• Title/Summary/Keyword: Semi-Permeability

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Effect of spinning parameters of polyethersulfone based hollow fiber membranes on morphological and mechanical properties

  • Tewfik, Shadia R.;Sorour, Mohamed H.;Shaalan, Hayam F.;Hani, Heba A.
    • Membrane and Water Treatment
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    • v.9 no.1
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    • pp.43-51
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    • 2018
  • Hollow fiber (HF) membranes are gaining wide interest over flat membranes due to their compaction and high area to surface volume ratio. This work addresses the fabrication of HF from polysulfone (PS) and polyethersulfone (PES) using N-methylpyrrolidone (NMP) as solvent in addition to other additives to achieve desired characteristics. The semi-pilot spinning system includes jacketed vessel, four spinneret block, coagulation and washing baths in addition to dryer and winder. Different parameters affecting dry-wet spinning phase inversion process were investigated. Dope compositions of PES, NMP and polyvinyl pyrrolidone (PVP) of varying molecular weights as additive were addressed. Some critical parameters of importance were also investigated. Those include dope flow rate, air gap, coagulation & washing baths and drying temperatures. The measured dope viscosity was in the range from 1.7 to 36.5 Pa.s. Air gap distance was adjusted from 20 to 45 cm and coagulation bath temperature from 20 to $46^{\circ}C$. The HF membranes were characterized by scanning electron microscope (SEM), atomic force microscope (AFM) and mechanical properties. Results indicated prevalence of finger like structure and average surface roughness from about 29 to 78.3 nm. Profile of stress strain characteristics revealed suitability of the fibers for downstream interventions for fabrication of thin film composite membrane. Different empirical correlations were formulated which enable deeper understanding of the interaction of the above mentioned variables. Data of pure water permeability (PWP) confirmed that the fabricated samples fall within the microfiltration (MF)-ultrafiltration (UF) range of membrane separation.

Semi-Rational Screening of Probiotics from the Fecal Flora of Healthy Adults against DSS-Induced Colitis Mice by Enhancing Anti-Inflammatory Activity and Modulating the Gut Microbiota

  • Wang, Weiwei;Xing, Wentao;Wei, Sichen;Gao, Qiaoying;Wei, Xinliang;Shi, Liang;Kong, Yu;Su, Zhenhua
    • Journal of Microbiology and Biotechnology
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    • v.29 no.9
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    • pp.1478-1487
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    • 2019
  • Ulcerative colitis (UC), a chronic inflammatory bowel disease, substantially impacts patients' health-related quality of life. In this study, an effective strategy for discovering high-efficiency probiotics has been developed. First, in order to survive in the conditions of the stomach and intestine, high bile salt-resistant and strong acid-resistant strains were screened out from the fecal flora of healthy adults. Next, the probiotic candidates were rescreened by examining the induction ability of IL-10 (anti-inflammatory factor) production in dextran sodium sulfate (DSS)-induced colitis mice, and Lactobacillus sakei 07 (L07) was identified and selected as probiotic P. In the end, fourteen bifidobacterium strains isolated from stools of healthy males were examined for their antimicrobial activity. Bifidobacterium bifidum B10 (73.75% inhibition rate) was selected as probiotic B. Moreover, the colonic IL-6 and $TNF-{\alpha}$ expression of the DSS-induced colitis mice treated with L. sakei 07 (L07) - B. bifidum B10 combination (PB) significantly decreased and the IL-10 expression was up-regulated by PB compared to the DSS group. Furthermore, Bacteroidetes and Actinobacteria decreased and Firmicutes increased in the DSS group mice, significantly. More interestingly, the intestinal flora biodiversity of DSS colitis mice was increased by PB. Of those, the level of B. bifidum increased significantly. The Bacteriodetes/Firmicutes (B/F) ratio increased, and the concentration of homocysteine and LPS in plasma was down-regulated by PB in the DSS-induced colitis mice. Upon administration of PB, the intestinal permeability of the the DSS-induced colitis mice was decreased by approximately 2.01-fold. This method is expected to be used in high-throughput screening of the probiotics against colitis. In addition, the L. sakei 07 - B. bifidum B10 combination holds potential in UC remission by immunomodulatory and gut microbiota modulation.

Separation Purification Characteristics of Rinsing Solution in Semiconductor Process using Bigh Performance Polymer Membranes ( I ) (기능성 고분자막을 이용한 반도체 공정 세정액의 분리정제특성 (I))

  • Lee Jae-Dal;Hong Young-Ki;Ro Duck-Kil;Bae Kie-Seo
    • Textile Coloration and Finishing
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    • v.17 no.3 s.82
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    • pp.34-42
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    • 2005
  • In this work, a practical separation performance was investigated on aqueous alcohol solutions, especially for iso-propyl alcohol (IPA), which is usually used during the semi- conductor rinsing process. The removal of various substances from waste aqueous IPA solutions was carried out by microfiltration with $0.1\~1{\mu}$m pore size of mean diameter as a pre-filter. Permeability and molecular weight cut-off of the functional polysulfone(PSf) ultrafiltration membrane to purify waste aqueous IPA solutions were measured through the ultrafiltration test. The solute rejection of PSf membrane had $92\%$ in 1,000ppm aqueous PEG solution with PEG molecular weight 10,000, the molecular weight cut-off had 10,000. The IPA concentration on the $CMPA-K^+$ membrane performance using pervaporation module system could be increased from $95.04 wt\%$ to more than $98.50wt\%$ in about 9hr at operation temperature of $70^{\circ}C$ using the pervaporation module system.

A Study on the Semiconductor Wastewater Treatment and Recycling by VSEP system (진동막분리장치에 의한 반도체폐수처리와 재이용에 관한 연구)

  • Kang Gyung-Hwan
    • Journal of Environmental Science International
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    • v.14 no.3
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    • pp.335-343
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    • 2005
  • The objective of this research is to evaluate a feasibility of wastewater reuse by membrane treatment with vibrating membrane separation equipment. Molecular weight of compounds in wastewater, permeability of membrane and retentate characterization after membrane filtration were investigated in order to determine appropriate membrane pore size and materials for wastewater treatment. Selected membrane was evaluated with vibration membrane separation equipment to optimize operating conditions. The following conclusion are drawn. 1. We got as following test results after the distribution of particles in the semiconductor wastewater, are made up of $1\~20{\mu}m$. Si, gold and Al in turn are contained in semiconductor wastewater. 2. Recovery rate is changeless under increasing recovery rate in operation. Though a value can be if pressure can be changed, the highest value of permeate rate is presented in 150 psi. 3. The AS-100(polysulpone) was selected as the most appropriate membranes for the treatment of semi-conductor wastewater to VSEP system. The fouling almost did not occur during this experiments. The analyses of treated water with VSEP system showed conductivity: 0.059,us/cm, TDS: 40mg/l, COD: 20mg/l, SS : 5mg/l, n-Hexane: 8.3mg/l. Comparing previous systems, operating expenses is decreased by more $50\%$.

Televiewer에서 관찰되는 단열특성과 수리전도도와의 상관관계 분석

  • Park Gyeong-U;Bae Dae-Seok;Kim Gyeong-Su;Go Yong-Gwon
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2005.04a
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    • pp.284-287
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    • 2005
  • The flow of groundwater in fractured medium is related to the geometric characteristics of the fracture system. And a fracture aperture and a fracture density are considered as important factor concerning the permeability. Data acquisition of the properties of fracture such as aperture and density is so difficult and has uncertainty. We also cannot know the fracture characteristics through the in-situ tests. We usually obtain the fracture information from a ultrasonic scan logging or borehole television indirectly. Using the deduced results, we can make the fracture system and simulate the groundwater flow and solute transport in the crystalline rock. This study aimed to analyze the correlation between the properties of fracture and hydraulic conductivities obtained at the same interval. The properties of fracture are examined by acoustic televiwer and hydraulic conductivities are obtained by constant Pressure injection test. The distributioin of fracture width and fracture frequency shows the log-normal probability plot. And, Results of correlation analysis explain that opened type fractures have proper relation with hydraulic conductivity. But, as though there are semi-opened type fractures or closed type fractures, those have the permeable structure.

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Effect of post-treatment routes on the performance of PVDF-TEOS hollow fiber membranes

  • Shadia R. Tewfik;Mohamed H. Sorour;Hayam F. Shaalan;Heba A. Hani;Abdelghani G. Abulnour;Marwa M. El Sayed;Yomna O. Mostafa;Mahmoud A. Eltoukhy
    • Membrane and Water Treatment
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    • v.14 no.2
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    • pp.85-93
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    • 2023
  • Membrane separation is widely used for several applications such as water treatment, membrane reactors and climate change. Cross-linked organic-inorganic hybrid polyvinylidene fluoride (PVDF) / Tetraethyl orthosilicate (TEOS) was adopted for the preparation of optimized hollow membrane (HFM) for membrane distillation or other low pressure separators for mechanical properties and permeability under varying pretreatment schemes. HFMs were prepared on semi-pilot membrane fabrication system. Novel adopted post-treatment schemes involved soaking in glycerol, magnesium sulphate (MgSO4), sodium hypochlorite (NaOCl), and isopropanol for different durations. All fibers were characterized for morphology using a scanning electron microscope (SEM), surface roughness using atomic force microscope (AFM), elemental composition by examining Energy Dispersive Spectroscopy (EDS), water contact angle (CA°) and porosity. The performance of the fibers was evaluated for pure water permeation flux (PWF). Post-treatment with MgSO4 gave the highest both tensile modulus and flux. Assessment of properties and performance revealed comparable results with other organic-inorganic separators, HF or flat. In spite of few reported data on post treatment using MgSO4 in presence of TEOS, this proves the potential of low cost treatment without negative impact on other membrane properties. The flux is also comparable with hypochlorite which manifests substantial precaution requirements in actual industrial use.The relatively high values of flux/bar for sample treated with TEOS, post treated with MgSO4 and hypochlorite are 88 and 82 LMH/bar respectively.

Enhanced Bioslurping System for Remediation of Petroleum Contaminated Soils (Enhanced Bioslurping system을 이용한 유류오염 토양의 복원)

  • Kim Dae-Eun;Seo Seung-Won;Kim Min-Kyoung;Kong Sung-Ho
    • Journal of Soil and Groundwater Environment
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    • v.10 no.2
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    • pp.35-43
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    • 2005
  • Bioslurping combines the three remedial approaches of bioventing, vacuum-enhanced free-product recovery, and soil vapor extraction. Bioslurping is less effective in tight (low-permeability) soils. The greatest limitation to air permeability is excessive soil moisture. Optimum soil moisture is very soil-specific. Too much moisture can reduce air permeability of the soil and decrease its oxygen transfer capability. Too little moisture will inhibit microbial activity. So Modified Fenton reaction as chemical treatment which can overcome the weakness of Bioslurping was experimented for simultaneous treatment. Although the diesel removal efficiency of SVE process increased in proportion to applied vacuum pressure, SVE process was difficulty to remediation quickly semi- or non-volatile compounds absorbed soil strongly. And SVE process had variation of efficiency with distance from the extraction well and depth a air flow form of hemisphere centering around the well. Below 0.1 % hydrogen peroxide shows the potential of using hydrogen peroxide as oxygen source but the co-oxidation of chemical and biological treatment was impossible because of the low efficiency of Modified Fenton reaction at 0.1 % (wt) hydrogen peroxide. NTA was more efficiency than EDTA as chelating agent and diesel removal efficiency of Modified Fenton reaction increased in proportion to hydrogen peroxide concentration. Hexadecane as typical aliphatic compound was removed less than Toluene as aromatic compound because of its structural stability in Modified Fenton reaction. What minimum 10% hydrogen peroxide concentration has good remediation efficiency of diesel contaminated groundwater may show the potential use of Modified Fenton reaction after bioslurping treatment.

A Study on Compression Paddle Materials to Reduce Radiation Exposure Dose During Mammography; PC and PMMA and Carbon (유방촬영 시 피폭선량을 줄이기 위한 압박대 재질의 PC, PMMA, Carbon에 대한 연구)

  • Hong, Dong-Hee;Jung, Hong-Ryang
    • Journal of radiological science and technology
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    • v.38 no.2
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    • pp.81-87
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    • 2015
  • This study was designed the band material in order to reduce the exposure pressure of the breast and the material was measured of Radiolucent and radiation properties with a radiation materials of PC, PMMA, Carbon. Also the image quality by image analysis to obtain the following results are below: Unfors Xi dosimetry using radiation transmittance when the results of 8.353mGy is measured after removal of the cuff, the PC 6.308mGy, PMMA 6.223mGy, Carbon 7.218mGy were measured respectively. Semi-layer PC 0.375mmAl, PMMA 0.370mmAl, with Carbon 0.360mmAl Carbon, PC, PMMA was higher radiation properties and transparency in order. InLight / OSL NanoDotTM dosimeter was used in the cuff and then removed by placing the dosimeter measured results center on 1.143mGy, at the edge 12.56mGy, on the central PC 8.990mGy, at the edge 10.291mGy, PMMA center on 8.391mGy, the edge 9.654mGy, on Carbon center 9.581mGy, 11.313 mGy were measured at the edge of Carbon, PC, PMMA showed a high permeability in order. Image Pixel average J is then removed from the cuff 976.655, PC 831.032, PMMA 819.069, Carbon 897.118 Carbon, PC, PMMA was measured by high order.

Case study of landslide types in Korea (우리나라 산사태의 형태분류에 따른 사례)

  • 김원영;김경수;채병곤;조용찬
    • The Journal of Engineering Geology
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    • v.10 no.2
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    • pp.18-35
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    • 2000
  • The most dominant type of landslide in Korea is debris flows which mostly take place along mountain slopes during the rainy season, July to August. The landslides have been reported to begin activation when rainfall is more than 200mm within 2days. The debris flows are usually followed by translational slips which occur upper part of mountain slopes and they transit to debris flow as getting down to the valleys. Lithology, location, slope inclination, grain size distribution of soil, permeability, dry density and porosity have been proved as triggering factor causing translational slides. The triggering data taken from mapping are statistically analysed to get landslide potential quantitatively. Rock mass creeps mostly occur on well bedded sedimentary rocks in Kyeongsang Basin. Although the displacement of rock mass creep is relatively small about 1m, the creep can cause severe hazards due to relatively large volume of the involved rock mass. Examples are rock mass creep occurred in the mouth of Hwangryongsan Tunnel, in Chilgok and in Sachon in 1999. Although the direct factor of the creeps are due to slope cutting at the foot area, more attention is required A rotational slide occurring within thick soil formation or weathered rock is also closely related to bottom part of slope cutting. It is propagated circular or semi-circular type. Especially in korea, the rotational slide may be frequently occurred in Tertiary tuff area. Because they are mainly composed of volcanic ash and pyroclastic materials, well developed joints and high degree of swelling and absorption can easily cause the slide. The landslide among the Pohang-Guryongpo national road is belong to this type of slide.

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Relationship between Hydraulic Conductivity and Electrical Conductivity in Sands (사질토의 투수계수와 전기전도도 간의 상관관계)

  • Kim, Jinwook;Choo, Hyunwook;Lee, Changho;Lee, Woojin
    • Journal of the Korean Geotechnical Society
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    • v.31 no.6
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    • pp.45-58
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    • 2015
  • The aim of this study is to suggest a semi-empirical equation for estimating the hydraulic conductivity of sands using geoelectrical measurements technique. The suggested formula is based on the original Kozeny-Carman equation; therefore varying factors affecting the Kozeny-Carman equation were selected as the testing variables, and six different sands with varying particle sizes and particle shapes were used as the testing materials in this study. To measure both hydraulic and electrical conductivities, a series of constant head permeameter tests equipped with the four electrodes conductivity probe was conducted. Test results reveal that the effects of both pore water conductivity and flow rate in relation between hydraulic conductivity and formation factor (=pore water conductivity / measused conductivity of soil) of tested materials are negligible. However, because the variations of hydraulic conductivity of the tested sands according to particle sizes are significant, the estimated hydraulic conductivity using the formation factor varies with particle sizes. The overall comparison between the measured hydraulic conductivity and the estimated hydraulic conductivity using the suggested formula shows a good agreement, and the variation of hydraulic conductivity with varying Archie's m exponents is smaller compared with varying porosities.