
    • 전력전자학회논문지
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    • 제23권3호
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    • pp.190-198
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    • 2018
  • This paper proposes a nonisolated, bidirectional, soft-switching DC - DC converter with PWM plus phase shift (PPS) control. The proposed converter has an input-parallel/output-series configuration and can achieve the interleaving effect and high voltage gains, resulting in decreased voltage ratings in all related devices. The proposed converter can operate under zero-voltage switching (ZVS) conditions for all switches in continuous conduction mode. The power flow of the proposed converter can be controlled by changing the phase shift angle, and the duty is controlled to balance the voltage of four high voltage side capacitors. The PPS control device of the proposed converter is simple in structure and presents symmetrical switching patterns under a bidirectional power flow. The PPS control also ensures ZVS during charging and discharging at all loads and equalizes the voltage ratings of the output capacitors and switches. To verify the validity of the proposed converter, an experimental investigation of a 2 kW prototype is performed in both charging and discharging modes under different load conditions and a bidirectional power flow.

광노출에 따른 Ag도핑 메카니즘 해석 (The analysis of Ag doping mechanism by photo-exposure)

  • 이현용;김민수;정홍배
    • E2M - 전기 전자와 첨단 소재
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    • 제8권4호
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    • pp.472-477
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    • 1995
  • The degree of the photodoping process in Ag(100[.angs.])/a-Se$_{75}$Ge$_{25}$(1500[.angs.]) films has measured as a function of the photon energy between 1.5[eV] and 2.9[eV] with the exposing time. The "window" characteristics of Ag occur at 3400[.angs.] (3.65[eV]) and Ag is almost transparent in this region. It is shown that transmittance is almost constant (40-50%) for the wavelength ranges of our experiment. It is found that the energy gap of a unexposed a-Se$_{75}$Ge$_{25}$ film is 1.81[eV]. Ag photodoping process results in the photodarkening effect which the absorption edge shifts to the long wavelength. Especially, very large band shift (-0.3[eV]) is obtained by exposing He-Ne laser(6328[.angs.]).. We have obtained "the U-type property" for Ar He-Ne and semiconductor laser. It is associated with the variation of energy gap(E$_{g}$) with photo-dose and substantially is explained by DWP model.l.gap(E$_{g}$) with photo-dose and substantially is explained by DWP model.

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The Effect of Spent Medium Recycle on Cell Proliferation, Metabolism and Baculovirus Production by the Lepidopteran Se301 Cell Line Infected at Very Low MOI

  • Beas-Catena, Alba;Sanchez-Miron, Asterio;Garcia-Camacho, Francisco;Contreras-Gomez, Antonio;Molina-Grima, Emilio
    • Journal of Microbiology and Biotechnology
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    • 제23권12호
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    • pp.1747-1756
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    • 2013
  • The aim of this paper was to study the effect of spent medium recycle on Spodoptera exigua Se301 cell line proliferation, metabolism, and baculovirus production when grown in batch suspension cultures in Ex-Cell 420 serum-free medium. The results showed that the recycle of 20% of spent medium from a culture in mid-exponential growth phase improved growth relative to a control culture grown in fresh medium. Although both glucose and glutamine were still present at the end of the growth phase, glutamate was always completely exhausted. The pattern of the specific glucose and lactate consumption and production rates, as well as the specific glutamine and glutamate consumption rates, suggests a metabolic shift at spent medium recycle values of over 60%, with a decrease in the efficiency of glucose utilization and an increase in glutamate consumption to fuel energy metabolism. Baculovirus infection provoked a change in the metabolic pattern of Se301 cells, although a beneficial effect of spent medium recycle was also observed. Both growth rate and maximum viable cell density decreased relative to uninfected cultures. The efficiency of glucose utilization was dramatically reduced in those cultures containing the lowest percentages of spent medium, whereas glutamine and glutamate consumption was modulated, thereby suggesting that infected cells were devoted to virus replication, retaining their ability to incorporate the nutrients required to support viral replication. Recycle of 20% of spent medium increased baculovirus production by around 90%, thus showing the link between cell growth and baculovirus production.

비정질 칼코게나이드박막으로서의 Ag 도핑효과에 대한 U-형 모델 (The U-type Model on Ag Doping effect in Amorphous Chalcogenide thin films)

  • 김민수;이현용;정홍배
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1995년도 춘계학술대회 논문집
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    • pp.50-53
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    • 1995
  • In this paper we have obtained property by considering the change of optical energy gap as a function of photo-does for exposing photo on Ag/a-Se$\sub$75/Ge$\sub$25/ thin films. This U-type property was obsered for all photo-exposing except for blu-pass filtered Hg lamep. Expecially, very large band shift(~0.3[eV]) is obtained by exposing He-Ne laser (6328[${\AA}$]). It is impossible to explain this property for exposing He-Ne and semiconductor laser through DWP model, which was explained for photo-exposing above the energy gap. Therefore we suggest a new modified model of DWP model for Ag/a-Se$\sub$75/Ge$\sub$25/ bilayer thin films.

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전이할당 분석을 이용한 한중카페리 항만의 구조분석에 관한 연구 -인천항을 중심으로- (Structural Analysis for Ports of Korea-China Car Ferry using Shift Effect Method - Focusing on Incheon Port)

  • 이진규;여기태
    • 한국항만경제학회지
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    • 제30권3호
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    • pp.39-58
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    • 2014
  • 우리나라와 중국은 1993년 5월에 체결된 한중 해운회담을 통해 양국간 안정적인 항로 관리를 수행하고 있다. 이러한 노력에 기인하여 한중카페리 시장은 황해를 중심으로 한 거대시장으로 성장했으며 그 수요 또한 지속적으로 증가하고 있다. 하지만 카페리 사업은 지역 및 국가 경제에 미치는 파급효과가 크며 항로 간 경쟁이 치열하다. 이러한 측면에서 본 연구는 전이할당 분석을 이용하여 한중카페리 항만의 구조분석을 수행하는 것을 연구의 목적으로 하였다. 분석결과 인천항은 지속적으로 평택 당진항과 군산항에 여객과 화물 물동량이 전이된 것으로 나타났다. 또한 인천항의 절대성장치가 잠재성장치에 크게 못 미치는 것으로 나타나 평택 당진항과 군산항과의 경쟁에서 열세임을 확인할 수 있었다. 또한 서해안 권역의 물동량은 지속적으로 증가추세에 있으나 인천항의 여객과 화물 물동량은 그 성장률을 밑돌고 있다. 향후 인천항의 경우, 군산항과 평택 당진항과 경쟁에서 우위를 점하려면 단기적으로는 항만 마케팅을 통해 여객과 화물을 유치해야 하며, 장기적으로는 카페리운송의 장점인 통관의 신속성과 운항속도의 장점을 극대화 시켜 고부가가치 화물을 유치하고 항만을 특화할 필요가 있다.

Short Channel GaAs MESFET의 채널전하분포와 채널전하에 의한 전위장벽의 변화 (Potential Barrier Shift Caused by Channel Charge in Short Channel GaAs MESFET)

  • 원창섭;이명수;류세환;한득영;안형근
    • 한국전기전자재료학회논문지
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    • 제19권9호
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    • pp.793-799
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    • 2006
  • In this paper, the gate leakage current is first calculated using the experimental method between gate and drain by opening source electrode. the gate to drain current has been obtained with ground source. The difference between two currents has been tested and proves that the electric field generated by channel charge effect against the image force lowering.

Injection 온도 및 합성시간에 따른 CdSe 양자점 합성 및 특성 (Synthesis and Characterization of CdSe Quantum Dot with Injection Temperature and Reaction Time)

  • 엄누시아;김택수;좌용호;김범성
    • 한국재료학회지
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    • 제22권3호
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    • pp.140-144
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    • 2012
  • Compared with bulk material, quantum dots have received increasing attention due to their fascinating physical properties, including optical and electronic properties, which are due to the quantum confinement effect. Especially, Luminescent CdSe quantum dots have been highly investigated due to their tunable size-dependent photoluminescence across the visible spectrum. They are of great interest for technical applications such as light-emitting devices, lasers, and fluorescent labels. In particular, quantum dot-based light-emitting diodes emit high luminance. Quantum dots have very high luminescence properties because of their absorption coefficient and quantum efficiency, which are higher than those of typical dyes. CdSe quantum dots were synthesized as a function of the synthesis time and synthesis temperature. The photoluminescence properties were found strongly to depend on the reaction time and the temperature due to the core size changing. It was also observed that the photoluminescence intensity is decreased with the synthesis time due to the temperature dependence of the band gap. The wavelength of the synthesized quantum dots was about 550-700 nm and the intensity of the photoluminescence increased about 22~70%. After the CdSe quantum dots were synthesized, the particles were found to have grown until reaching a saturated concentration as time increased. Red shift occurred because of the particle growth. The microstructure and phase developments were measured by transmission electron microscopy (TEM) and X-ray diffractometry (XRD), respectively.

스마트폰 환경하의 실시간 처리를 위한 가변 탐색영역을 이용한 마커 추적 방법 (Realtime Processing for Marker Tracking in Smart-Phone Environment Using Deformable Searching Area)

  • 김세훈;임성준;이민호;김계영;최형일
    • 한국HCI학회:학술대회논문집
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    • 한국HCI학회 2009년도 학술대회
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    • pp.542-546
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    • 2009
  • 모바일상의 혼합현실 기반의 소프트웨어 기술은 현재 국내외적으로 시작 단계에 있다. 하지만 급속한 모바일 인터넷 인프라의 확산, 모바일 기기의 성능 향상 및 개방형 모바일 OS의 등장으로 인해 모바일 혼합현실과 같은 새로운 융합형 IT기술이 사용자의 요구에 부흥하여, 수요가 급신장 되고 있다. 모바일 혼합현실 기반 기술 중 하나인 마커의 검출과 추적은 혼합현실의 가장 기본이며 매우 중요한 과정이다. 본 논문에서는 낮은 CPU를 이용하는 모바일 환경에 최적화된 실시간 마커 추적 방법에 대하여 제안한다. 낮은 CPU의 처리속도를 보완하기 위하여 처리영역을 축소하여 가변 탐색영역내의 공간에서 처리를 수행하고, 좌표변환정보를 이용하여 추적을 수행하는 캘리브레이션 과정을 대신하여 캠 시프트 알고리즘을 이용하여 효과적인 추적 방법을 제안한다.

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Effect of carrier concentration of ITO films on Quantum Efficiency Window in Heterojunction Silicon Solar Cells

  • Kim, Hyunsung;Kim, Sangho;Yi, Junsin
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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    • pp.314-314
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    • 2016
  • In this paper, the effects of carrier concentration on dielectric constant of ITO films were investigated by spectroscopic ellipsometry. From SE results, we find the pronounced shift of the ${\varepsilon}1$ peaks toward high energy with concentration; while contrarily, the ${\varepsilon}2$ values at low energy region increases with decreasing concentration. These shifts are attributed to the Burstein-Moss and free-carrier absorption effects within ITO films. With increases carrier concentration, the values of extinction coefficients show quite different behaviors in range of wavelength from 200 to 1200 nm. The reduction in k at ${\lambda}{\leq}500nm$, while increasing at ${\lambda}{\geq}500nm$ was observed. The QE of HJ solar cells behaviors can be roughly classified into two regions: short-wavelengths (${\leq}650nm$) and long-wavelengths region (${\geq}650nm$). With increasing carrier concentration as well as energy band gap, QE shows improvement at short-wavelength, while at long-wavelength QE shows opposite trend. Widening band gap energy due to Burstein-Moss shift is the key to improve QE in short-wavelength; simultaneously FCA effect due to optical scattering is attributed to the reduction in QE at long-wavelength. In spite of band gap extension, Jsc calculated from QE decreases from 34.7 mA/cm2 to 33.2 mA/cm2 with increasing carrier concentration. It demonstrated that FCA effect may more govern Jsc in the HJ solar cells.

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