• 제목/요약/키워드: Self diffusion

검색결과 386건 처리시간 0.036초

Synthesis and Characterization of Cu(In,Ga)Se2 Nanostructures by Top-down and Bottom-up Approach

  • Lee, Ji-Yeong;Seong, Won-Kyung;Moon, Myoung-Woon;Lee, Kwang-Ryeol;Yang, Cheol-Woong
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2012년도 제43회 하계 정기 학술대회 초록집
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    • pp.440-440
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    • 2012
  • Nanomaterials have emerged as new building blocks to construct light energy harvesting assemblies. Size dependent properties provide the basis for developing new and effective systems with semiconductor nanoparticles, quantized charging effects in metal nanoparticle or their combinations in 2 and 3 dimensions for expanding the possibility of developing new strategies for photovoltaic system. As top-down approach, we developed a simple and effective method for the large scale formation of self-assembled Cu(In,Ga)$Se_2$ (CIGS) nanostructures by ion beam irradiation. The compositional changes and morphological evolution were observed as a function of the irradiation time. As the ion irradiation time increased, the nano-dots were transformed into a nano-ridge structure due to the difference in the sputtering yields and diffusion rates of each element and the competition between sputtering and diffusion processes during irradiation. As bottom-up approach, we developed the growth of CIGS nanowires using thermal-chemical vapor deposition (CVD) method. Vapor-phase synthesis is probably the most extensively explored approach to the formation of 1D nanostructures such as whiskers, nanorods, and nanowires. However, unlike binary or ternary chalcogenides, the synthesis of quaternary CIGS nanostructures is challenging because of the difficulty in controlling the stoichiometry and phase structure. We introduced a method for synthesis of the single crystalline CIGS nanowires in the form of chalcopyrite using thermal-CVD without catalyst. It was confirmed that the CIGS nanowires are epitaxially grown on a sapphire substrate, having a length ranged from 3 to 100 micrometers and a diameter from 30 to 500 nm.

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ACCELERATION OF COSMIC RAYS AT LARGE SCALE COSMIC SHOCKS IN THE UNIVERSE

  • KANG HYESUNG;JONES T. W.
    • 천문학회지
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    • 제35권4호
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    • pp.159-174
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    • 2002
  • Cosmological hydrodynamic simulations of large scale structure in the universe have shown that accretion shocks and merger shocks form due to flow motions associated with the gravitational collapse of nonlinear structures. Estimated speed and curvature radius of these shocks could be as large as a few 1000 km/s and several Mpc, respectively. According to the diffusive shock acceleration theory, populations of cosmic-ray particles can be injected and accelerated to very high energy by astrophysical shocks in tenuous plasmas. In order to explore the cosmic ray acceleration at the cosmic shocks, we have performed nonlinear numerical simulations of cosmic ray (CR) modified shocks with the newly developed CRASH (Cosmic Ray Amr SHock) numerical code. We adopted the Bohm diffusion model for CRs, based on the hypothesis that strong Alfven waves are self-generated by streaming CRs. The shock formation simulation includes a plasma-physics-based 'injection' model that transfers a small proportion of the thermal proton flux through the shock into low energy CRs for acceleration there. We found that, for strong accretion shocks, CRs can absorb most of shock kinetic energy and the accretion shock speed is reduced up to $20\%$, compared to pure gas dynamic shocks. For merger shocks with small Mach numbers, however, the energy transfer to CRs is only about $10-20\%$ with an associated CR particle fraction of $10^{-3}$. Nonlinear feedback due to the CR pressure is insignificant in the latter shocks. Although detailed results depend on models for the particle diffusion and injection, these calculations show that cosmic shocks in large scale structure could provide acceleration sites of extragalactic cosmic rays of the highest energy.

오스테나이트계 25Cr-20Ni 스테인리스강의 Ω법을 이용한 고온 크리프 거동 해석 (Creep Behavior Analysis of 25Cr-20Ni Stainless Steels by Omega Method)

  • 박인덕;남기우
    • 대한기계학회논문집A
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    • 제26권2호
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    • pp.349-356
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    • 2002
  • For two kinds of 25Cr-20Ni stainless steels, STS310J1TB and STS310S with and without a small amount of Nb and N, creep behavior has been studied in a stress and temperature range from 147 to 392 MPa and from 923 to 773 K with a special reference to tertiary creep. The average creep life of STS310J1TB was about 100 times longer than that of the STS310S. The apparent activation energy for the initial creep rate was 330 kJ/mol in STS310J1TB, while that of the STS310S was 274kJ/mol in a power law creep region and 478 kJ/mol in a region of power law breakdown (PLB). The activation energy for STS310S below PLB is close to the for self-diffusion. When compensating for the temperature dependence of the Young's modulus and the omega value, it was found that the apparent activation energy for STS310J1TB was reduced to the activation energy for diffusion of chromium atom in gamma steel. The stress exponent of STS310S was about 12.3 above PLB and 5.1 in a power law creep region. Notwithstanding that the creep condition for STS310J1TB was in a power law creep region, its stress exponent was 7.9 larger than that of STS310S corresponding to the same creep conditions. This was ascribed to the presence of fine precipitates in STS310J1TB.

웹기반 학습 시스템(에듀넷) 활용 결정에 영향을 미치는 요인에 관한 연구 (A study on factors influencing the decision of Web-based Learning System (Edunet) use)

  • 편은진;박병호
    • 컴퓨터교육학회논문지
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    • 제8권5호
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    • pp.63-72
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    • 2005
  • 본 연구는 초중고학생들의 웹 교육정보 시스템인 에듀넷의 활용 결정에 영향을 미치는 변수들을 찾아냄으로써 에듀넷 활용 확산을 위한 방안을 모색하고자 하였다. 이를 위해 혁신의 확산 이론과 웹 활용 교육에 대한 관련 선행연구들의 조사를 통해 에듀넷 활용에 영향을 미칠 것으로 예상되는 변수로써 혁신의 속성(상대적 유용성, 적합성, 복잡성), 혁신성, 자기효능감, 주관적 판단, 지원을 추출하였다. 설문 조사는 서울.경기 지역의 초등학교 5, 6학년 315명을 대상으로 실시하였으며, 응답결과는 로지스틱 회귀분석 방법을 이용하여 분석하였다. 분석 결과, 혁신의 속성, 혁신성, 자기효능감, 주관적 판단, 지원을 포함한 회귀 모형의 적합성이 검정되었으며, 주관적판단, 지원이 에듀넷활용 여부를 결정짓는데 유의미한 영향을 미치는 변수로 확인되었다.

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오스테나이트계 25Cr-20Ni 스테인리스강의 $\Omega$ 법을 이용한 고온 크리프 거동 해석 (Creep Behavior Analysis of 25Cr-20Ni Stainless Steels With Omega Methods)

  • 박인덕;남기우
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2001년도 추계학술대회논문집A
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    • pp.117-122
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    • 2001
  • For two kinds of 25Cr-20Ni stainless steels, SUS310J1TB TB and SUS310S with and without a small amount of Nb and N, creep behavior has been studied in a stress and temperature range from 147 to 392MPa and from 923 to 973K with a special reference to tertiary creep. The average creep life of SUS310J1TB was about 100 times longer than that of the SUS310S. The apparent activation energy for the initial creep rate was 330 kJ/mol in SUS310J1TB, while that of the SUS310S was 274 kJ/mol in a power law creep region and 478 kJ/mol in a region of power law breakdown (PLB). The activation energy for SUS310S below PLB is close to the that for self-diffusion. When compensating for the temperature dependence of the Young's modulus and the omega value, it was found that the apparent activation energy for SUS310J1TB was reduced to the activation energy for diffusion of chromium atom in a gamma steel. The stress exponent of SUS310S was about 12 above PLB and 5.1 in a power law creep region. Notwithstanding that the creep condition for SUS310J1TB was in a power law creep region, its stress exponent was 8.3 larger than that of SUS310S corresponding to the same creep conditions. This was ascribed to the presence of fine precipitates in SUS310J1TB.

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21 세기 한국 농촌지도사업의 비전과 발전과제 (Vision and Developmental Tasks for Korea Agricultural Extension Services for the 21 st Century)

  • 이수철;이채식
    • 농촌지도와개발
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    • 제7권1호
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    • pp.101-119
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    • 2000
  • Agricultural Extension Services in Korea have accomplished a significant role in self- sufficiency of rice, a national staple food, through green revolution in 1970's; supplying green vegetables even during the winter season through white revolution in 1980's; and establishing technical agriculture by organizing rural leaders and 4-H members. In 1990s changes were made in international situations under the Uruguay Round multilateral trade negotiations and inauguration of the World Trade Organization. This was followed by localization of the extension staffs and the functions of extension services in Korea changed dramatically from national government to local governments. Thus, a weakened national function resulted in loosening of the linkages of research and extension in central government and local extension offices. Difficulties were reported in diffusion of new agricultural technology and efficient management of extension personnel. Developmental tasks for better extension services for the 21st century in Korea would include recovering national functions of agricultural extension, and developing a new paradigm for extension service. This should include the following measures; 1) Cooperative extension service should be adapted to involve national as well as local governments and non-government organization. 2) The target groups for extension services should be expanded to include farmers, noel residents as well as urban consumers. 3) The role of the extension service should cover agricultural technological diffusion of innovations as well as managerial skills and leadership development for rural organizations. 4) Extension services should be introduced to small farmers as well as consultation services for advanced farms. Diversified approaches should be employed for mama effective services. 5) Pre-service as well as in-service education should be offered to secure better extension educators equipped with knowledge, understanding and abilities on agricultural technology, information, agricultural philosophy, instructional methods and communication skills.

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폐감귤박으로 제조한 활성탄에 의한 아세톤, 벤젠 및 메틸메르캅탄의 흡착특성 (Adsorption Characteristics of Acetone, Benzene, and Metylmercaptan by Activated Carbon Prepared from Waste Citrus Peel)

  • 감상규;강경호;이민규
    • 공업화학
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    • 제28권6호
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    • pp.663-669
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    • 2017
  • 활성화제로 KOH, NaOH 및 $ZnCl_2$를 사용하여 폐감귤박으로부터 활성탄을 제조하였다. 최적조건(활성화제의 침적비율 300%, 활성화 온도 : KOH의 경우 $900^{\circ}C$, NaOH의 경우 $700^{\circ}C$, $ZnCl_2$의 경우 $600^{\circ}C$, 활성화 시간 1.5 h)에서 제조한 활성탄을 각각 ACK, ACN 및 ACZ로 명명하였다. 이들 활성탄을 사용하여 회분식 반응기에서 아세톤, 벤젠 및 메틸메르캅탄(MM) 등의 3가지 대상가스에 대한 흡착 특성을 검토하였다. 이들 활성탄에 의한 3가지 대상 가스의 흡착은 Langmuir 모델식보다는 Freundlich 모델식에 더 부합되는 것으로 나타났다. 그리고 흡착 속도실험결과는 유사 1차 속도식보다는 유사 2차 속도식에 잘 부합하였으며, 입자 내 확산 모델 결과는 흡착 과정에서 외부물질전달과 입자확산이 동시에 일어나는 것을 시사해 주었다.

리튬전지용 에테르가 기능화된 이온성 액체 기반 이온성 액정 전해질의 전기화학적 특성 (Ionic Liquid Crystal Electrolytes based on Ether Functionalized Ionic Liquid for Lithium Batteries)

  • 김일진;김기수;이진홍
    • 공업화학
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    • 제31권3호
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    • pp.305-309
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    • 2020
  • 본 연구에서는 에테르가 기능화된 이온성 액체인 [DMIm][MPEGP] (1,3-dimethylimidazolium (2-methoxy(2-ethoxy(2-ethoxy)))-ethylphosphite)와 리튬염인 LiTf2N (lithium bis(trifluoromethanesulfonyl)imide)을 혼합하였고, 리튬염의 함량을 조절하여 전해질을 특성을 조사하였다. 제조된 전해질은 리튬염 혼합에 따라 불투명해지고 흐름성이 제한된 열방성 액정을 형성하였으며, 이때 리튬염의 함량에 따라 형성되는 이온성 액정의 자기조립구조와 이온 전도 현상을 다양한 분광학적 분석을 통해 조사하였다. 그 결과 이온성 액정의 향상된 이온전도도는 정렬된 구조를 통한 이온 전도 특성과 관계가 있음을 확인하였으며, 리튬이온전지 특성 평가에서 우수한 전기화학적 특성을 나타냄을 확인하였다.

자외선 차단 의복에 대한 소비자 조사 -아웃도어 스포츠웨어를 중심으로- (A Study on UV Protective Clothing - An Emphasis on Outdoor Sports Consumers -)

  • 성희원;전양진;박혜선
    • 한국의류학회지
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    • 제29권8호
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    • pp.1136-1145
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    • 2005
  • The objective of this study was to determine factors affecting sun protective behavior and intention to buy UV protective clothing among outdoor sport persons in Korea. A self-administered questionnaire was distributed to mountain climbers, bikers and in-line skaters with a convenience sampling method. Two theoretical frameworks, health belief(HB) model and diffusion theory(DT) were used for the study. Based on HB model, sun protection behaviors(SPBs) were associated with cancer perception, perceived benefits, behavioral barriers and cues to actions based on the HB model. Based on DT model, intention to buy (ITB) was determined by an individual's perceived attributes of UV protective shirt. Appearance concern variables were added to the extended HB model. The extended DT model was proposed by adding the variables in the HB model and variables of appearance concern. Multiple regression analysis was applied. Results were as follows. First, perceived benefits, behavioral barriers, cues to action, and all three appearance concern variables as well as gender and age were significant determinants of SPB for Korean outdoor consumers. Second, relative advantage, compatibility, friability, behavioral barriers and cues to action with some appearance concern variables were significant in affecting intention to buy UV protective clothes. Extended HB model and extended DT model were useful to understand SPBs of Korean outdoor consumers.

A Molecular Dynamics Study of the Stress Effect on Oxidation Behavior of Silicon Nanowires

  • 김병현;김규봉;박미나;마우루디;이광렬;정용재
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2011년도 제40회 동계학술대회 초록집
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    • pp.499-499
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    • 2011
  • Silicon nanowires (Si NWs) have been extensively studied for nanoelectronics owing to their unique optical and electrical properties different from those of bulk silicon. For the development of Si NW devices, better understanding of oxidation behavior in Si NWs would be an important issue. For example, it is widely known that atomic scale roughness at the dielectric (SiOx)/channel (Si) interface can significantly affect the device performance in the nano-scale devices. However, the oxidation process at the atomic-scale is still unknown because of its complexity. In the present work, we investigated the oxidation behavior of Si NW in atomic scale by simulating the dry oxidation process using a reactive molecular dynamics simulation technique. We focused on the residual stress evolution during oxidation to understand the stress effect on oxidation behavior of Si NWs having two different diameters, 5 nm and 10 nm. We calculated the charge distribution according to the oxidation time for 5 and 10 nm Si NWs. Judging from this data, it was observed that the surface oxide layer started to form before it is fully oxidized, i.e., the active diffusion of oxygen in the surface oxide layer. However, it is well-known that the oxide layer formation on the Si NWs results in a compressive stress on the surface which may retard the oxygen diffusion. We focused on the stress evolution of Si NWs during the oxidation process. Since the surface oxidation results in the volume expansion of the outer shell, it shows a compressive stress along the oxide layer. Interestingly, the stress for the 10 nm Si NW exhibits larger compressive stress than that of 5 nm Si NW. The difference of stress level between 5 an 10 anm Si NWs is approximately 1 or 2 GPa. Consequently, the diameter of Si NWs could be a significant factor to determine the self-limiting oxidation behavior of Si NWs when the diameter was very small.

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