• 한국정보통신학회:학술대회논문집
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• 한국해양정보통신학회 2008년도 춘계종합학술대회 A
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• pp.997-999
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• 2008

본 연구에서는 항만오염의 주원인의 하나인 오염물질을 검출할 수 있는 센서 개발을 위하여 Viologen 유도체를 사용하였다. 자기조립법을 이용하여 Viologen 유도체를 수정진동자의 금 전극에 수식하였으며, 순환전압전류법을 이용하며 산화 환원 반응 특성과 피크전류의 변화를 관찰하였다. 그리고 벤젠, 인산염, 계면활성제 등의 오염물질에 대한 선택적 특성을 검토하였다.

• Bulletin of the Korean Chemical Society
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• 제27권3호
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• pp.381-385
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• 2006

The temperature dependence on the electron transfer rate constant $(k_{app})$ for hydroquinone redox center in $H_2Q(CH_2)_n$SH-SAMs (n = 1, 4, 6, 8, 10, and 12) on gold electrode was investigated to obtain reorganization energy $(\lambda)$ using Laviron’s formalism and Arrhenius plot of ln $[k_{app}/T^{1/2}]$ vs. T^{-1} based on the Marcus densityof-states model. All the symmetry factors measured for the SAMs were relatively close to unity and rarely varied to temperature change as expected. The electron tunneling constant $(\beta)$ determined from the dependence of the $k_{app}$ on the distance between the redox center and the electrode surface gives almost the same $\beta$ values which are quite insensitive to temperature change. Good linear relationship of Arrhenius plot for all $H_2Q(CH_2)_n$SH-SAMs on gold electrode was obtained in the temperature range from 273 to 328 K. The slopes n Arrhenius plot deduced that $\lambda$ of hydroquinone moiety is ca. 1.3-1.4 eV irrespectively of alkyl chain length of the electroactive SAM.

• Bulletin of the Korean Chemical Society
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• 제32권5호
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• pp.1679-1684
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• 2011

Interfacial reactions kinetics often differ from kinetics of bulk reactions. Here, we describe how the density change of an immobilized reactant influences the kinetics of interfacial reactions. Self-assembled monolayers (SAMs) of alkanethiolates on gold were used as a model interface and the Diels-Alder reaction between immobilized quinones and soluble cyclopentadiene was used as a model reaction. The kinetic behavior was studied using varying concentrations of quinones. An unusual threshold density of quinones (${\Gamma}_c$ = 5.2-7.2%), at which the pseudo-first order rate constant started to vary as the reaction progressed, was observed. This unexpected kinetic behavior was attributed to the phase-separation phenomena of multi-component SAMs. Additional experiments using more phase-separated two-component SAMs supported this explanation by revealing a significant decrease in ${\Gamma}_c$ values. When the background hydroxyl group was replaced with carboxylic or phosphoric acid groups, ${\Gamma}_c$ was observed at below 1%. Also, more phase-separated thermodynamically controlled SAMs produced a lower critical density (3% < ${\Gamma}_c$ < 4.9%) than that of the less phaseseparated kinetically controlled SAMs (6.5% < ${\Gamma}_c$ < 8.9%).

• Bulletin of the Korean Chemical Society
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• 제33권10호
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• pp.3269-3273
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• 2012

In this study, we report a new method for the high contrast imaging of biomolecular interactions at roller printed protein surfaces using thermotropic liquid crystals (LCs). Avidin was roller printed and covalently immobilized onto the obliquely deposited gold surface that was decorated with carboxylic acid-terminated self-assembled monolayers (SAMs). The optical response of LCs on the roller printed film of avidin contrasted sharply with that on the obliquely deposited gold surface. The binding of biotin-peroxidase to the roller printed avidin was then investigated on the obliquely deposited gold substrate. LCs exhibited a non-uniform and random orientation on the roller printed area decorated with the complex of avidin and biotin-peroxidase, while LCs displayed a uniform and planar orientation on the area without roller printed proteins. The orientational transition of LCs from uniform to non-uniform state was triggered by the erasion of nanometer-scale topographies on the roller printed surface after the binding of biotin-peroxidase to the surface-immobilized avidin. The specific binding events of protein-receptor interactions were also confirmed by atomic force microscopy and ellipsometry. These results demonstrate that the roller printing of proteins on obliquely deposited gold substrates could provide a high contrast signal for imaging biomolecular interactions using LC-based sensors.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2001년도 하계학술대회 논문집 C
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• pp.1893-1895
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• 2001

In this paper, novel release technique using wet etch is proposed. The results of this technique and the results of SAMs (Self-Assembled monolayers) coated after release using this technique are compared. Fabricated structure have 100 um in width and experimental length is from 100 um to 1 mm. Thickness of aluminum sacrificial layer is 2 um and structure thickness is 2.5 um. Cantilevers and bridges are fabricated with electroplated gold and silicon nitride deposited on substrate. An aluminium sacrificial layer was evaporated thermally and removed in various wet etching solutions. Detachment length of cantilever is 200 um and detachment length of bridge is 1 mm after isooctane rinsing. And the SAMs coating condition which is appropriate for gold and nitride are studied respectively.

• Bulletin of the Korean Chemical Society
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• 제26권3호
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• pp.361-370
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• 2005

In this review, the field of biosurface organic chemistry is defined and some examples are presented. The aim of biosurface organic chemistry, composed of surface organic chemistry, bioconjugation, and micro- and nanofabrication, is to control the interfaces between biological and non-biological systems at the molecular level. Biosurface organic chemistry has evolved into the stage, where the lateral and vertical control of chemical compositions is achievable with recent developments of nanoscience and nanotechnology. Some new findings in the field are discussed in consideration of their applicability to nanobiotechnology and biomedical sciences.

• Tribology and Lubricants
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• 제20권6호
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• pp.343-349
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• 2004

The adsorption of soot particles onto a sensor surface of the engine soot detector posses a critical problem in the measurement. In order to prevent the optical rod surface from soot contamination, various functional coatings and flow-induced cleaning were applied to the surface in this work. For surface coatings, various materials of self-assembled monolayers (SAM) such as OTS (octadecyltrichlorosilane), PFDTES (perfluorodecyl-triethoxysilane) and PFDTMS (perfluorodecyltrimethoxysilane) were coated on the optical rod surface ,which have different characteristics in both hydrophobicity and oleophobicity. These coatings were tested with soot content varying from $0\%\;to\;3wt\%$ and oil temperature from 20 to $70^{\circ}C$. Test results showed that surface coatings were not effective for preventing the adsorption of soot panicles on the surface of optical rod. It was thought that these coatings provided the surface with additional attractive surface forces. However, it was found that adsorption of soot particles onto a sensor surface was minimized by flow-induced cleaning. This effect was tested with varying the flow velocity.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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• pp.380.1-380.1
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• 2014

열 화학기상증착법은 여러 가지 그래핀의 제작방법 중 대면적으로 양질의 그래핀을 효과적으로 합성할 수 있는 방법으로 널리 이용되고 있다. 이 방법으로 그래핀을 합성할 경우, 주요 변수로 성장 온도와 촉매 금속이 있으며 이를 적절히 조절함으로써 합성되는 그래핀의 결정성과 층수를 조절할 수 있다[1-3]. 본 연구에서는 탄소 용해도가 작은 두꺼운 촉매 금속 기판 위에 선택적인 위치에 탄소 용해도가 큰 얇은 촉매 금속을 증착하여 그래핀의 층수를 적절하게 제어하고자 한다. 그래핀을 합성하기 위해 온도를 증가시키는 과정에서 두 층의 촉매 금속은 표면 에너지를 낮추기 위해 합금을 형성하게 되며, 이 때 탄소 용해도가 변화할 것으로 예상된다. 이 변화하는 탄소 용해도에 맞추어 탄소 공급원인 메탄 가스를 주입하는 시기를 적절히 조절하게 되면, 합성되는 그래핀의 층수 조절이 가능할 것이라 예상한다. 탄소 용해도가 큰 금속으로 니켈을, 탄소 용해도가 작은 금속으로 구리를 선택하였다. 우선 니켈의 확산 거리를 계산하여 메탄 가스를 주입하는 적절한 온도를 결정하였으며, 이 온도를 기준으로 표면에서의 니켈의 함량을 분석하였다. 니켈의 함량과 표면에서의 탄소의 구성비의 관계를 조사한 결과, 본 실험에서 이용한 방법으로 그래핀의 층수를 조절하는 것이 가능하다는 것을 확인하였다.

• Bulletin of the Korean Chemical Society
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• 제31권11호
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• pp.3103-3108
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• 2010

Conducting polymers (CPs) are widely used as matrixes for the entrapment of enzymes in analytical chemistry and biosensing devices. However, enzyme-catalyzed polymerization of CPs is rarely used for immunosensing due to the difficulties involved in the quantitative analysis of colloidal CPs in solution phase. In this study, an enzyme-amplified electrocatalytic immunosensor employing a CP as a redox marker has been developed. A polyanionic polymer matrix, $\alpha$-amino-$\omega$-thiol terminated poly(acrylic acid), was employed for precipitation of CP. The acrylic acid group acts as a polyanionic template. The thiol terminus of the polymer was used to produce self-assembled monolayers (SAMs) on Au electrodes and the amine terminus was employed for immobilization of biomolecules. In an enzymeamplified sandwich type immunosensor, the polyaniline (PANI) produced enzymatically is attracted by the electrostatic force of the matrix polymer. The precipitated PANI was characterized by electrochemical methods.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2007년도 추계학술대회 논문집
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• pp.514-514
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• 2007

1차원 구조를 갖는 나노 와이어들은 나노 소자를 구현하기 위한 building-block으로 많은 과학자들의 주목을 받고 있고 또한 연구되고 있다. 하지만 그것을 정확하게 위치시키고 일정한 간격으로 정렬시키기 위한 기술 개발은 아직도 해결해야 할 큰 과제로 남아 있다. 이 논문에서, 우리는 ahsing 기술과 표면 패터닝 기술을 이용하여 대면적의 실리콘웨이퍼 위에 DNA(deoxyribonucleic acid)를 기반으로 한 금 나노 와이어를 정확하게 위치시키고 일정한 간격으로 정렬시킬 수 있는 새로운 제어 기술을 제안한다. 먼저 우리는 포토 리소그래피 공정과 $O_2$ 플라즈마 ashing 기술을 이용하여 선폭을 100 nm로 감소 시켰다. 그리고 자기조립단분자막 (self-assembled monolayers; SAMs) 방법과 lift-off 공정을 반복함으로서 1-octadecyltrichlorosilane(OTS) 층과 aminopropylethoxysilane(APS) 층을 형성하였다. 마지막으로 DNA 용액을 샘플 표면 위에 도포하고 분자 빗질 방법으로 DNA를 한 방향으로 정렬 시켰고 금 나노입자 용액을 처리하였다. 그 결과 금 나노 와이어는 $10{\mu}m$ 간격으로 일정하게 정열 되었고, APS 층에만 정확하게 정렬되었다. 우리는 금 나노 와이어를 관찰하기 위하여 원자간력 현미경 (Atomic Force Microscope AFM)을 사용하였다.