• Title/Summary/Keyword: Scattering process

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Ostwald Ripening in Hydrogenated Lecithin-stabilized Oil-in-Water Nano-emulsions (수첨 레시틴으로 안정화된 오일/물 나노에멀젼에서의 Ostwald Ripening)

  • Cho, Wan-Goo;Yang, Hee-Jung;Park, Soo-Nam
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.34 no.1
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    • pp.9-14
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    • 2008
  • Formation of oil-in-water nano-emulsions has been studied in oil/hydrogenated lecithin/water systems by two shear different instrument. The influence of surfactant concentration on nano-emulsion droplet size and stability has been studied. Droplet size was determined by dynamic light scattering, and nano-emulsion stability was evaluated by measuring the variation of droplet size as a function of time. The results obtained showed that the breakdown process of nano-emulsions studied could be attributed to Ostwald ripening. An increase of nano-emulsion instability with increase in surfactant concentration was found in the droplet size in the range of 100~200nm, however, an decrease of instability was found in the droplet size in the range of 300~400nm.

SAXS and AFM Study on Porous Silicon Prepared by Anodic Etching in HF-based Solution (SAXS와 AFM에 의한 HF-용액내 양극 에칭에 의해 제조된 기공성 실리콘의 구조연구)

  • Kim, Eu-gene;Kim, Hwa-Joong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.11
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    • pp.1218-1223
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    • 2004
  • Porous silicon materials have been shown to have bright prospects for applications in light emitting, solar cell, as well as light- and chemical-sensing devices. In this report, structures of porous silicon prepared by anodic etching in HF-based solution with various etching times were studied in detail by Atomic Force Microscopy and Small Angle X -ray Scattering technique using the high energy beam line at Pohang Light Source in Korea. The results showed the coexistence of the various pores with nanometer and submicrometer scales. For nanameter size pores, the mixed ones with two different shapes were identified: the larger ones in cylindrical shape and the smaller ones in spherical shape. Volume fractions of the cylindrical and the spherical pores were about equal and remained unchanged at all etching times investigated. On the whole uniform values of the specific surface area and of the size parameters of the pores were observed except for the larger specific surface area for the sample with the short etching time. The results implies that etching process causes the inner surfaces to become smoother while new pores are being generated. In all SAXS data at large Q vectors, Porod slope of -4 was observed, which supports the fact that the pores have smooth surfaces.

Raman scattering spectroscopy as a characterization method of coated conductors

  • Um, Y.M.;Jo, W.
    • Progress in Superconductivity and Cryogenics
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    • v.9 no.4
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    • pp.24-27
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    • 2007
  • The purpose of this work is to develop, integrate, and implement an optical characterization method to evaluate physical properties in coated conductors and investigate the local distribution of the causes of degraded performance. The method that we selected at this moment is Raman scattering spectroscopy, which is accompanied with measurements of local supercurrent transport, phase composition, microstructure, and epitaxy quality for coated conductors that range in size up to multi-meter-length tapes and that embrace the entire tape embodiment (substrate through cap layer). The establishment of Raman spectroscopy as an on-line process monitoring tool is our eventual goal of research, but it requires very robust and cost-effective equipments. We analyzed $YBa_2Cu_3O_7(YBCO)$ thin films grown at various substrate temperatures by using Raman spectroscopy. YBCO films were grown by a high-rate electron-beam co-evaporation method. Raman spectra of YBCO films with lower-transport properties exhibit additional phonon modes at ${\sim}300cm^{-1}$, ${\sim}600cm^{-1}$ and ${\sim}630cm^{-1}$, which are related to second-phases such as $Ba_2Cu_3O_{5.9}$ and $BaCuO_2$. We propose a new method to characterize Raman spectra of coated conductors for an in-line quality control.

Evaluation of mechanical properties on friction stir lap jointed Al6061/HT590 alloys (겹치기 마찰교반접합 된 Al6061/HT590 합금의 기계적 특성 평가)

  • Kim, Eun-Hye;Lee, Kwang-Jin;Song, Kuk-Hyun
    • Journal of Welding and Joining
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    • v.33 no.2
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    • pp.8-13
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    • 2015
  • This study was carried out to evaluate mechanical properties of the jointed Al6061/HT590 alloys by friction stir welding (FSW). FSW was conducted under the conditions with tool rotating speed of 500 RPM and traveling speed of 300 mm/min., where Ar gas was introduced to prevent the materials from corrosion during the welding process. Electron back-scattering diffraction (EBSD) was used to characterize microstructures such as grain size, misorientation angle and crystal orientation. Evolution of intermetallic compounds in Al6061 during the process were examined in terms of morphology, size and aspect ratio at three distinct zones Al base material, heat affected zone and stir zone, where transmission electron microscope (TEM) was used. It was revealed that FSW gave rise to refinement of grains as well as growth of intermetallic compounds in Al6061. The morphological changes of intermetallic compounds exerted an influence on mechanical properties, resulting in occurrence of fracture in the part of the base material instead of the jointed parts (heat affected zone and stir zone). This study systematically evaluated the microstructural evolutions during the FSW for joining Al6061 with HT590 and their effect on mechanical properties.

Thermal Stability of Photo-produced H3O+ in the Photolyzed Water-ice Film

  • Moon, Eui-Seong;Kang, Heon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.192-192
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    • 2011
  • Hyperthermal ion scattering experiments were conducted with low kinetic energy (<35 eV) cesium ion beams to analyze the UV-photolyzed water-ice films. Neutral molecules (X) on the surface were detected as cesium-molecule ion clusters ($CsX^+$) which were formed through a Reactive Ion Scattering (RIS) process. Ionic species on the surface were desorbed from the surface via a low energy sputtering (LES) process, and were analyzed [1]. Using these methods, the thermal stability of hydronium ion ($H_3O^+$) that was produced by UV light was examined. As the thermal stability of $H_3O^+$ is related with the reaction, $H_3O^+$ + OH + $e^-$ (or $OH^-$) ${\rightarrow}$ $2H_2O$, which is similar or same with the reverse reaction of the auto-ionization of water, the result from this work would be helpful to understand the auto-ionization of $H_2O$ in water-ice that has not been well-understood yet. However, as $H_3O^+$ was not detected through a LES method, the titration experiment of $H_3O^+$ with methylamine ($CH_3NH_2$, MA), MA + $H_3O^+\;{\rightarrow}\;MAH^+$ + $H_2O$, was conducted. In this case, the presence of $MAH^+$ indicates that of $H_3O^+$ in the ice. Thus the pristine ice was photolyzed with UV light for a few minutes and this photolyzed ice was remained at the certain temperature for minutes without UV light. Then MA was adsorbed on that surface so that the population of $H_3O^+$ was found. From the calibration experiments, the relation of $MAH^+$ and $H_3O^+$ was found, so that the thermal stability of $H_3O^+$ can be investigated [2].

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The Characteristics of Arc Scattering and Fusing Current of Copper Wire in the Fault Process DB System of Cables in a PL Environment

  • Kim, Young-Seok;Shong, Kil-Mok;Kim, Sun-Gu
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.22 no.3
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    • pp.52-58
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    • 2008
  • The importance of. identifying the causes of electrical faults cannot be overstated because of the accidents caused by over-current that take place at the home, the office and electrical facilities due to misuse, poor products and system faults. It is necessary to gather objective, scientific data pertaining to electrical fault investigation in a product liability(PL) environment. To date, no database(DB) has been built concerning the accurate cause analysis of faultyfacilities. In this paper, accident hazard and arc scattering when over-current flows in copper wire was investigated. It was found that when over-current flows in a copper wire, the copper wire became heated and bent and beads were scattered around the wire with a flash. It was determinedthat the fusing current and time was related to the current rise per second. For example, when the current rise per second was largethe fusing current was higher than when the current rise per second was small, and the beads dispersed along a wide area. Fusing time, however, was shorter. The possibility of electrical fault became highest when the fusing current was higher. As the current rise per second is short, the dendrite structure is distributed in the surface of the copper wire. These experimental results can be utilized for a fault process DB system in the investigation and the prevention of electrical faults.

Microstructure and Conductivity of Cu-Nb Microcomposites Fabricated by Bundling and Drawing Process (다발체형성과 인발공정에 의해 제조된 Cu-Nb 미세복합재료의 미세조직과 전도도)

  • Kwon, Hoi-Joon;Hong, Sun-Ig;Jee, Kwang-Koo
    • Korean Journal of Materials Research
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    • v.11 no.2
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    • pp.115-119
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    • 2001
  • The electrical properties of heavily drawn bundled Cu- Nb filamentary microcomposite wires were examined and correlated with the microstructural changes caused by thermomechanical treatments. The cross sectional shape of Nb filaments in wires fabricated by bundling and drawing appear straight or slightly curved. The different shape of Nb filaments is attributed to the break- up and cylinderization of Nb filaments during the bundling process at high temperatures. The resistivity of Cu-Nb microcomposites is predominantly controlled by electron scattering at Cu-Nb interfaces. The decrease of the conductivity below the annealing temperature of $400^{\circ}C$ is due to the increasing contribution of the scattering associated with coherency strains of needle- shaped precipitates. The slight decrease of the resistivity ratio (${\rho}_{295K}/{\rho}_{75K}$) is also due to the precipitation of Nb atoms. The increase in conductivity in Cu-Nb microcomposites at an annealing temperature of 50$0^{\circ}C$ is due to the coarsening and spheroidization of Nb filaments.

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Enhancing the performance of a long-life modified CANDLE fast reactor by using an enriched 208Pb as coolant

  • Widiawati, Nina;Su'ud, Zaki;Irwanto, Dwi;Permana, Sidik;Takaki, Naoyuki;Sekimoto, Hiroshi
    • Nuclear Engineering and Technology
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    • v.53 no.2
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    • pp.423-429
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    • 2021
  • The investigation of the utilization of enriched 208Pb as a coolant to enhance the performance of a long-life fast reactor with a Modified CANDLE (Constant Axial shape of Neutron flux, nuclide densities, and power shape During Life of Energy production) burnup scheme has performed. The analyzes were performed on a reactor with thermal power of 800 MegaWatt Thermal (MWTh) with a refueling process every 15 years. Uranium Nitride (enriched 15N), 208Pb, and High-Cr martensitic steel HT-9 were employed as fuel, coolant, and cladding materials, respectively. One of the Pb-nat isotopes, 208Pb, has the smallest neutron capture cross-section (0.23 mb) among other liquid metal coolants. Furthermore, the neutron-producing cross-section (n, 2n) of 208Pb is larger than sodium (Na). On the other hand, the inelastic scattering energy threshold of 208Pb is the highest among Na, natPb, and Bi. The small inelastic scattering cross-section of 208Pb can harden the neutron energy spectrum. Therefore, 208Pb is a better neutron multiplier than any other liquid metal coolant. The excess neutrons cause more production than consumption of 239Pu. Hence, it can reduce the initial fuel loading of the reactor. The selective photoreaction process was developing to obtain enriched 208Pb. The neutronic was calculated using SRAC and JENDL 4.0 as a nuclear data library. We obtained that the modified CANDLE reactor with enriched 208Pb as coolant and reflector has the highest k-eff among all reactors. Meanwhile, the natPb cooled reactor has the lowest k-eff. Thus, the utilization of the enriched 208Pb as the coolant can reduce reactor initial fuel loading. Moreover, the enriched 208Pb-cooled reactor has the smallest power peaking factor among all reactors. Therefore, the enriched 208Pb can enhance the performance of a long-life Modified CANDLE fast reactor.

Software Formal Verification Methodology using Aspect DEVS Verification Framework (Aspect DEVS 검증 틀을 이용한 소프트웨어 정형 검증 방법론)

  • Choi, Chang-Beom;Kim, Tag-Gon
    • Journal of the Korea Society for Simulation
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    • v.18 no.3
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    • pp.113-122
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    • 2009
  • Software is getting more complex due to a variety of requirements that include desired functions and properties. Therefore, verifying and testing the software are complicated problems. Moreover, if the software is already implemented, inserting and deleting tracing/logging code into the source code may cause several problems, such as the code tangling and the code scattering problems. This paper proposes the Aspect DEVS Verification Framework which supports the verification and testing process. The Aspect DEVS Verification Framework utilizes Aspect Oriented Programming features to handle the code tangling and the code scattering problems. By applying aspect oriented features, a user can find and fix the inconsistency between requirement and implementation of a software without suffering the problems. The first step of the verification process is the building aspect code to make a software act as a generator. The second step is developing a requirement specification using DEVS diagrams and implementing it using the DEVSIM++. The final step is comparing the event traces from the software with the possible execution sequences from DEVS model.

Analysis of Multi-Mode Reflection and Transmission Coefficients of a Lamb Wave Across a Rectangular Notch (사각형 노치에 대한 램파의 다중 모드 반사와 투과 계수 해석)

  • Kim, Byung-Soo;Roh, Yong-Rae
    • The Journal of the Acoustical Society of Korea
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    • v.27 no.3
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    • pp.129-139
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    • 2008
  • The purpose of the present work is to derive the reflection and transmission coefficients of $S_0\;and\;A_0$ mode Lamb waves in relation to the geometry of a rectangular notch when the waves propagate across the notch in an elastic plate. Firstly, the excitable modes of the Lamb wave were analyzed with respect to the plate thickness. The scattering phenomena were divided into three independent processes according to the boundary shape of the notch and the direction of the wave propagation. Linear equations for each process were derived with corresponding free or continuous boundary conditions to analyze the scattered waves. By the rule of linear superposition, the waves scattered at each process were summed for each mode. Then the steady-state reflection and transmission coefficients of the scattered waves were determined so that the difference of energy flux between the incident and the scattered waves would remain within 4%.