• Title/Summary/Keyword: Shift Effect(SE)

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The optical characteristics of amorphous $Se_{75}Ge_{25}$ thin film by the low-energy lon beam exposure (저 에너지 이온빔 조사에 따른 비정질 $Se_{75}Ge_{25}$ 박막의 광학적 특성)

  • 이현용;오연한;정홍배
    • Electrical & Electronic Materials
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    • v.7 no.2
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    • pp.100-106
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    • 1994
  • A bilayer film consisting of a layer of a-Se$_{75}$ Ge$_{25}$ with a surface layer of silver -100[.angs.] thick and a monolayer film of a-Se$_{75}$ Ge$_{25}$ are irradiated with 9[keV] Ga$^{+}$ ion beam. The Ga$^{+}$ ion (10$^{16}$ [ions/cm$^{2}$] exposed a-Se$_{75}$ Ge$_{25}$ and Ag/a-Se$_{75}$ Ge$_{25}$ thin films show an increase in optical absorption, and the absorption edge on irradiation with shifts toward longer wavelength. The shift toward longer wavelength called a "darkening effect" is observed also in film exposure to optical radiation(4.5*10$^{20}$ [photons/cm$^{2}$]). The 0.3[eV] edge shift for ion irradiation films is about twice to that obtained on irradiation with photons. These large changes are primarily due to structural changes, which lead to high etch selectivity and high sensitivity.

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A Study on the Properties of Fe-Se-Te System (Fe-Se-Te계의 특성 연구)

  • Choe, Seung-Han
    • Korean Journal of Materials Research
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    • v.9 no.8
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    • pp.854-857
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    • 1999
  • The properties of Fe-Se-Te system(FeSe(sub)1-xTe(sub)x, x=0.2, 0.5, 0.8) have been studied by means of the X-ray diffraction method and Mossbauer spectroscopy. The results of X-ray diffraction patterns show that three samples have the ixed structure of tetragonal PbO and a small amount of hexagonal NiAs structure respectively. For x=0.5 the lattice parameters of tetragonal PbO structure are a=3.795$\AA$, c=5.896$\AA$ and c/a=1.55. The Mossbauer spectra were obtained with the various temperature variation and than they do not exhibit magnetic hyperfine structure but show a strong doublet. The values of observed isomer shift and quadrupole splitting suggest that the irons of all samples exist in the +2 oxidation state with a major covalent contribution. The temperature dependence of isomer shift values for x=0.8 seems to be originated from the second order Doppler effect.

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Luminescent Characteristics of CdSe Quantum Dot Phosphor Depending on Se Precursor Ratio (Se 전구체 함량 따른 CdSe 양자점 형광체의 발광특성)

  • Eom, Nu Si A;Kim, Taek-Soo;Choa, Yong-Ho;Kim, Bum Sung
    • Journal of Powder Materials
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    • v.19 no.6
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    • pp.442-445
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    • 2012
  • The quantum dots (QD) have unique electrical and optical properties due to quantum dot confinement effect. The optical properties of QDs are decided by various synthesis conditions. In a prior QDs study, a study on the QDs size with synthesis condition such as synthesis time and temperature is being extensively researched. However, the research on QDs size with composition ratio has hitherto received scant attention. In order to evaluate the ratio dependence of CdSe crystal, synthesis ratio of Se precursor is changed from 16.7 mol%Se to 44 mol%Se. As the increasing Se ratio, the band gap was increased. This is caused by red shift of emission. We confirmed optical property of CdSe QDs with composition ratio.

The Photoluminescence(PL) Spectroscopy and the Photo-Darkening(PD) Effect of the Amorphous SeGe Thin Films (비정질 SeGe 박막의 PL 특성과 광흑화 효과에 관한 연구)

  • 김진우;이현용;정홍배
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.5
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    • pp.435-440
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    • 2002
  • In this study, we have investigated photo-induced changes of optical energy gap( $E_{OP)}$ and photoluminescence (PL) in amorphous ($\alpha$-) S $e_{100-x}$G $e_{x}$ (x=5, 25 and 33) thin films prepared by conventional thermal evaporation method. In the $\alpha$-S $e_{100-x}$G $e_{x}$ thin film, the $E_{OP}$ is obtained by a linear extrapolation of the ($\alpha$hν)$^{\frac{1}{2}}$ versus hν plot to the energy axis using the optical absorption coefficient ($\alpha$) calculated from the extinction coefficient k measured in the wavelength range of 290~900nm. Although the values of $\Delta$ $E_{OP}$ are very different, all films exhibit photo-induced photo-darkening (PD) effect that is a red shift of $E_{OP}$ . In particular, $\Delta$ $E_{OP}$ in $\alpha$-S $e_{75}$ G $e_{25}$ thin film exhibits the largest value (i, e., $\Delta$ $E^{OP}$ ~40meV for $\alpha$-S $e_{95}$ G $e_{5}$ , $\Delta$ $E_{OP}$ ~200meV for $\alpha$-S $e_{75}$ G $e_{25}$ , $\Delta$ $E_{OP}$ ~130meV for $\alpha$-S $e_{67}$ G $e_{33}$ ). PL spectra in $\alpha$-SeGe by hν$_{HeCd}$ have no-Stokes shift (SS) and show a tendency dependent on both composition and illumination time. We explain the energy-induced phenomena such as the PD and thermal bleaching, the native charged-defect generation and the no-SS PL, etc..the PD and thermal bleaching, the native charged-defect generation and the no-SS PL, etc..tc..

Annealing Effects on $Zn_{0.9}Cd_{0.1}$/Se/ZnSe Strained Single Quantum Well (Zn_{0.9}Cd_{0.1}/ZnSe 변형된 단일 양자우물구조의 열처리 효과)

  • 김동렬;배인호;손정식
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.13 no.6
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    • pp.467-471
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    • 2000
  • The thermal annealing effect of $Zn_{0.9}Cd_{0.1}$ single quantum-well structures grown by molecular beam epitaxy is investigated. As the results of before and after rapid thermal annealed samples a red shift of E1-HH1 peak by Cd interdiffusion during thermal annealing of ZnCeSe/ZnSe sample was observed. In the case of annealed sample over $450^{\circ}C$ donor and acceptor impurities related peaks were observed which seems to be due to a diffusion of Ga and As from GaAs substrate. And also interdiffusion phenomena is idenified by the results of DCX measurements and which are consisten with the PL measurements.

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Optical Characteristics of CdSe/ZnS Quantum Dot with Precursor Flow Rate Synthesized by using Microreactor (마이크로리액터를 이용한 전구체 유속에 따른 CdSe/ZnS 양자점의 광학특성)

  • Park, Ji Young;Jeong, Da-Woon;Ju, Won;Seo, Han Wook;Cho, Yong-Ho;Kim, Bum Sung
    • Journal of Powder Materials
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    • v.23 no.2
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    • pp.91-94
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    • 2016
  • High-quality colloidal CdSe/ZnS (core/shell) is synthesized using a continuous microreactor. The particle size of the synthesized quantum dots (QDs) is a function of the precursor flow rate; as the precursor flow rate increases, the size of the QDs decreases and the band gap energy increases. The photoluminescence properties are found to depend strongly on the flow rate of the CdSe precursor owing to the change in the core size. In addition, a gradual shift in the maximum luminescent wave (${\lambda}_{max}$) to shorter wavelengths (blue shift) is found owing to the decrease in the QD size in accordance with the quantum confinement effect. The ZnS shell decreases the surface defect concentration of CdSe. It also lowers the thermal energy dissipation by increasing the concentration of recombination. Thus, a relatively high emission and quantum yield occur because of an increase in the optical energy emitted at equal concentration. In addition, the maximum quantum yield is derived for process conditions of 0.35 ml/min and is related to the optimum thickness of the shell material.

Design of Linear Synchronous Motor for Thrust Force Ripple Reduction using Module Phase Set Shift (Module Phase Set Shift를 이용한 선형 동기 전동기의 추력 리플 저감 설계)

  • Ryu, Gwang-Hyeon;Lee, Hyung-Woo;Cho, Su-Yeon;Oh, Se-Young;Ham, Sang-Hwan;Im, Jong-Bin;Ahn, Han-Woong;Lee, Ju
    • Proceedings of the KIEE Conference
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    • 2011.07a
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    • pp.848-849
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    • 2011
  • Rotating machines are using gears to change the rotary motion into the linear motion, on the other hand, linear motors have a accurate position control and excellent dynamic characteristics because of generating a thrust force directly. But the important problem, one of the linear motor is a high thrust force ripple. Thrust force ripple has a bad effect on the position accuracy and the dynamic characteristics, so it is necessary to reduce the thrust force ripple. Cogging is one of the cause that affect thrust force ripple. Cogging has some connection with the GCD between pole pitch and teeth pitch It is proposed method to reduce a thrust ripple of the linear motor that chamfering, skew, and so on. In this paper, the module phase set shift(MPSS) is used to reduce a thrust force ripple that has a similar effect to skew. And propose a method that reduce a thrust force ripple more by use of chamfering.

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Tanner Graph Based Low Complexity Cycle Search Algorithm for Design of Block LDPC Codes (블록 저밀도 패리티 검사 부호 설계를 위한 테너 그래프 기반의 저복잡도 순환 주기 탐색 알고리즘)

  • Myung, Se Chang;Jeon, Ki Jun;Ko, Byung Hoon;Lee, Seong Ro;Kim, Kwang Soon
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.39C no.8
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    • pp.637-642
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    • 2014
  • In this paper, we propose a efficient shift index searching algorithm for design of the block LDPC codes. It is combined with the message-passing based cycle search algorithm and ACE algorithm. We can determine the shift indices by ordering of priority factors which are effect on the LDPC code performance. Using this algorithm, we can construct the LDPC codes with low complexity compare to trellis-based search algorithm and save the memory for storing the parity check matrix.

Ag/a-$Se_{75}Ge_{25}$ 박막의 Ag Doping Mechanism 해석[ll]-Ag 도핑의 광에너지 의존성

  • 김민수;이현용;정홍배;이영종
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1994.11a
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    • pp.187-189
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    • 1994
  • The degree of the photodoping process in Ag(100 )/a-$Se_{75}Ge_{25}$(2000 ) films has been measured as a funcition of photon energy between 1.5eV and 2.9eV with the exposing time. The window of Ag occurs at 3400 (3.65eV) and Ag is almost transparent in this region. It was shown that transmitance is always constant (40∼50%) for the wavelength ranges of our experiment. It was found that the energy gap of a unexposed a-$Se_{75}Ge_{25}$ film is 1.81eV. Ag photodoping process result in the photodarkenting effect which the absorption edge shift to the large wavelength. Especially, we could obtain very large band shut ( ∼0.3eV) resulting in exposing He-Ne laser(6328[ ]). From the result of our experimental, we suggest that Ag photodoping process depends on the photon absorption in Ag.

High Crystalline Epitaxial Bi2Se3 Film on Metal and Semiconductor Substrates

  • Jeon, Jeong-Heum;Jang, Won-Jun;Yun, Jong-Geon;Gang, Se-Jong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.302-302
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    • 2011
  • The binary chalcogenide semiconductor Bi2Se3 is at the center of intensive research on a new state of matter known as topological insulators. It has Dirac point in their band structures with robust surface states that are protected against external perturbations by strong spin-orbit coupling with broken inversion symmetry. Such unique band configurations were confirmed by recent angle-resolved photoelectron emission spectroscopy experiments with an unwanted n-type doping effect, showing a Fermi level shift of about 0.3 eV caused by atomic defects such as Se vacancies. Since the number of defects can be reduced using the molecular beam epitaxy (MBE) method. We have prepared the Bi2Se3 film on noble metal Au(111) and semiconductor Si(111) substrates by MBE method. To characterize the film, we have introduced several surface sensitive techniques including x-ray photoemission electron spectroscopy (XPS) and micro Raman spectroscopy. Also, crystallinity of the film has been confirmed by x-ray diffraction (XRD). Using home-built scanning tunneling microscope, we observed the atomic structure of quintuple layered Bi2Se3 film on Au(111).

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