• Title/Summary/Keyword: Secondary batteries

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Hydrogen Storage Properties of Carbon Nanotube Composites (탄소나노튜브 복합재의 수소저장특성)

  • Ahn, Jung-Ho;Jang, Min-Kyu
    • Journal of Powder Materials
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    • v.15 no.3
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    • pp.188-195
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    • 2008
  • Carbon nanotube (CNT)/$Mg_2Ni$ composites were synthesized to enhance the hydrogen storage properties. The emphasis was made on the effect of different shortening methods of CNTs on the open-tip structure and the resulting properties. The use of open CNTs as a starting material resulted in an enhanced hydrogen properties of CNT/$Mg_2Ni$ composites. Among the employed methods for the shortening of CNTs, wet milling using ethanol was the most efficient, while ultrasonic acid treatment or thermal decomposition resulted in a less hydrogen storage capacity.

Crystallinity and Battery Properties of Lithium Manganese Oxide Spinel with Lithium Titanium Oxide Spinel Coating Layer on Its Surface

  • Ji, Mi-Jung;Kim, Eun-Kyung;Ahn, Yong-Tae;Choi, Byung-Hyun
    • Journal of the Korean Ceramic Society
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    • v.47 no.6
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    • pp.633-637
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    • 2010
  • In this study, lithium manganese oxide spinel ($LiMn_{1.9}Fe_{0.1}Nb_{0.0005}O_4$) as a cathode material of lithium ion secondary batteries is synthesized with spray drying, and in order to increase its crystallinity and electrochemical properties, the granulated $LiMn_{1.9}Fe_{0.1}Nb_{0.0005}O_4$ particle surface is coated with lithium titanium oxide spinel ($Li_4Ti_5O_{12}$) through a sol-gel method. The granulated particles present a higher tap density and lower specific surface area. The crystallinity and discharge capacity of the $Li_4Ti_5O_{12}$ coated material is relatively higher than uncoated material. With the coating layer, the discharge capacity and cycling stability are increased and the capacity fading is suppressed successfully.

Effect of particle size on capacity of $LiMn_2O_4$ as cathode materials of lithium ion secondary batteries for HEV application (HEV용 리튬이온 배터리의 양극물질로 사용되는 $LiMn_2O_4$의 용량에 대한 입자크기의 효과)

  • Jee, Mi-Jung;Choi, Byung-Hyun;Lee, Dae-Jin;Wai, Yin-Loo;Bae, Hyun
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.11a
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    • pp.169-172
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    • 2007
  • HEV용 리튬이온 전지에 대한 연구는 최근에 많은 연구가 진행되고 있으며 그중 고용량 및 저렴한 가격, 환경에 대한 안정성으로 인해 Li-Mn spinel에 대한 성능향상 연구가 많이 이루어지고 있다. 본 연구에서는 Li-Mn spinel의 입자크기에 대한 기초 물성 과 전기적 특성을 측정하여 입자크기가 용량에 미치는 영향에 대한 고찰을 하였다. Li-Mn spinel의 비표면적, C-V 특성, 전기적 용량, coulomb efficiency 등을 통하여 입자의 크기와 전해액, Li의 구동등과 관련하여 용량특성에 향상을 가져오는 입자크기 조건을 정의하였고 그에 따라 온도별로 합성 한 후 입자사이즈에 대한 특성을 나타내었다.

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Electrochemical Properties of Polyaniline Cathode for Lithium Secondary Batteries (리튬 2차 전지용 Polyaniline cathode의 전기화학적 특성)

  • Kim, H.C.;Kim, J.U.;Gu, H.B.;Moon, S.I.
    • Proceedings of the KIEE Conference
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    • 1996.07c
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    • pp.1685-1687
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    • 1996
  • Recently, conducting polymer has been much attracted as novel materials because of its electronic behavior and functional application by doping process. In this paper, we electrochemically synthesized polyaniline films under potential sweep conditions, which exhibit high electric conductivity about 200 S/cm. Specific energy of 600 Wh/kg and Ah efficiency 98% were achieved during the charge/discharge cycling using liquid electrolyte system. On the other hand, consequences of the cycling were 260 Wh/kg and 95% Ah efficiency using polyethylene oxide(PEO) based solid-state electrolyte system.

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Mixture of the Lithium Secondary Batteries and Analyses (리튬 2차전지용 전해액의 초성 및 비교 분석)

  • 임동규;김영호;조봉희;우병원;나두찬
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.11a
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    • pp.395-397
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    • 1999
  • There are many efforts to improve electrolytes to satisfy the requirements of a lithium rechargeable battery. We have investigated a binary solvent mixture containing the electrolyte lithium salt($LiBF_4$, $LiPF_6$), that is conductive and electrochemically stable. Ionic conductivities were measured between -5 and $80^{\circ}C$, and cyclic voltammetry between 2.5 and 4.3 V were measured by SUS or platinum electrode.

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Electrochemical Properties of LiNiO$_2$/Li cell (LiNiO$_2$/Li cell의 전기화학적 특성)

  • 전대규;김철중;성창호;구할본
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.11a
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    • pp.279-282
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    • 1997
  • The propose of this study is research and improvement of LiNiO$_2$as cathode material for Lithium secondary batteries. LiNiO$_2$is prepared by heating LiOH . $H_2O$ and Ni(OH)$_2$(mole ratio 1 : 1) on various heat condition. In the result of XRD mesurement, all LiNiO$_2$prepared at this study showed hexagonal structure. In Cyclic Voltammetry, LiNiO$_2$is not conspicous about oxidation peak but oxidation curve change steeply over 3.8V and reduction peak discover at 3.6V. In discharge capacities, specific capacity is higher $O_2$than air when preliminary heated and 75$0^{\circ}C$ than $700^{\circ}C$, 80$0^{\circ}C$ when heated. Therefore, when preliminary heat at $650^{\circ}C$ $O_2$and heat at 75$0^{\circ}C$ carried out, discharge property is the best.

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Probing of Electrochemical Reactions for Battery Applications by Atomic Force Microscopy

  • Kim, Yun-Seok
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.98.2-98.2
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    • 2013
  • Electrochemical phenomena underpin a broad spectrum of energy, chemical, and information technologies such as resistive memories and secondary batteries. The optimization of functionalities in these devices requires understanding electrochemical mechanisms on the nanoscale. Even though the nanoscale electrochemical phenomena have been studied by electron microscopies, these methods are limited for analyzing dynamic electrochemical behavior and there is still lack of information on the nanoscale electrochemical mechanisms. The alternative way can be an atomic force microscopy (AFM) because AFM allows nanoscale measurements and, furthermore, electrochemical reaction can be controlled by an application of electric field through AFM tip. Here, I will summarize recent studies to probe nanoscale electrochemical reaction in battery applications by AFM. In particular, we have recently developed electromechanical based AFM techniques for exploring reversible and irreversible electrochemical phenomena on the nanoscale. The present work suggests new strategies to explore fundamental electrochemical mechanisms using the AFM approach and eventually will provide a powerful paradigm for probing spatially resolved electrochemical information for energy applications.

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THE SOC ESTIMATION OF THE LEAD-ACID BATTERY USING KALMAN FILTER

  • JEON, YONGHO
    • Journal of applied mathematics & informatics
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    • v.39 no.5_6
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    • pp.851-858
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    • 2021
  • In general, secondary batteries are widely used as an electric energy source. Among them, the state of energy storage of mobile devices is very important information. As a method of estimating a state, there is a method of estimating the state by integrating the current according to an energy storage state of a battery, and a method of designing a state estimator by measuring a voltage and estimating a charge amount based on a battery model. In this study, we designed the state estimator using an extended Kalman filter to increase the precision of the state estimation of the charge amount by including the error of the system model and having the robustness to the noise.

Various Alcohols as Electrolysis Suppressants in Zn-air Secondary Batteries

  • Yang, Soyoung;Kim, Ketack
    • Journal of Electrochemical Science and Technology
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    • v.9 no.4
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    • pp.339-344
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    • 2018
  • The gelling agent used in Zn-air cells plays a role in improving battery life. It prevents the evaporation of water and diffusion of $Zn^{2+}$ ions away from the current collector. Additional functionality was incorporated by replacing some of the gelling agents with new materials. Alcohols with moderate viscosity, namely maltose, sucrose, poly ethylene glycol 600, and 2-hydroxyethyl cellulose, were used to replace some gelling agents in this work. Among these alcohols, poly ethylene glycol 600 and 2-hydroxyethyl cellulose improved the cycle life of full cells. This improved cycle life was attributed to the inhibition of water electrolysis and the improved cycle life of the anode.

Design of Charge and Discharge System for Secondary Batteries (2차 전지용 충방전 시스템 설계)

  • Shim, Jae-Hwe;Lee, Jun-Ha
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2009.10a
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    • pp.690-691
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    • 2009
  • This study intends to discuss the Charge and Discharge Monitoring System for HEV. Study is aim to charge and discharge stability and efficient. This study is include hardware module and application software development. It is possible to maintain charge and discharge performance efficiently.

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