• Ocean and Polar Research
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• v.30 no.3
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• pp.225-238
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• 2008

In order to investigate the effects of intertidal sediments on the nutrient cycle in coastal environments, the benthic fluxes of ammonium, nitrate, nitrite, phosphate, and silicate at two stations on the intertidal flat of Keunso Bay were determined during each season. The efflux of ammonium was observed at S1 and resulted from the diffusion of remineralized ammonium and acceleration caused by the bioirrigation of macrofauna. The influx of ammonium at S2 was probably due to nitrification in the water column. The influx of nitrate was observed at both stations during all seasons, indicating that the nitrate in the pore water was removed by denitrification. Vigorous bioirrigation led to the efflux of dissolved inorganic nitrogen (DIN) at S1, whereas the influx of DIN at S2 was predominantly caused by denitrification. Contrary to the diffusive and bio-irrigated release of remineralized phosphate from the sediment at S1, the influx of phosphate was observed at S2, which may be attributable to adsorption onto iron oxides in the aerobic sediment layer. Silicate, which is produced by the dissolution of siliceous material, was mostly released from the sediment by molecular diffusion and bioirrigation. However, the influx of silicate was observed at S2 during spring and winter, which was ascribed to adsorption by particulate matter or assimilation by benthic microphytes. The annual fluxes of DIN were 328 mmol $m^{-2}yr^{-1}$ at S1 and -435 mmol $m^{-2}yr^{-1}$ at S2. The annual fluxes of phosphate were negative at both sites (-2.8 mmol $m^{-2}yr^{-1}$ at S1 and -28.9 mmol $m^{-2}yr^{-1}$ at S2), whereas the annual fluxes of silicate were positive at both sites (843 mmol $m^{-2}yr^{-1}$ at S1 and 243 mmol $m^{-2}yr^{-1}$ at S2).

• Journal of Korean Society for Atmospheric Environment
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• v.22 no.4
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• pp.477-486
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• 2006

Dry deposition fluxes for $SO_2$, particulate sulfate, nitrate, ammonium and $HNO_3$ were estimated in urban area for the time period January$\sim$ October 2005. Fluxes were generated using atmospheric concentration data collected both in Acid Deposition and Air Quality Monitoring Networks, and deposition velocities computed by combining land-use data with meteorological information. The resulting annually averaged $SO_2$, $NO_3$, and aerosol deposition velocities were found to be 0.4 cm/s, 4.3 cm/s and 0.1 cm/s, respectively, and thus deposition rates were 4.4 mg/$m^2$. day for $SO_2$, and 5.4 mg/$m^2$ . day for $NHO_3$, and particulate sulfate, ammonium and nitrate recorded 1.0 mg/$m^2$ . day, 0.4 mg/$m^2$ . day and 0.4 mg/$m^2$ day, respectively. Maximum for in seasonal variation of monthly averaged deposition velocities occurred in summer in contrast to $HNO_3$ showing peak in spring. There was no significant variation for aerosol. The dry to total (wet and dry) deposition contributed about 40% for sulfur and 28% for nitrogen species in this study.

• Journal of the Korean Geographical Society
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• v.44 no.4
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• pp.429-446
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• 2009

To understand the sulfur flux and cycle in the forest catchment, the hydrological processes and chemical variation of soil solution, groundwater and stream water were analyzed at the Matsuzawa catchment located in the Kiryu Experimental Basin, Shiga Prefecture, central Japan. Unsaturated soil layer at the upper slope of catchment was the source area of ${SO_4}^{2-}$, and deep soil layer and groundwater were the sink zone of ${SO_4}^{2-}$. The vertical distribution of ${SO_4}^{2-}$ concentrations in groundwater affected seasonal variation of ${SO_4}^{2-}$ concentrations in stream water, as groundwater level changed. It is reasonable to assume that each hydrological processes in the forest catchment play an important roles in the retention and discharge of ${SO_4}^{2-}$.

• Journal of Korean Society for Atmospheric Environment
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• v.22 no.3
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• pp.337-351
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• 2006

In this study, to describe the basic characteristics of strong odorous sources, the emissions of odorous compounds from a large-scale sewage treatment plant in K city were investigated. According to this study, the emission patterns of major odorous compounds were distinguished clearly by several factors such as treatment processing types, chemical compositions of odors released, and temporal changes (e.g., seasonal variations). For the purpose of this study, emission rates of odorous compounds were quantified using a dynamic flux chamber (DFC) method from three major treatment (T) processes including T1 (Grit sedimentation basin), T2 (Aeration tank), and T3 (Final sedimentation). When the relative strengths of each emission source were compared, the strongest one was seen from T1 with the maximum of $NH_{3}\;(34.5\;{\mu}g/m^{2}/min)$ followed by $H_{2}S\;(20.4\;{\mu}g/m^{2}/min)($. While the strongest emissions of most odorous compounds were seen commonly from T1, those seen from T2 and T3 were significantly reduced relative to the ones found in T1. Considering the general patterns of odorous emission, it is concluded that control of odors from T1 unit is most important because of its considerably high emission strengths.

• Proceedings of the Korean Society of Agricultural Engineers Conference
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• 1999.10c
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• pp.155-161
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• 1999

The land reclamation area of Saemangeum(Kunsan) is located between 126$^{\circ}$10' E~126$^{\circ}$50' E and 35$^{\circ}$35' N~356$^{\circ}$05'N at the western coast of the Korean peninsula. The are many small islands including extensive areas of semi-diurnally flooded and dewatered tidal flats. The reclamation area of Saemangeum has a range of 5.6m spring tide and the maximum tidal current speed is about 1.41m s-1 in ordinary spring tide. Most of the sediments deposited on the tidal flats are transported from the Geum river, the Manjyung river and The Dongjin river. The soil in this area consists of silty sand with the depth of 10m to 30m . The wind in winter is strong from the direction of northwest. In the past twenty years, land reclamation projects for agricutural purpose or industrial cocmplex have been mostly implemented along the western coast of Korea. Saemangeum coastal area is being constructed the33km sea dike and 40, 100ha reclamation area. The purpose of this study is to find the residual circulations in four seasons after the dike construction by a robust diagnostic and prognostic numerical model. Heat flux at the sea surface in January ,May , August , October was asopted on the basis on the daily inflow of solar radiation at the earth surface, assuming an average atomospheric transmission and no clouds , as a function of latitude and time of year(George L.P.J.E William, 1990). The discharge from the Geum , the Mankyung and the Dongjin rivers was adopted on the basis of experience formula of river flow in January , May ,August, October (The M. of C.Korea, 1993) . Water temperature and salinity along the open boundaries are obtained from the results of field observation s.

• Korean Journal of Soil Science and Fertilizer
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• v.21 no.1
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• pp.15-19
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• 1988

Heat energy distribution forming net radiation above corn canopy was determined by means of the Bowen ratio-energy balance method. Total-global solar radiation above crop canopy during the growing season was $1,559MJm^{-2}$ and total latent heat flux density was $960MJm^{-2}$. The data showed that 61.6% of the global solar radiation was used for a heat source of evapotranspiration (ETa) above corn canopy. Mean daily ETa ranged from 2.7 to 5.6mm. Total ETa, total drymatter, and water use efficiency were 394mm, $2,214gm^{-2}$, and $5.6gm^{-2}mm^{-1}$, respectivively.

• Journal of Climate Change Research
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• v.7 no.4
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• pp.397-405
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• 2016

For better understand of the soil respiration characteristic in ecosystem, it is necessary to accurately determine the daily, monthly and seasonal $CO_2$ flux related to various environmental factors. In general, soil respiration is being measured on a sunny day. But soil respiration is known to be affected by soil temperature and soil moisture content. In case of forestry, changes in soil moisture content are entirely dependent on rainfall. If we calculated the monthly soil respiration measured based on sunny days data only, it could be a factor that loses credibility soil respiration. On this study, we measured soil respiration on Pinus koraiensis plantation at Mt. Taehwa of Gwangju, Gyeonggi-do on sunny and rainy days in 2012, using Automatic Open-Closed Chamber system (AOCC) and portable $CO_2$ analyzer (GMP343). Then we computed the regression equations using sunny days data, precipitation less than 10 mm data, and precipitation over 10 mm data. At first, there were no significant differences in observed data and computed data. But less than 10 mm precipitation, computed data was 26.5% lower than observed data. Precipitation over 10 mm, on the other hand, the former was 29.3% higher than the latter. In each case, it showed significant differences between observed and computed data (p<0.05). So if we computed regression equation using soil respiration measured sunny days only, about 30% of annual soil respiration could be overestimated. Through further study, we suggest the subdivision and computation of regression equation on the basis of the rainfall intensity.

• Journal of Korea Water Resources Association
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• v.56 no.4
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• pp.285-299
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• 2023

Estimating the evapotranspiration is very important factor for effective water resources management, and FAO Penman-Monteith (FAO P-M) model has been applied for reference evapotranspiration estimation by many researchers. However, because various input data are required for the application of FAO P-M model, understanding the effect of each input data on FAO P-M model is necessary. Therefore, in this study, for 56 study stations located in South Korea, the effects of 8 meteorological factors (maximum and minimum temperature, wind speed, relative humidity, solar radiation, vapor pressure deficit, net radiation, ground heat flux), energy and aerodynamic terms of FAO P-M model, and elevation on FAO P-M reference evapotranspiration (RET) estimation were analyzed. The relative sensitivity analysis was performed to determine how 10% increment of each specific independent variable affects a reference evapotranspiration under given set of condition that other independent variables are unchanged. Furthermore, to select the 5 representative stations and perform the monthly relative sensitivity analysis for those stations, 56 study stations were classified into 5 clusters using cluster analysis. The study results showed that net radiation was turned out to be the most sensitive factor in 8 meteorological factors for 56 study stations. The next most sensitive factor was relative humidity, solar radiation, maximum temperature, vapor pressure deficit and wind speed, followed by minimum temperature in order. Ground heat flux was the least sensitive factor. In case of ground surface condition, elevation showed very low positive relative sensitivity. Relativity sensitivities of energy and aerodynamic terms of FAO P-M model were 0.707 for energy term and 0.293 for aerodynamic term respectively, indicating that energy term was more contributable than aerodynamic term for reference evapotranspiration. The monthly relative sensitivities of meteorological factors showed the seasonal effects, and also the relative sensitivity of elevation showed different pattern each other among study stations. Therefore, for the application of FAO P-M model, the seasonal and regional sensitivity differences of each input variable should be considered.

• Proceedings of The Korean Society of Agricultural and Forest Meteorology Conference
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• 2013.11a
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• pp.23-24
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• 2013

Micrometeorological fluxes measured over a tall forest in a complex terrain are difficult to interpret. $CO_2$ storage often makes significant contributions to net ecosystem exchange of $CO_2$ (NEE) in early morning and during nighttime due to calm and stable conditions. We measured the above-canopy $CO_2$ flux along with its concentration profiles at eight levels within and above the canopy to evaluate $CO_2$ storage term. Our question is whether or not the $CO_2$ storage term can be estimated accurately from a single level measurement of $CO_2$ concentration in a complex terrain. Our objectives are (1) to document vertical profiles of $CO_2$ concentration and (2) to compare the diurnal and seasonal variations of $CO_2$ storages estimated from single and multi-level $CO_2$ concentration data. Seasonally averaged Diurnal variations of $CO_2$ concentration ranged from 398 to 455 ppm near the forest floor at 0.1 m whereas they ranged from 364 to 395 ppm at 40 m in the atmosphere. The diurnal variation of vertical profiles of $CO_2$ concentration shows very interesting features with season. At all eight levels, diurnal variation of $CO_2$ concentration showed little change in winter. In spring, the diurnal variations of $CO_2$ concentration at 8 levels showed three distinct groups of layers with height: the first layer: 0.1m (near surface), second layer: 1.0 m and 4.0m (below canopy) and the third layer: 7.4m to 40.7 m (near canopy and above). In summer, these three groups of layers were further separated with larger variations whereas such distinction became smaller in fall. The diurnal variation of $CO_2$ concentration in the first three layers near surface always showed higher concentration with larger variability. Typically, $CO_2$ concentration showed peaks in early morning and in the evening. After the evening peak, $CO_2$ concentration gradually increased except for those near the surface (i.e., 0.1, 1.0 and 4.0 m) where the concentrations actually decreased. We suspect that this could be attributed to the drainage flow of $CO_2$ along the hill slope from the headwater to downstream, which is not taken into account for net ecosystem $CO_2$ exchange. In comparison to the results of other studies, the distinct and different vertical structures of $CO_2$ concentrations observed at our site may be due to complex terrain and weak turbulent mixing under calm conditions at the site. The annual mean of diurnal variation of $CO_2$ storage flux from single level ranged from -0.6 to $0.9{\mu}mol\;m^{-2}s^{-1}$ and from multi-level from -1.2 to $1.0{\mu}\;{\mu}mol\;m^{-2}s^{-1}$. When compared against the results from the multi-level concentrations, the storage flux estimated from a single-level concentration was generally adequate except for specific hours near sunrise and sunset. Further details and their implication will be discussed in the presentation.

• Korean Journal of Environmental Agriculture
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• v.38 no.4
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• pp.338-351
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• 2019

BACKGROUND: To investigate distribution and seasonal variation of concentration and flux of pesticides in Han river basin, water samples were examined at 24 sites in 2012 and 2014. METHODS AND RESULTS: Water samples were collected four times per year and subjected to liquid-liquid partition extraction followed by GC-ECD/NPD analysis. Of fifteen pesticides detected, iprobenfos, diazinon, isoprothiolane, endosulfan sulfate and oxadiazon were detected in a higher frequency, while fenoxanil, carbofuran, fenitrothion, butachlor and metolachlor were only detected in a sample. Pesticides with high occurrences, iprobenfos, diazinon, isoprothiolane, endosulfan sulfate and oxadiazon were detected in residue level of 0.01-0.46, 0.01-0.24, 0.03-0.85, 0.02-0.06 and 0.05-0.24 ㎍/L, respectively. Carbofuran and acetanilide herbicides were found at lower frequencies, but their concentrations were one order of magnitude higher than those of the others. CONCLUSION: Discharge of pesticides in downstream area were mainly contributed from rice farming and suburban horticulture, while pesticide occurrences in upstream area, such as Donggang river basin were caused by highland agriculture for cabbage and potato production. Despite the influx of pesticides from tributaries through intensive agriculture areas, pesticide concentration in the main stream water was low due to the dilution effect from the upstream. Therefore, the water quality was considered to be good at the most downstream, the effluent of Paldang dam.