• Proceedings of the Korea Water Resources Association Conference
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• 2010.05a
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• pp.889-893
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• 2010

전 세계적으로 기후변화에 따른 주기적인 가뭄 현상과 기상 이변으로 인해 물 부족 사태는 심각해져 가고 있으며(UNEP은 물 기근에 시달리는 세계 도시 곳곳에 사는 많은 사람들은 2000년 5억 명에서 2025년 40억 명까지 증가할 것이라고 추측하였다), 산업화 이후 인구의 증가와 산업의 발달에 따른 삶의 질을 향상시키기 위한 물의 수요 또한 증가하고 있는 추세다. 그러나 인간이 사용 가능한 수자원은 지구상에 존재하는 물의 3% 이내로 한정되어 있으며 산업발달 및 도시화에 따른 지표수의 바다로의 유출 또한 빨라져 지하수개발, 하수재이용, 인공강우 및 해수담수화 등의 대체수자원의 개발이 요구되는 실정이다. 본 연구에서는 Global Water Intelligence(GWI)의 자료를 기초로 하여 중동 및 북아프리카 지역 20개 국가를 대상으로 생활 용수 자본지출 추세, 공업용수 수요 시장규모 성장추세, 이용가능한 수자원 및 그에 따른 사용 중인 수자원 비율, 2007년 기준 물 부족 인구, 2011년~2016년 물 부족 인구를 조사 및 분석하였다. 용도별 생활용수 공업 용수의 추세 분석 기간은 2008년부터 2016년까지 실시하였으며 평균 연감 증가 백분율 5%이상 국가를 선정하였다. 중동 및 북아프리카 지역 20개 국가 중 18개 국가가 생활용수 자본지출 연감 증가 백분율 5%이상의 높은 수요 전망을 보였으며, 공업용수 수요 시장 전망은 높은 성장성을 보이며 큰 규모의 주요 2개 국가가 선정되었다. 또한 20개 국가 각각의 이용 가능한 수자원 및 그에 따른 사용 중인 수자원 비율, 2006년 기준물 부족 인구, 2011~2016년 물 부족 인구를 조사한 결과 전체 20개 국가 모두 물 부족 국가로 산정되었으며, 20개 국가 모두 해안지역에 위치해 있어 해수담수화 시설의 건설 가능성이 높은 지역인 것을 확인하였다. 조사한 중동 및 북아프리카 지역 중 많은 수의 국가가 물 부족 현상에 시달리고 있으며 물 수요 시장 전망 또한 증가할 것으로 나타나 대체수자원의 필요성은 증대될 것으로 판단되며 그에 따라 본 연구는 향후 국내 기업들이 세계 해수담수화 시장에 진출하는데 있어 진출 전략 마련에 기초가 될 것이라고 판단된다.

• Journal of Adhesion and Interface
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• v.20 no.3
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• pp.110-115
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• 2019

Graphene oxide has been gathering interests as a way to exfoliate graphene. Since the oxidation group of graphene oxide can hydrogen bond with various functional groups, tremendous efforts have been actively conducted to apply various applications. However, graphene oxide alone cannot substantially possess the mechanical properties required for the practical application. Therefore, in this study, polydopamine, which is a bio-mimetic mussel protein-inspired material, was combined with graphene oxide to form a large-area composite membrane at the liquid-gas interface. In addition, the morphology of the polydopamine-graphene oxide composite thin film was also controlled to obtain a composite membrane having a nano-wrinkle structure. It can be expected to be used in the next generation seawater desalination membranes or carbon composites because it can form mechanically superior and sophisticated nanostructures.

• Journal of Korean Society of Water and Wastewater
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• v.35 no.1
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• pp.93-100
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• 2021

Forward osmosis (FO) process is a chemical potential driven process, where highly concentrated draw solution (DS) is used to take water through semi-permeable membrane from feed solution (FS) with lower concentration. Recently, commercial FO membrane modules have been developed so that full-scale FO process can be applied to seawater desalination or water reuse. In order to design a real-scale FO plant, the performance prediction of FO membrane modules installed in the plant is essential. Especially, the flux prediction is the most important task because the amount of diluted draw solution and concentrate solution flowing out of FO modules can be expected from the flux. Through a previous study, a theoretical based FO module model to predict flux was developed. However it needs an intensive numerical calculation work and a fitting process to reflect a complex module geometry. The idea of this work is to introduce deep learning to predict flux of FO membrane modules using 116 experimental data set, which include six input variables (flow rate, pressure, and ion concentration of DS and FS) and one output variable (flux). The procedure of optimizing a deep learning model to minimize prediction error and overfitting problem was developed and tested. The optimized deep learning model (error of 3.87%) was found to predict flux better than the theoretical based FO module model (error of 10.13%) in the data set which were not used in machine learning.

• Membrane and Water Treatment
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• v.13 no.5
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• pp.235-243
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• 2022

The paper presents the effect of operating temperatures and flow rates on the distillate flux that can be obtained from a hydrophobic membrane having the characteristics: pore size of 0.15 ㎛; thickness of 130 ㎛; and 85% porosity. That membrane in the present investigation could be the direct contact (DCMD) or the air-gap membrane distillation (AGMD). To model numerically the membrane distillation processes, the two-dimensional computational fluid dynamic (CFD) is used for the DCMD and AGMD cases here. In this work, DCMD and AGMD models have been validated with the experimental data using different flows (Parallel and Counter-current flows) in non-steady-state situations. A good agreement is obtained between the present results and those of the experimental data in the literature. The new approach in the present numerical modeling has allowed examining effects of the nature of materials (Polyvinylidene fluoride (PVDF) polymers, copolymers, and blends) used on thermal properties. Moreover, the effect of the area surface of the membrane (0.021 to 3.15 ㎡) is investigated to explore both the laminar and the turbulent flow regimes. The obtained results found that copolymer P(VDF-TrFE) (80/20) is more effective than the other materials of membrane distillation (MD). The mass flux and thermal efficiency reach 193.5 (g/㎡s), and 83.29 % using turbulent flow and an effective area of 3.1 ㎡, respectively. The increase of feed inlet temperatures and its flow rate, with the reduction of cold temperatures and its flow rate are very effective for increasing distillate water flow in MD applications.

• Membrane Journal
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• v.33 no.3
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• pp.87-93
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• 2023

Electrodialysis (ED) is essential in separating ions through an ion exchange membrane. The disposal of brine generated from seawater desalination is a primary environmental concern, and its recycling through membrane separation technology is highly efficient. Alkali is produced by several chemical industries such as leather, electroplating, dyeing, and smelting, etc. A high concentration of alkali in the waste needs treatment before releasing into the environment as it is highly corrosive and has a chemical oxygen demand (COD) value. The concentration of calcium and magnesium is almost double in brine and is the perfect candidate for carbon dioxide adsorption, a major environmental pollutant. Sodium hydroxide is essential for the metal carbonation process which, is easily produced by the bipolar membrane electrodialysis process. Various strategies are available for its recovery, like reverse osmosis (RO), nanofiltration (NF), ultrafiltration (UF), and ED. This review discusses the ED process by ion exchange membrane for alkali recovery are discussed.

• Prospectives of Industrial Chemistry
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• v.14 no.6
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• pp.21-28
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• 2011

이온교환막을 이용한 전기적 탈염기술은 막모듈 내에 양이온교환막과 음이온교환막을 교대로 장착시키고 모듈의 양단 전극에 전압을 적용함으로써 물속에 용존되어 있는 양이온과 음이온들을 전기의 힘을 이용하여 선택적으로 투과시키는 원리를 기반으로 하는 청정공정 기술이다. 이온교환막 공정은 전통적으로 산/알칼리의 생산, 산업폐수의 중금속의 제거, 해수의 담수화, 반도체 산업의 초순수의 제조, 해수에서 식염의 제조, 발효산업의 유기산 및 아미노산의 회수 등 다양한 산업분야에서 응용되어 왔다. 최근에는 이러한 기존의 응용분야에서 벗어나 새롭게 응용분야가 넓어지고 있다. 이온교환막과 다공성 탄소전극을 결합한 막축전식 해수담수화기술, 해수와 담수의 염도차를 이용한 역전기투석식 해수발전 등의 새로운 선택분리기능 및 응용분야를 가진 이온교환막의 개발 및 공정에 관한 연구가 활발히 이루어지고 있다. 그러나 국내에서는 이온교환막이 아직 상용화되지 않고 있어 이온교환막을 이용한 응용연구가 활발하게 진행되지 못하고 있어 그 개발이 시급하다. 본 논문에서는 먼저 이온교환막을 이용한 전기투석식 탈염기술, 물분해 전기투석, 전기탈이온 공정에 관한 동향을 조사하였다. 아울러 미래의 이온교환막의 응용기술인 해수담수화기술로서 역삼투법과 경쟁하여 에너지를 낮게 소모할 것으로 예상되는 분리막을 이용한 막축전식 탈염기술과 무한한 신재생에너지원인 해수와 담수를 이용한 역전기투석 해수발전기술에 대해 기술의 원리들과 최근의 연구동향 등을 정리하였다.

• Membrane Journal
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• v.28 no.2
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• pp.96-104
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• 2018

With the rapid increase in seawater desalination, the importance of boron rejection is rising. This study was conducted to investigate the effect of hydrophilic compounds on surface modification to maximize water flux and increase boron rejection. First, polyamide active layer was fabricated by interfacial polymerization of polysulfone ultrafiltration membrane with M-phenylenediamine (MPD) and trimesoyl chloride (TMC) to obtain Control polyamide membrane. Next, D-gluconic acid (DGCA) and D-gluconic acid sodium salt (DGCA-Na) were synthesized with glutaraldehyde (GA) and hydrochloric acid (HCl) by modifying the surface of Control polyamide membrane. XPS analysis was carried out for the surface analysis of the synthesized membrane, and it was confirmed that the reaction of surface with DGCA and DGCA-Na compounds was performed. Also, FE-SEM and AFM analysis were performed for morphology measurement, and polyamide active layer formation and surface roughness were confirmed. In the case of water flux, the membrane fabricated by the surface modification had a value of 10 GFD or less. However, the boron rejection of the membranes synthesized with DGCA and DGCA-Na compounds were 94.38% and 94.64%, respectively, which were 12.03 %p and 12.29 %p larger than the Control polyamide membrane, respectively.

• Journal of the Korean Society for Marine Environment & Energy
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• v.15 no.2
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• pp.118-125
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• 2012

World population has increased rapidly following the industrial revolution, reaching 7 billion in 2012. Several forecasts estimate that this number will rise to about 8 billion in 2025. Improvements of living standards in developing nations have also raised resource and energy demands worldwide. In consequences, human beings have faced many global and urgent problems, such as global warming, water and food shortages, resource and energy crises, and so on. Many ocean utilization technologies for avoiding or reducing such big problems have been developed, for examples $CO_2$ ocean sequestration, seawater desalination, artificial upwelling, deepwater mining, and ocean energies. It is important, however, to assess such technologies from the viewpoints of sustainability and public acceptancy, since the aims of those technologies are to develop sustainable social systems rather than conventional ones based on fossil resources. Inclusive Marine Pressure Assessment and Classification Technology Research Committee (generally called IMPACT Research Committee) of Japan Society of Naval Architects and Ocean Engineers, has proposed Inclusive Impact Index "Triple I" as an indicator, which can predict both environmental sustainability and economical feasibility, in order to assess the ocean utilization technologies from the viewpoints of sustainability and public acceptancy. This index was considered by combining Ecological Footprint and Environmental Risk Assessment. The Ecological Footprint and the Environmental Risk Assessment are introduced in the first part of this paper. Then the concept and the structure of the Triple I are explained in the second part of this paper. Finally, the economy-ecology conversion factor in Triple I accounting is considered.

• Membrane Journal
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• v.26 no.4
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• pp.239-252
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• 2016

Two-dimensional materials offer unique characteristics for membrane applications to water technology. With its atomic thickness, availability and stackability, graphene in particular is attracting attention in the research and industrial communities. Here, we present a brief overview of the recent research activities in this rising topic with bringing two membrane architecture into focus. Pristine graphene in single- and polycrystallinity poses a unique diffusion barrier property for most of chemical species at broad ambient conditions. If well designed and controlled, physical and chemical perforation can turn this barrier layer to a thinnest feasible membrane that permits ultimate permeation at given pore sizes. For subcontinuum pores, both molecular dynamics simulations and experiments predict potential salt rejection to envisage a seawater desalination application. Another novel membrane architecture is a stack of individual layers of 2D materials. When graphene-based platelets are chemically modified and stacked, the interplanar spacing forms a narrow transport pathway capable of separation of solvated ions from pure water. Bearing unbeknownst permeance and selectivity, both membrane architecture - ultrathin porous graphene and stacked platelets - offer a promising prospect for new extraordinary membranes for water technology applications.

• Membrane Journal
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• v.22 no.5
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• pp.369-380
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• 2012

A one-dimensional numerical model based on the energy and mass equations have been developed to predict the trans membrane water vapor flux and thermal efficiency under various operating conditions in Direct Contact Membrane Distillation (DCMD) process. The model validation have been carried out by experimental data from literature and showed good agreement. The effect of operating parameters such as brine inlet temperature and velocity, and distillate inlet temperature and velocity to increase water vapor flux and thermal efficiency were predicted by the steady-state model. The results showed that the inlet temperature and velocity in brine side are dominant factors to control the water vapor flux and thermal efficiency because the effect of inlet temperature and velocity in brine side showed the higher water vapor flux and thermal efficiency than that of inlet temperature and velocity in distillate side. The water vapor flux was increased 3.4 times in the range of 21.22 $kg/m^2h$ to 71.26 $kg/m^2h$ and the thermal efficiency was increased 37.5% in that of 0.556 to 0.765 with increasing brine inlet temperature from $60^{\circ}C$ to $95^{\circ}C$. Meanwhile, the water vapor flux was increased 30% in that of 27.91 $kg/m^2h$ to 36.33 $kg/m^2h$ and thermal efficiency increased 7.5% in that of 0.6 to 0.646 as the brine inlet velocity was increased from 60 m/h to 300 m/h.