• Bulletin of the Korean Chemical Society
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• v.32 no.9
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• pp.3411-3420
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• 2011

Kinetic and structural studies have been carried out on the effects of meso-tetrakis(4-sulfonatophenyl)-porphyrin ($H_2TPPS_4$) as an anionic and meso-tetrakis(3-N-methyl-pyridyl)porphyrin ($H_2TMPYP$) as a cationic porphyrin with adenosine deaminase (ADA) in 25 mM citrate/phosphate buffer, pH = 4-8, at $37^{\circ}C$ using UVvis spectrophotometry, circular dichroism (CD), fluorescence spectrophotometry as well as molecular dynamics (MD) and molecular docking. Kinetic results showed that the two porphyrins are non-competitive inhibitors. Increasing pH, increases $K_I$ and cationic porphyrin has a higher $K_I$ and lower binding constant ($K_b$) at all pH ranges. Analyzing the secondary structure revealed that both ligands decrease the secondary structure and that the anionic porphyrin is more effective.

• Journal of the Korean Ceramic Society
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• v.34 no.5
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• pp.453-460
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• 1997

Sr-ferrite having magnetoplumbite structure is similar to Ba-ferrite in magnetic characteristics, but better magnetic characteristics for using motor application. To improve remanence magnetic flux density(Br) and coercive force(iHc), it is necessary that sintered ferrites must have high density and grain size less than 1 $\mu$m. By varying n values in SrO.nFe2O3 basic composition, calcination temperature, and BaO addition, Sr-ferrite powder and sintered specimen was prepared. The n values, calcination temperature, and BaO addition affected secondary phase formation, particle size, and particle shape. BaO addition enhanced Fe2O3 secondary phase and hexagonal shape particle. Fe2O3 phase reduced sintered density which greatly decreased Br.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.26 no.7
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• pp.1309-1316
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• 2002

The purpose of this study is to analyze the effects of the parameters of the suspension system in railway rolling-stock for KT-23 type passenger vehicle. According to the results of simulation and the field test, Optimal condition was obtained for the stiffness ratio of the primary spring and the secondary of the suspension system. When the stiffness ratio was increased, the vibration was increased on the car body and decreased on the bogie, and ride quality are getting worse because of increase of the vertical natural frequency of the car body. The results of this study are usefull to improve the technology of the ride quality of KT-23 type vehicle.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.30 no.1 s.244
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• pp.48-56
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• 2006

We investigated gas residence time and mixing characteristics due to various swirl numbers generated by normal injection of secondary air to a lab-scale cylinderical combustor. The residence time was estimated by measuring the temporal pressure difference which was caused by deposition of test particles on a filter media after the injection by a syringe. The mixing characteristics were evaluated by standard deviation value of test gas concentration at different measuring points. The test gas concentration was detected by a gas analyzer. The swirl number of $20{\sim}30$ for ${\theta}=5^{\circ}$ caused long residence time enough to improve mixing characteristics. Numerical calculations were also carried out to understand physical meanings of the experimental results.

• Proceedings of the KSME Conference
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• 2001.11b
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• pp.102-105
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• 2001

Numerical simulations of coal combustion were carried out to identify what kind of burner design parameters are affecting the NOx emission. Where used burner design parameters are primary air velocity, secondary air velocity, $2^{nd}/3^{rd}$ air ratio, tertiary air velocity, and tertiary air injection location. Taguchi method was used to find the effective burner design parameters related to NOx formation. The results of numerical simulations showed that secondary air velocity and $2^{nd}/3^{rd}$ air ratio was the key parameters reducing the NOx emission. The total number of simulation cases was reduced by Taguchi method.

• Bulletin of the Korean Chemical Society
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• v.32 no.7
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• pp.2306-2310
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• 2011

The nucleophilic substitution reactions of diethyl thiophosphinic chloride with substituted anilines ($XC_6H_4NH_2$) and deuterated anilines ($XC_6H_4ND_2$) are investigated kinetically in acetonitrile at 55.0 $^{\circ}C$. The values of deuterium kinetic isotope effects (DKIEs; $k_H/k_D$) invariably increase from secondary inverse ($k_H/k_D$ < 1) to primary normal (kH/kD > 1) as the nucleophiles change from the strongly basic to weakly basic anilines. The secondary inverse with the strongly basic anilines and primary normal DKIEs with the weakly basic anilines are rationalized by the gradual transition state (TS) variation from a predominant backside attack, via invariably increasing the fraction of a frontside attack, to a predominant frontside attack, in which the reaction mechanism is a concerted $S_N2$ pathway. A frontside attack involving a hydrogen bonded, four-center-type TS is substantiated by the primary normal DKIEs.

• Proceedings of the KSR Conference
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• 2007.05a
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• pp.916-921
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• 2007

In this paper, the inductive power collector using electromagnetic induction for vehicle such as the electric railway vehicle system is suggested and some ideas for power collector design to improve the power transfer performance are presented. The inductive power of secondary part is related to amount of linked flux to secondary part by the length of air-gap, which is expected by such a system parameter as mutual inductance. This paper will study for the transfer characteristic of power from input to output and equation including mutual inductance. And also, effect of leakage inductance variation of inductive power collector according to structure of winding was considered.

• Journal of Korean Society of Water and Wastewater
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• v.20 no.4
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• pp.535-543
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• 2006

The Ozone oxidation process was applied to increase the efficiency of reuse process when treating the secondary effluent by the membrane system. This paper focus on decreasing efficiency of membrane fouling, because of membrane fouling reduction by ozone and evaluation of application of the ozone oxidation. The feed water was secondary effluent from BNR process. The result shows that the ozone pretreatment can reduce membrane fouling effectively. Also, the improvement of treated water quality was obvious. The reduction of the membrane fouling led decrease of following pollutant and increase of lnner adsorptive ability of hydrophilic organic matter and decrease of molecular weight. MF membrane process alone can meet the domestic reuse water standards. And ozone pretreatment process also can increase the removal rates of turbidity, COD, nitrogen, and color.

• Bulletin of the Korean Chemical Society
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• v.34 no.4
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• pp.1096-1100
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• 2013

The kinetic studies on the reactions of O-methyl (1), O-propyl (3) and O-isopropyl (4) phenyl phosphonochloridothioates with substituted anilines and deuterated anilines have been carried out in acetonitrile at $55.0^{\circ}C$. A concerted $S_N2$ mechanism is proposed for the anilinolyses of 1, 3 and 4. The anilinolysis rates of the phosphonochloridothioates are predominantly dependent upon the steric effects over the inductive effects of the two ligands. The deuterium kinetic isotope effects (DKIEs; $k_H/k_D$) are primary normal with 1 and 3, while secondary inverse with 4. Primary normal and secondary inverse DKIEs are rationalized by frontside and backside nucleophilic attack transition state, respectively. The DKIEs of the phosphonochloridothioates do not have any consistent correlations with the two ligands.

• Journal of Korea Foundry Society
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• v.37 no.4
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• pp.108-114
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• 2017

In this study, we investigated the effect of the Si content on the secondary dendrite arm spacing (SDAS) of hypoeutectic Al-Si binary alloys in the range of 4~10 wt% Si. Cooling curves were measured during the solidification of the alloy cast in a step-wise mold. We compared two kinds of solidification time: the first is the total solidification time for both dendritic and eutectic growth, and the second is the solidification time for only dendritic growth. The proportional constant in the relationship between SDAS and cooling rate was estimated, as this constant represents the stability of the cast microstructure. The proportional constant decreased with the Si contents from 4 wt% to 8 wt%, and it remains relatively uniform with up to 10 wt% of Si.