• Journal of Korea Soil Environment Society
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• v.3 no.2
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• pp.3-12
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• 1998

To analyze of oils in contaminated soils, it is necessary to classify of oils accurately and it has to be selected suitable extraction method and instrumental analysis method in according to the character of sample. In this study, oils are classified into three groups-gasoline, diesel and kerosene-we consider extraction methods and quantitative analysis method of these oils using GC/MS. As the analysis example of real sample, we analyze some gasolines and diesels of some oil refining company and calculate BTEX in gasoline and saturated n-hydrocarbons in diesel. And also, we study the representative quantitative method of each kind of oils.

• Economic and Environmental Geology
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• v.31 no.5
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• pp.415-424
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• 1998

In order to investigate soil-gas $^{222}Rn$ concentrations, Kwanak Campus (Seoul National University), Boeun (Choong-buk) and Gapyung (Kyonggi) areas were selected and classified depending on their base rock types. Radon risk indices of these study areas decrease in the order of Gapyung>Kwanak Campus>Boeun areas, and in the order of rock type as banded gneiss>granite gneiss>granite>black slate-shale>mica schist>shale-lirnestone>phyllite-schist. Radon emanating trends with water content and grain size of soils were assessed by modified Morse 3 min. method. Radon emanation increases with the increase of water content in soils which is lower than 6~16 wt.%, and decreases in the range of higher than 6-16 wt. %. It shows that Rn emanation increases with the decrease of soil grain size. Radioactivity analysis of radionuclides of 238U series in some soil samples shows that radioactive disequilibrium state between $^{226}Ra$ and $^{238}U$ exists owing to different geochemical behavior of each radionuclide, and, it is necessary to carry out radioactive isotope geochemical approach for soil-gas $^{222}Rn$ study.

• Korean Journal of Soil Science and Fertilizer
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• v.47 no.3
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• pp.205-212
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• 2014

Chronological changes of soil organic carbon (SOC) must be prepared by IPCC guidelines for national greenhouse gas inventories. IPCC suggested default reference SOC stocks for mineral soils and relative stock factors for different management activities where country own factors were not prepared. 3.4 million data were downloaded from agricultural soil information system and analyzed to get chronological changes of SOC for some counties and for land use in Korea. SOC content of orchard soil was higher than the other soils but chronological SOC changes of all land use had no tendency in differences with high standard deviation. SOC contents of counties depended on their own management activities and chronological SOC changes of districts also had no tendency in differences. Thus, Korea should survey the official records and relative stock factors on management activities such as land use, tillage and input of organic matter to calculate SOC stocks correctly. Otherwise, Korea should establish a model for predicting SOC by analyzing selected representative fields and by calculating SOC differences from comparing management activities of lands with those of representative fields.

• Journal of the Korean Society of Hazard Mitigation
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• v.8 no.1
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• pp.139-143
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• 2008

Recently, detections of huge amount of wastes in the unsanitary landfills at a residential development sites were reported. Because the sites were the residential development sites, all landfilled wastes should be removed for the constructions. Therefore the way that the unsanitary landfills were excavated and then the wastes were sorted into three categories such as soils, noncombustibles, and combustibles was selected as the best method. Soils and noncombustibles could be recycled in the sites and combustibles could be compacted and be relandfilled in a smaller area.

• Geomechanics and Engineering
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• v.30 no.5
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• pp.479-487
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• 2022

This study evaluates the performance of gravel impact compaction piers system (GICPs) in strengthening retrofitting a very loose silty sand layer with a very high liquefaction risk with a thickness of 3.5 meters in a multilayer coastal soil located in Bushehr, Iran. The liquefiable sandy soil layer was located on clay layers with moderate to very stiff relative consistency. Implementation of gravel impact compaction piers is a new generation of aggregate piers. After technical and economic evaluation of the site plan, out of 3 experimental distances of 1.8, 2 and 2.2 meters between compaction piers, the distance of 2.2 meters was selected as a winning option and the northern ring of the site was implemented with 1250 gravel impact compaction piers. Based on the results of the standard penetration test in the matrix soil around the piers showed that the amount of (N₁)₆₀ in compacted soils was in the range of 20-27 and on average 14 times the amount of (1-3) in the initial soil. Also, the relative density of the initial soil was increased from 25% to 63% after soil improvement. Also the safety factor of the improved soil is 1.5-1.7 times the minimum required according to the two risk levels in the design.

• Journal of Soil and Groundwater Environment
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• v.19 no.5
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• pp.35-44
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• 2014

In this study, the bio-phytoremediation and phytoremediation technologies were applied to the soils contaminated with total petroleum hydrocarbons (TPH) and heavy metals to evaluate the remediation efficacy from May 2012 to December 2013. Poplar (Populus bonatii Levl.) and Sun Hemp (Crotalaria juncea L.) were selected and planted in phytoremediation practice. These plants were also utilized in the bio-phytoremediation practice, with the addition of earthworm (Eisenia fetida) and petroleum-degrading bacteria (Pseudomonos sp. NKNU01). Furthermore, physiological characteristics, such as photosynthesis rate and maximal photochemical yield, of all testing plants were also measured in order to assess their health conditions and tolerance levels in adverse environment. After 20 months of remedial practice, the results showed that bio-phytoremediation practice had a higher rate of TPH removal efficacy at 30-60 cm depth soil than that of phytoremediation. However, inconsistent results were discovered while analyzing the soil at 100 cm depth. The study also showed that the removal efficiency of heavy metals was lower than that of TPH after remediation treatment. The results from test field tissue sample analysis revealed that more Zinc than Chromium was absorbed and accumulated by the tested plants. Plant height measurements of Poplar and Sun Hemp showed that there were insignificant differences of growth between the plants in remediation plots and those in the control plot. Physiological data of Poplar also suggested it has higher tolerance level toward the contaminated soils. These results indicated that the two testing plants were healthy and suitable for this remediation study.

• Journal of Korean Society on Water Environment
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• v.25 no.5
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• pp.674-681
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• 2009

Characteristics of organic matters (OM) in wastewater and the removal efficiencies were investigated using the influent and the effluent samples collected from 21 wastewater treatment plants. The OM characteristics investigated included biodegradability, humic content, specific UV absorbance (SUVA), the distribution percentage of refractory OM (R-OM), and synchronous fluorescence spectra. The types of wastewater (sewage, livestock waste/night soils, industrial waste) were easily distinguished by comparing the synchronous fluorescence spectra of the influent wastewater. The prominent peak of protein-like fluorescence (PLF) was observed for livestock waste/night soils whereas sewage exhibited a unique fluorescence peak at a wavelength of 370 nm. Irrespective of the wastewater types, the distribution percentage of R-OM increased from the influent to the effluent. Livestock waste/night soils showed the highest removal efficiency among all the three types of wastewater. There was no statistical difference of the removal efficiency between a traditional activated sludge and biological advanced treatment processes. Removal efficiency based on dissolved organic carbon DOC presented good correlations with the distribution percentage of R-OM and fulvic-like fluorescence (FLF) of the influent. The prediction for DOC removal efficiency was improved by using multiple regression analyses based on some selected OM characteristics and mixed liquid suspended solid (MLSS).

• Membrane and Water Treatment
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• v.9 no.3
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• pp.137-146
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• 2018

Soil washing is one of the most frequently used remediation technologies for heavy metal-contaminated soils. Inorganic and organic acids and chelating agents that can enhance the removal of heavy metals from contaminated soils have been employed as soil washing agents. However, the toxicity, low removal efficiency and high cost of these chemicals limit their use. Given that humic substance (HS) can effectively chelate heavy metals, the development of an eco-friendly, performance-efficient and cost-effective soil washing agent using a nano-scale chelator composed of HS was examined in this study. Copper (Cu) and lead (Pb) were selected as target heavy metals. In soil washing experiments, HS concentration, pH, soil:washing solution ratio and extraction time were evaluated with regard to washing efficiency and the chelation effect. The highest removal rates by soil washing (69% for Cu and 56% for Pb) were achieved at an HS concentration of 1,000 mg/L and soil:washing solution ratio of 1:25. Washing with HS was found to be effective when the pH value was higher than 8, which can be attributed to the increased chelation effect between HS and heavy metals at the high pH range. In contrast, the washing efficiency decreased markedly in the low pH range due to HS precipitation. The chelation capacities for Cu and Pb in the aqueous phase were determined to be 0.547mmol-Cu/g-HS and 0.192mmol-Pb/g-HS, respectively.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.8 no.2
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• pp.33-40
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• 1988

In this study, effects of the density of soil and the confining pressure applied to the soil sample on the elastic moduli of subgrade soils are experimentally analyzed. Through investigation of subgrade materials of domestic expressways, five typical types of subgrade soils are selected for the experiments. A series of unconsolidated undrained triaxial tests is performed on samples prepared with various water contents and densities at the confining pressures of 1.02, 2.04, and $3.06kg/cm^2$. Initial tangent modulus is inferred from the unloading-reloading portion of the stress strain curve obtained during an individual loading-unloading-reloading test. As a result of the analysis, it is found that the effect of the confining pressure on the elastic modulus of subgrade material is well consistent with the equation proposed by Janbu, and that the elastic modulus can be related to the dry unit weight expressing the Janbu constants as exponentiial functions of it. It is also found that the water content has little effect on the elastic modulus for the samples with the degree of saturation less than 70%.

• Journal of Microbiology and Biotechnology
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• v.22 no.1
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• pp.1-12
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• 2012

The present study examines the effects of 30 mg/kg butachlor on the cyanobacterial diversity of rice fields in Eastern Uttar Pradesh and Western Bihar in India. A total of 40 samples were grouped into three classes [(i) acidic, (ii) neutral, and (iii) alkaline soils], based on physicochemical and principle component analyses. Acidic soils mainly harbored Westillopsis, Trichormus, Anabaenopsis, and unicellular cyanobacteria; whereas Nostoc, Anabaena, Calothrix, Tolypothrix, and Aulosira were found in neutral and alkaline soils. Molecular characterization using 16S rRNA PCR and DGGE revealed the presence of 13 different phylotypes of cyanobacteria in these samples. Butachlor treatment of the soil samples led to the disappearance of 5 and the emergence of 2 additional phylotypes. A total of 40 DGGE bands showed significant reproducible changes upon treatment with butachlor. Phylogenetic analyses divided the phylotypes into five major clusters exhibiting interesting links with soil pH. Aulosira, Anabaena, Trichormus, and Anabaenopsis were sensitive to butachlor treatment, whereas uncultured cyanobacteria, a chroococcalean member, Westillopsis, Nostoc, Calothrix, Tolypothrix, Rivularia, Gloeotrichia, Fischerella, Leptolyngbya, and Cylindrospermum, appeared to be tolerant against butachlor at their native soil pH. Butachlor-induced inhibition of nitrogen fixation was found to be 65% (maximum) and 33% (minimum) in the soil samples of pH 9.23 and 5.20, respectively. In conclusion, low butachlor doses may prove beneficial in paddy fields having a neutral to alkaline soil pH.