• 제목/요약/키워드: Self-aggregate

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계면활성제 수용액의 미셀형성(제1보) - Polyoxyethylene Alkyl Ether의 자기확산과 프로톤 이완 - (Studies on the Micelle Formation of Nonionic Surfactant(1) -1NMR Self-Diffusion and Proton Relaxation of Polyoxyethylene Alkyl Ether-)

  • 최성옥;정환경;이진희;남기대
    • 공업화학
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    • 제9권6호
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    • pp.822-828
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    • 1998
  • $^1H$ NMR gradient spin echo법을 이용하여 polyoxyethylene dodecyl ether[$C_{12}H_{25}(OCH_2CH_2)nOH$] 수용액에서 미셀 형성과정에 대한 것을 비교검토 하였다. 여기서 n=5($C_{12}EO_5$) 및 n=8($C_{12}EO_8$)인 비이온성 계면활성제를 사용하였으며 등방성상의 영역범위에서의 자기확산 계수는 일정온도에서 농도변화에 따른 pulsed field gradient법을 사용하여 측정하였고, 또한 여러 프로톤의 시그날에 대한 피크폭(line width)을 추적하여 액정 특성에 대한 것을 검토하였다. 알킬사슬의 메틸렌 시그날의 넓혀짐은 $C_{12}EO_5-$물 계에서는 핵사고날 액정상의 근접될 때 관찰되었지만 $C_{12}EO_8-$물 계에서는 넓혀짐이 보다 작게 관찰되었다. 낮은 온도에서 농도가 증가함에 따라 $C_{12}EO_5$에서는 막대형 미셀이 형성되지만 $C_{12}EO_8$에서는 전 농도 범위에서 작은 미셀로 이루워 진다. 계면활성제의 자기확산계수는 서서히 증가하다가 극소점에 이르러서는 농도가 증가함에 따라 급격히 감소한다. 극소점의 위치는 온도가 담점에 이르렀을 때 낮은 농도에서 나타나고 이 계에서는 두 개의 등방성 상으로 분리된다. 피크폭 연구에서 피크폭의 넓어짐은 $C_{12}EO_5$에서는 온도가 증가되었을 때 온도의 차이로 형성된다. 그 결과 담점에 이르러 계면활성제의 회합체가 커지는 것으로 생각한다. 이 회합체가 담점에 이르러 한정된 모양을 갖는 것은 아니다. $C_{12}EO_8$에서는 미셀들이 온도의 증가에 영향을 받지 않고 미셀형성이 불확실하다. 에틸렌옥사이드 일부분의 메틸렌 시그날은 일관되게 좁게 나타났다. 회합에 있어서 이들은 알킬사슬 메틸렌보다 작은 질서로 나타내었다. 회합의 크기나 모양에 있어서 여러 변화성은 상 변화에 따라 등방성과 액정상의 안정성 범위가 정하여 진다. 회합체 크기와 상 구조는 여러 온도와 농도 변화에서 분자의 효과적 모형을 고려하여 정성적인 결과에 따른다.

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ACTIFELD에 근거한 증평 장소마케팅의 전략적 의사결정

  • 홍성호;김미성;김보경;김총회;이만형
    • 한국시스템다이내믹스학회:학술대회논문집
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    • 한국시스템다이내믹스학회 2007년도 춘계학술대회 발표논문집
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    • pp.93-111
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    • 2007
  • Even though place-marketingstrategies geared towards upgrading regional competitiveness have been brought to the forefront, due attention has not given to how to set up practical and viable strategies. Based on Geoff Coyle's ACTIFELD method, this study aims at formulating a series of implementation strategies of Jeungpyeong Place-Marketing. As the ACTIFELD technique contains intrinsic devices which would facilitate structural and systematic approach, it can easily encompass both qualitative and quantitative factors in reinterpreting complicated social phenomena and providing feasible alternatives. Furthermore, the study carries out additional public opinion surveys and expert brainstorming methods, as specific means to overcome relative weak points within the proposed ACTIFELD approach. The followings are major research findings. Firstly, in terms of maximizing existing strategies, Jeungpyeong should develop commercial items focused on Korean Ginseng and its byproducts. Secondly, among various festivals, Jeungpyeong should devise concrete processes to concurrently concentrate its support on Pork (Samgyupsal) and Korean Ginseng Festivals. Thirdly, as the majority of Jeungpyeong people prefers both do-it-your-self and traditional types, Jeungpyeong should prepare appropriate governance systems to deal with these issues. Fourthly, in order to contribute regional vitality, Jeungpyeong should strengthen public relation activities including guest-staying facilities. Lastly, Jeungpyeong should constantly improve the aggregate value of County Identity (CI)-based brands and it should also pursue production and public relation strategies actively applying the elderly.

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Adhesive Strength in Tension of High Volume PAE-Modified Cement Mortar with High Flowability for Floor Finishing

  • Do, Jeong-Yun;Soh, Yang-Seob
    • 콘크리트학회논문집
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    • 제15권5호
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    • pp.739-746
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    • 2003
  • Various researches on the application of polymer dispersions to the cement mortar and concrete have been carried out in many countries like America, Japan and Germany and so on due to their high performance and good modification effect. PAE of polymer dispersion widely used in situ was employed that the high flowability may be induced in the cement mortar. In order to investigate the modification of cement mortar with high flowability by PAE and fracture mode of adhesive strength properties in tension of that, experimental parameters were set as PAE solid-cement ratio(P/C) and cement: fine aggregate(C:F) and the experiments such as unit weight, flow, consistency change, crack resistance and segregation that inform on the general properties have been done. Adhesion in tension is measured with a view to comprehending the properties and fracture mode in tensile load. Consistency change of cement mortar modified by PAE did grow better as the ratio of PAE solid-cement increased and was much superior to that of resin based flooring such as polyurethane and epoxy which recorded the loss of consistency in 90 min. after mixing. Adhesive strength in tension increased with continuity during curing period and showed the maximum in case of C:F=1:1 and P/C=20%.

Prediction model of resistivity and compressive strength of waste LCD glass concrete

  • Wang, Chien-Chih
    • Computers and Concrete
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    • 제19권5호
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    • pp.467-475
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    • 2017
  • The purpose of this study is to establish a prediction model for the electrical resistivity ($E_r$) of self-consolidating concrete by using waste LCD (liquid crystal display) glass as part of the fine aggregate and then, to analyze the results obtained from a series of laboratory tests. A hyperbolic function is used to perform nonlinear multivariate regression analysis of the electrical resistivity prediction model, with parameters such as water-binder ratio (w/b), curing age (t) and waste glass content (G). Furthermore, the relationship of compressive strength and electrical resistivity of waste LCD glass concrete is also found by a logarithm function, while compressive strength is evaluated by the electrical resistivity of non-destructive testing (NDT). According to relative regression analysis, the electrical resistivity and compressive strength prediction models are developed, and the results show that a good agreement is obtained using the proposed prediction models. From the comparison between the predicted analysis values and test results, the MAPE value of electrical resistivity is 17.0-18.2% and less than 20%, the MAPE value of compressive strength evaluated by $E_r$ is 5.9-10.6% and nearly less than 10%. Therefore, the prediction models established in this study have good predictive ability for electrical resistivity and compressive strength of waste LCD glass concrete. However, further study is needed in regard to applying the proposed prediction models to other ranges of mixture parameters.

Bio-functionalized Gold Nanoparticles for Surface-Plasmon- Absorption-Based Protein Detection

  • Kim, Wan-Joong;Choi, Soo-Hee;Rho, Young-S.;Yoo, Dong-Jin
    • Bulletin of the Korean Chemical Society
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    • 제32권12호
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    • pp.4171-4175
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    • 2011
  • Bio-functionalized gold nanoparticles (AuNPs), which bio-specifically interact with biotin-(strept)avidin, were investigated in this study. AuNPs were functionalized with a synthetically-provided biotin-linked thiol (BLT), which was synthesized by amidation of the active ester of biotin with 2-mercaptoethylamine. The BLT-attached AuNP was bio-specific for streptavidin, making it potentially useful for biosensor applications. To test the bio-specific interactions, the colors, absorption spectra and TEM images were investigated for proteins such as streptavidin, cytochrome C, myoglobin and hemoglobin. The colors and absorption spectra changed when streptavidin was added to the BLT-attached AuNP solution. However, the color and spectra did not change when the other proteins were added to the same solution. These results show that the AuNPs provided a colloidal solution with excellent stability and highly selective absorption characteristics for streptavidin as a target molecule. Proteins were also screened in order to identify a general strategy for the use of optical biosensing proteins based on AuNPs. In addition, TEM images confirmed that streptavidin led the BLT-attached AuNPs to aggregate or precipitate.

Self-organized Spectrum Access in Small-cell Networks with Dynamic Loads

  • Wu, Ducheng;Wu, Qihui;Xu, Yuhua
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • 제10권5호
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    • pp.1976-1997
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    • 2016
  • This paper investigates the problem of co-tier interference mitigation for dynamic small- cell networks, in which the load of each small-cell varies with the number of active associated small-cell users (SUs). Due to the fact that most small-cell base stations (SBSs) are deployed in an ad-hoc manner, the problem of reducing co-tier interference caused by dynamic loads in a distributed fashion is quite challenging. First, we propose a new distributed channel allocation method for small-cells with dynamic loads and define a dynamic interference graph. Based on this approach, we formulate the problem as a dynamic interference graph game and prove that the game is a potential game and has at least one pure strategy Nash equilibrium (NE) point. Moreover, we show that the best pure strategy NE point minimizes the expectation of the aggregate dynamic co-tier interference in the small-cell network. A distributed dynamic learning algorithm is then designed to achieve NE of the game, in which each SBS is unaware of the probability distributions of its own and other SBSs' dynamic loads. Simulation results show that the proposed approach can mitigate dynamic co-tier interference effectively and significantly outperform random channel selection.

GA 기반 자기구성 다항식 뉴럴 네트워크의 최적화를 위한 새로운 설계 방법 (A New Design Approach for Optimization of GA-based SOPNN)

  • 박호성;박병준;박건준;오성권
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2003년도 하계학술대회 논문집 D
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    • pp.2627-2629
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    • 2003
  • In this paper, we propose a new architecture of Genetic Algorithms(GAs)-based Self-Organizing Polynomial Neural Networks(SOPNN). The conventional SOPNN is based on the extended Group Method of Data Handling(GMDH) method and utilized the polynomial order (viz. linear, quadratic, and modified quadratic) as well as the number of node inputs fixed (selected in advance by designer) at Polynomial Neurons (or nodes) located in each layer through a growth process of the network. Moreover it does not guarantee that the SOPNN generated through learning has the optimal network architecture. But the proposed GA-based SOPNN enable the architecture to be a structurally more optimized networks, and to be much more flexible and preferable neural network than the conventional SOPNN. An aggregate performance index with a weighting factor is proposed in order to achieve a sound balance between approximation and generalization (predictive) abilities of the model. To evaluate the performance of the GA-based SOPNN, the model is experimented with using nonlinear system data.

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Theoretical Inquiry for the Study on Beauty Aesthetics - Centered on the hairstyle -

  • Kim, Seong-Nam;Jung, Hyun-Jin
    • 패션비즈니스
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    • 제12권3호
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    • pp.16-30
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    • 2008
  • The purpose of this study is to inquire into the necessity and problem of the study on beauty aesthetics, and the direction and method of its study theoretically by applying the concept of aesthetics to the beauty art as an attempt to build up aesthetic concepts of beauty art. As results of inquiry, the study on beauty aesthetics is essential for the adaptation to demands for the creativity of beauty art. As for problem of study on beauty aesthetics, it is necessary to conduct an aggregate study at various angles since the aesthetic value of beauty art (hairstyle) is realized by interaction of the social cultural value or practical value and pure artistic value, and the unique cosmetic beauty of any era or nation group individual is created on the basis of hair designers and individual spirit, emotion and taste, etc. and its perceptual aesthetic enjoyment is accomplished variously. As for the direction and method of study on beauty aesthetics, the quest with abstract speculative self-examination into the beauty having its subjective meaning must be accomplished. This thesis would like to contribute to the building up of beauty industry field as beauty arts based on the aesthetics by successive coming forward of personnel for beauty who combine the aesthetic abilities meeting the diversified requirements of modern society and by improving the recognition of persons recognizing the beauty industry field as a technical field only.

농업 노동의 질적 차이를 반영한 감귤 생산 노동투입 효율성 비교 분석 -시장 임금차이를 기준으로- (A Comparison Analysis of the Labor Efficiency between Quality-Adjusted Labor and Quality-Unadjusted Labor in Jeju Mandarin Production -Based on the Difference in Market Wages-)

  • 이봉실;유영봉
    • 농촌지도와개발
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    • 제28권3호
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    • pp.153-165
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    • 2021
  • This study aims to analyze the difference in production elasticity based on the types of agricultural labor input regarding its qualitative difference in Jeju mandarin production. To estimate the production function of qualityadjusted labor, we have set up a Quality-Adjusted Index based on the market wage of the agricultural field. We have conducted a multiple regression analysis of the newly estimated labor inputs using the Ordinary Least Squares regression. Results show that the production efficiency of aggregate total labor hours (quality-unadjusted labor input) is overestimated compared to quality-adjusted labor with qualitative labor homogeneity. Moreover, by analyzing household labor and employment labor, we have observed that the marginal productivity of household labor exceeds that of employment labor. In conclusion, this study verifies that securing labor input homogeneity is crucial for analyzing agricultural labor hours' economic efficiency accurately.

Biofilm Signaling, Composition and Regulation in Burkholderia pseudomallei

  • Pravin Kumran Nyanasegran;Sheila Nathan;Mohd Firdaus-Raih;Nor Azlan Nor Muhammad;Chyan Leong Ng
    • Journal of Microbiology and Biotechnology
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    • 제33권1호
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    • pp.15-27
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    • 2023
  • The incidence of melioidosis cases caused by the gram-negative pathogen Burkholderia pseudomallei (BP) is seeing an increasing trend that has spread beyond its previously known endemic regions. Biofilms produced by BP have been associated with antimicrobial therapy limitation and relapse melioidosis, thus making it urgently necessary to understand the mechanisms of biofilm formation and their role in BP biology. Microbial cells aggregate and enclose within a self-produced matrix of extracellular polymeric substances (EPSs) to form biofilm. The transition mechanism of bacterial cells from planktonic state to initiate biofilm formation, which involves the formation of surface attachment microcolonies and the maturation of the biofilm matrix, is a dynamic and complex process. Despite the emerging findings on the biofilm formation process, systemic knowledge on the molecular mechanisms of biofilm formation in BP remains fractured. This review provides insights into the signaling systems, matrix composition, and the biosynthesis regulation of EPSs (exopolysaccharide, eDNA and proteins) that facilitate the formation of biofilms in order to present an overview of our current knowledge and the questions that remain regarding BP biofilms.