• 자원리싸이클링
• /
• 제27권2호
• /
• pp.68-76
• /
• 2018

전기로 제강분진은 아연, 연, 철의 2차자원으로서 매우 중요하다. 또한 제강분진의 리싸이클링은 분진 중에 함유되어 있는 증금속 성분 등의 유해원소에 의한 환경문제의 처리에 유용한 방법이다. 본 조사는 기존의 전기로 제강분진을 처리하는 방법의 개선이나 새로운 처리방법의 개발을 위해 건식처리 방법에 대하여 알아보았다. 상업중인 처리방법은 노의 형상 등에 따라 로터리 킬른형, 회전노상형, 샤프트형, 용융환원로형 등으로 구분할 수 있었다. 이러한 처리에서의 생성물은 ZnO와 환원철 또는 슬래그이다. 제강분진으로부터 ZnO를 만드는 기구는 탄소 열환원과 공기에 의한 아연증기의 산화에 의한 것이다.

• 한국결정성장학회지
• /
• 제33권1호
• /
• pp.37-44
• /
• 2023

Transition metal (Me = Cu, Fe, Ni) doped (Pr, Ba)Co₂O_5+𝛿 (PBCO) material were investigated in terms of electronic structure change and electrochemical properties. It was confirmed that (Pr, Ba)(Co, Cu)O_5+𝛿 (PBCCu) and (Pr, Ba)(Co, Fe)O_5+𝛿 (PBCFe) showed cubic and orthorhombic structures, respectively, but (Pr, Ba)(Co, Ni)O_5+𝛿 (PBCNi) showed secondary phases. PBCCu has an average particle diameter of 1093 nm, and PBCO and PBCFe have an average particle diameter of 495.1 nm and 728 nm, respectively. The average oxidation values of B site ions in PBCMe were calculated to be 3.26 (PBCO), 2.48 (PBCCu), 3.32 (PBCFe), and valence band maximum (VBM) was -0.42 eV (PBCO), -0.58 eV (PBCCu), -0.11 eV (PBCFe). It is expected that PBCCu easily interacts with adsorbed oxygen due to the lowest oxidation value and the highest VBM. The polarization resistance was 0.91 Ω cm² (PBCO), 0.77 Ω cm² (PBCCu), 1.06 Ω cm² (PBCFe) at 600℃, showing the lowest polarization resistance of PBCCu.

• Asian Journal of Atmospheric Environment
• /
• 제11권4호
• /
• pp.300-312
• /
• 2017

To improve the understanding of secondary organic aerosol (SOA) formation from the photo-oxidation of anthropogenic and biogenic precursors at the regional background station on Baengnyeong Island, Korea, gas phase and aerosol chemistries were investigated using the Proton Transfer Reaction Time of Flight Mass Spectrometer (PTR-ToF-MS) and the Aerodyne High Resolution Time of Flight Aerosol Mass Spectrometer (HR-ToF-AMS), respectively. HR-ToF-AMS measured fine particles ($PM_1$; diameter of particle matter less than $1{\mu}m$) at a 6-minute time resolution from February to November 2012, while PTR-ToF-MS was deployed during an intensive period from September 21 to 29, 2012. The one-minute time-resolution and high mass resolution (up to $4000m{\Delta}m^{-1}$) data from the PTR-ToF-MS provided the basis for calculations of the concentrations of anthropogenic and biogenic volatile organic compounds (BVOCs) including oxygenated VOCs (OVOCs). The dominant BVOCs from the site are isoprene (0.23 ppb), dimethyl sulphide (DMS, 0.20 ppb), and monoterpenes (0.38 ppb). Toluene (0.45 ppb) and benzene (0.32 ppb) accounted for the majority of anthropogenic VOCs (AVOCs). OVOCs including acetone (3.98 ppb), acetaldehyde (2.67 ppb), acetic acid (1.68 ppb), and formic acid (2.24 ppb) were measured. The OVOCs comprise approximately 75% of total measured VOCs, suggesting the occurrence of strong oxidation processes and/or long-range transported at the site. A strong photochemical aging and oxidation of the atmospheric pollutants were also observed in aerosol measured by HR-ToF-AMS, whereby a high $f_{44}:f_{43}$ value is shown for organic aerosols (OAs); however, relatively low $f_{44}:f_{43}$ values were observed when high concentrations of BVOCs and AVOCs were available, providing evidence of the formation of SOA from VOC precursors at the site. Overall, the results of this study revealed several different SOA formation mechanisms, and new particle formation and particle growth events were identified using the powerful tools scanning mobility particle sizer (SMPS), PTR-ToF-MS, and HR-ToF-AMS.

• 동아시아식생활학회지
• /
• 제23권4호
• /
• pp.470-476
• /
• 2013

The property of deep frying oil is one of the important factors in fried food quality. The purpose of this study is to identify the quality of deep frying oil in continuous usages for 4 days by two types of fryers: traditional deep-fat fryer and modified oil-water fryer. After frying pork cutlets, the frying oil was kept not only for several physical analyses such as color, viscosity, and water content but also for the quality analyses of frying oil, such as free fatty acid, double bond changes and oxidative rancidity formation. The oil fried in a traditional deep-fat fryer was significantly increased in terms of physical values including moisture content, viscosity, and color, compared to those of the modified fryer, continuously for 4 days. The oil fried by a traditional deep-fat fryer exhibited a significant increase in its free fatty acid content compared to that fried by a modified oil-water fryer, while the iodine value was significantly decreased in the oil fried by a traditional deep-fat fryer when compared to control oil and oil fried by the modified oil-water fryer. In the peroxide value as an indicator of primary oxidation products, the oil fried by both fryers was significantly increased till the second day but decreased in value after the third day because of unstable hydroperoxide decomposition. The p-anicidine value is used as an indicator of secondary oxidation products, the oil fried in a traditional deep-fat fryer was significantly increased in value compared to that of a modified oil-water fryer.

• Corrosion Science and Technology
• /
• 제12권2호
• /
• pp.102-112
• /
• 2013

A very high-temperature gas reactor (VHTR) is one of the next generation nuclear reactors owing to its safety, high energy efficiency, and proliferation-resistance. Heat is transferred from the primary helium loop to the secondary helium loop through an intermediate heat exchanger (IHX). Under VHTR environment Alloy 617 is being considered a candidate Ni-based superalloy for the IHX of a VHTR, owing to its good creep resistance, phase stability and corrosion resistance at high temperature. In this study, high-temperature corrosion tests were carried out at 850 - $950^{\circ}C$ in air and impure helium environments. Alloy 617 specimens showed a parabolic oxidation behavior for all temperatures and environments. The activation energy for oxidation was 154 kJ/mol in helium environment, and 261 kJ/mol in an air environment. The scanning electron microscope (SEM) and energy-dispersive x-ray spectroscopy (EDS) results revealed that there were a Cr-rich surface oxide layer, Al-rich internal oxides and depletion of grain boundary carbide after corrosion test. The thickness and depths of degraded layers also showed a parabolic relationship with the time. A corrosion rate of $950^{\circ}C$ in impure helium was higher than that in an air environment, caused by difference in the outer oxide morphology.

• 상하수도학회지
• /
• 제26권3호
• /
• pp.409-421
• /
• 2012

Ethanolamine (ETA) is mainly used to prevent corrosion of pipe in secondary cooling system of nuclear power plant. Condensed ETA in wastewater could increase COD and T-N when it was emitted to natural water system. Compared to conventional treatments, electrochemical oxidation process using packed bed bipolar electrodes was adopted to treat COD and T-N. According to arrangement of feeder electrode, single packed bed bipolar electrode reactor and multi-paired packed bed bipolar reactor were developed and conventional zero-valent iron (ZVI) was selected as conducting bipolar electrode. Bipolar electrodes were coordinated three-dimensionally in the reactor. The experimental results showed that COD and T-N was little removed in unit system at different pH condition (pH 8 and 11) on 100V. However, in multi-paired system that applied 600V, COD was eliminated 80.85% (anode-cathode-anode, A-C-A) and 85.11% (cathode-anode-cathode, C-A-C), respectively. T-N was also removed 96.88% (A-C-A) and 90.63% (C-A-C), simultaneously. Current efficiency was estimated both single and multi-paired system. At unit bipolar packed bed reactor, current efficiency was almost zero, however in multi-paired system, current efficiency was 300~500% at A-C-A and 250~350% at C-A-C. Current efficiency was over 100% hence it was confirmed that this system is more effective than conventional electrochemical oxidation system.

• 한국축산식품학회지
• /
• 제35권1호
• /
• pp.71-79
• /
• 2015

This study was performed to determine the effect of multilayered fish oil (FO) emulsion without or with trans-cinnamal-dehyde on pork patties. Multilayered FO (-primary, -secondary, -tertiary) emulsions were prepared using a layer-by-layer deposition technique with Tween 20, chitosan, and low methoxyl pectin, and were added to pork patties at the same concentration. Pork patties were then stored for 20 d in a refrigerator ($5^{\circ}C$) to study changes in quality. The results showed that the pH value of all samples significantly decreased but cooking loss increased during storage (p<0.05). However, water-holding capacity and moisture content showed no remarkable difference between treatments and storage periods (p>0.05). All pork patties containing multilayered FO (treated samples) showed higher values for lightness and significantly lower values for yellowness compared to control pork patties (untreated sample). Lipid oxidation was higher in treated pork patties than in control pork patties during storage. In addition, lipid oxidation and total viable bacterial count in pork patties decreased as the number of coating layers increased. However, hardness, cohesiveness, and springiness of all samples showed no significant change during storage (p>0.05) as compared to fresh pork patties. Furthermore, these did not remarkable change with addition of trans-cinnamaldehyde in all pork patties. From our results, we suggest that FO emulsion did not affect the texture characteristics of fresh pork patties, indicating that it could be used to improve the quality of pork patties by contributing high-quality fat such as unsaturated fatty acids.

• 공업화학
• /
• 제25권2호
• /
• pp.215-221
• /
• 2014

염기 처리에 의한 간단한 방법으로 합성된 $MnO_2$ (B-$MnO_2$)는 불균일 촉매시스템으로 호기성 조건에서 효과적인 아민 산화반응을 보여주었다. 이 B-$MnO_2$ 촉매는 다양한 종류의 방향족, 이원자 화합물, 비활성 지방족 등의 아민의 전환에 높은 활성과 선택성을 보여주었다. 이러한 산화반응은 온화한 온도($50^{\circ}C$)와 대기압의 공기 조건하에서 아민을 중간체인 이민으로 전환하고 자가 축합(self-condensation) 또는 산화적 탈수소화(oxidative dehydrogenation)을 통해 다이이민(diimine) 또는 나이트릴(nitrile)을 생성하였다. 사용된 촉매는 여과로 쉽게 분리할 수 있었고 5번 이상의 재사용 실험에서도 일정이상의 높은 수율을 보여주었다. 따라서 B-$MnO_2$는 아민 산화반응을 통해 이민과 나이트릴을 얻음에 있어 경제적으로나 환경친환적으로 효과적인 면을 보여 줌으로써, 그린화학(green chemistry)의 목적에 적합하다.

• Nuclear Engineering and Technology
• /
• 제45권2호
• /
• pp.211-218
• /
• 2013

Large quantities of irradiated graphite waste from graphite-moderated nuclear reactors exist and are expected to increase in the case of High Temperature Reactor (HTR) deployment [1,2]. This situation indicates the need for a graphite waste management strategy. Of greatest concern for long-term disposal of irradiated graphite is carbon-14 ($^{14}C$), with a half-life of 5730 years. Fachinger et al. [2] have demonstrated that thermal treatment of irradiated graphite removes a significant fraction of the $^{14}C$, which tends to be concentrated on the graphite surface. During thermal treatment, graphite surface carbon atoms interact with naturally adsorbed oxygen complexes to create $CO_x$ gases, i.e. "gasify" graphite. The effectiveness of this process is highly dependent on the availability of adsorbed oxygen compounds. The quantity and form of adsorbed oxygen complexes in pre- and post-irradiated graphite were studied using Time of Flight Secondary Ion Mass Spectrometry (ToF-SIMS) and Xray Photoelectron Spectroscopy (XPS) in an effort to better understand the gasification process and to apply that understanding to process optimization. Adsorbed oxygen fragments were detected on both irradiated and unirradiated graphite; however, carbon-oxygen bonds were identified only on the irradiated material. This difference is likely due to a large number of carbon active sites associated with the higher lattice disorder resulting from irradiation. Results of XPS analysis also indicated the potential bonding structures of the oxygen fragments removed during surface impingement. Ester- and carboxyl-like structures were predominant among the identified oxygen-containing fragments. The indicated structures are consistent with those characterized by Fanning and Vannice [3] and later incorporated into an oxidation kinetics model by El-Genk and Tournier [4]. Based on the predicted desorption mechanisms of carbon oxides from the identified compounds, it is expected that a majority of the graphite should gasify as carbon monoxide (CO) rather than carbon dioxide ($CO_2$). Therefore, to optimize the efficiency of thermal treatment the graphite should be heated to temperatures above the surface decomposition temperature increasing the evolution of CO [4].

• 한국재료학회지
• /
• 제33권7호
• /
• pp.315-322
• /
• 2023

In the present work, we address the new route for the green synthesis of manganese dioxide (MnO₂) by an innovative method named the solution plasma process (SPP). The reaction mechanism of both colloidal and nanostructured MnO₂ was investigated. Firstly, colloidal MnO₂ was synthesized by plasma discharging in KMnO₄ aqueous solution without any additives such as reducing agents, acids, or base chemicals. As a function of the discharge time, the purple color solution of MnO₄^- (oxidation state +7) was changed to the brown color of MnO₂ (oxidation state +4) and then light yellow of Mn²⁺ (oxidation state +2). Based on the UV-vis analysis we found the optimal discharging time for the synthesis of stable colloidal MnO₂ and also reaction mechanism was verified by optical emission spectroscopy (OES) analysis. Secondly, MnO₂ nanoparticles were synthesized by SPP with a small amount of reducing sugar. The precipitation of brown color was observed after 8 min of plasma discharge and then completely separated into colorless solution and precipitation. It was confirmed layered type of nanoporous birnessite-MnO₂ by X-ray powder diffraction (XRD), fourier-transform infrared spectroscopy (FT-IR), and electron microscopes. The most important merits of this approach are environmentally friendly process within a short time compared to the conventional method. Moreover, the morphology and the microstructure could be controllable by discharge conditions for the appropriate potential applications, such as secondary batteries, supercapacitors, adsorbents, and catalysts.